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Measurement of single-molecule devices connected with conductive polymer chains

Research Project

Project/Area Number 24241047
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionNational Institute for Materials Science

Principal Investigator

OKAWA Yuji  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA研究者 (40242169)

Co-Investigator(Kenkyū-buntansha) ARIGA Katsuhiko  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主任研究者 (50193082)
SAKURAI Makoto  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA研究者 (60280731)
KUBO Osamu  大阪大学, 工学(系)研究科(研究院), 准教授 (70370301)
NAKAHARAI Shu  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA研究者 (90717240)
OGAWA Shinichi  国立研究開発法人産業技術総合研究所, ナノエレクトロニクス研究部門, 招聘研究員 (00590085)
Co-Investigator(Renkei-kenkyūsha) HILL Jonathan P.  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA研究者 (30421431)
TATEYAMA Yoshitaka  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, グループリーダー (70354149)
KOBAYASHI Nobuhiko  筑波大学, 数理物質科学研究科(系), 准教授 (10311341)
ISHI Hiroyuki  国立研究開発法人科学技術振興機構, さきがけ研究者 (00585127)
Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥49,010,000 (Direct Cost: ¥37,700,000、Indirect Cost: ¥11,310,000)
Fiscal Year 2015: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2013: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2012: ¥36,920,000 (Direct Cost: ¥28,400,000、Indirect Cost: ¥8,520,000)
Keywordsナノ材料 / 走査プローブ顕微鏡 / ナノデバイス / 分子素子 / 導電性高分子
Outline of Final Research Achievements

We have developed a novel method for fabricating single-molecule devices. In this method, a single conductive polymer chain is fabricated by a chain polymerization and connected to a single functional molecule. The purpose of this study is to develop and evaluate new methods of measuring electric transport properties of such single-molecule devices. We first examined appropriate insulating substrates for this study, and found that a hexagonal boron nitride was a good candidate. We then fabricated metal nano-electrodes on the substrate, and succeeded in creating single conductive polymer chains between the electrodes. In addition, we found selective adsorption of molecules on a molybdenum disulfide substrate, and also found the formation of arrays of gold nanoparticles on molecular layers.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (32 results)

All 2016 2015 2014 2013 2012 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (22 results) (of which Int'l Joint Research: 4 results,  Invited: 10 results) Book (2 results) Remarks (5 results)

  • [Journal Article] Tunable morphology from 2D to 3D in the formation of hierarchical architectures from a self-assembling dipeptide: thermal-induced morphological transition to 1D nanostructures2015

    • Author(s)
      Pradyot Koley, Makoto Sakurai and Masakazu Aono
    • Journal Title

      J. Mater. Sci.

      Volume: 50 Issue: 8 Pages: 3139-3148

    • DOI

      10.1007/s10853-015-8875-6

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Ordered Monomolecular Layers as a Template for the Regular Arrangement of Gold Nanoparticles2013

    • Author(s)
      Marina Makarova, Swapan K. Mandal, Yuji Okawa and Masakazu Aono
    • Journal Title

      Langmuir

      Volume: 29 Issue: 24 Pages: 7334-7343

    • DOI

      10.1021/la400177u

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Adsorption of Thiol Molecules at Sulfur Vacancies on MoS2(0001), Followed by Vacancy Repair via S-C Dissociation2012

    • Author(s)
      Marina Makarova
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 116 Issue: 42 Pages: 22411-22416

    • DOI

      10.1021/jp307267h

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Diacetylene monolayers and aggregates self-assembled on atomically flat surfaces2016

    • Author(s)
      Elisseos Verveniotis, Yuji Okawa. Marina V. Makarova, Yasuo Koide, Jiangwei Liu, Bretislav Smid, Kenji Watanabe, Takashi Taniguchi, Katsuyoshi Komatsu, Christian Joachim and Masakazu Aono
    • Organizer
      AFM Conference 2016
    • Place of Presentation
      済州島(韓国)
    • Year and Date
      2016-08-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Diacetylene monolayers and aggregates self-assembled on atomically flat surfaces2016

    • Author(s)
      Elisseos Verveniotis, Yuji Okawa. Marina V. Makarova, Yasuo Koide, Jiangwei Liu, Bretislav Smid, Kenji Watanabe, Takashi Taniguchi, Katsuyoshi Komatsu, Christian Joachim and Masakazu Aono
    • Organizer
      2016 E-MRS Spring Meeting and Exhibit
    • Place of Presentation
      リール(フランス)
    • Year and Date
      2016-05-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Diacetylene monolayers and aggregates self-assembled on atomically flat surfaces2016

    • Author(s)
      Elisseos Verveniotis, Yuji Okawa. Marina V. Makarova, Yasuo Koide, Jiangwei Liu, Bretislav Smid, Kenji Watanabe, Takashi Taniguchi, Katsuyoshi Komatsu, Christian Joachim and Masakazu Aono
    • Organizer
      MANA International Symposium 2016
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Year and Date
      2016-03-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Cleaning of Graphene and h-BN Surfaces after Lithography Process2015

    • Author(s)
      Marina Makarova, Elisseos Verveniotis, Shu Nakaharai, Takashi Taniguchi, Yuji Okawa and Masakazu Aono
    • Organizer
      The 5th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO 2015)
    • Place of Presentation
      朱鷺メッセ新潟コンベンションセンター(新潟県新潟市)
    • Year and Date
      2015-06-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of Single Polydiacetylene Chains for Single Molecular Wiring2015

    • Author(s)
      Yuji Okawa and Masakazu Aono
    • Organizer
      EMN Meeting on Polymer
    • Place of Presentation
      オーランド (アメリカ合衆国 フロリダ州)
    • Year and Date
      2015-01-07 – 2015-01-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Electrical Wiring of Single Molecules using Single Conductive Polymer Chains2014

    • Author(s)
      Yuji Okawa, Swapan K. Mandal, Marina Makarova, Elisseos Verveniotis and Masakazu Aono
    • Organizer
      The 2nd International Symposium on the Functionality of Organized Nanostructures 2014 (FON’14)
    • Place of Presentation
      日本科学未来館 (東京都江東区)
    • Year and Date
      2014-11-27 – 2014-11-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Single molecule wiring to realize single molecule electronics2014

    • Author(s)
      Yuji Okawa and Masakazu Aono
    • Organizer
      The 7th International Workshop on Advanced Materials Science and Nanotechnology (IWAMSN 2014)
    • Place of Presentation
      ハロン (ベトナム)
    • Year and Date
      2014-11-02 – 2014-11-06
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] On-surface synthesis of single conjugated polymer chains for single molecular wiring2014

    • Author(s)
      Yuji Okawa
    • Organizer
      International Workshop “On-Surface Synthesis”
    • Place of Presentation
      レ・ズッシュ (フランス)
    • Year and Date
      2014-05-25 – 2014-05-30
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Self-assembly and Polymerization of Diacetylene on Hexagonal Boron Nitride Substrates for Electrical Studies of Single Polydiacetylene Chains2014

    • Author(s)
      Marina Makarova, Yuji Okawa, Takashi Taniguchi and Masakazu Aono
    • Organizer
      TNT Japan 2014
    • Place of Presentation
      東京ビッグサイト(東京都江東区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Hexagonal Boron Nitride as a Substrate for Electrical Studies of Polydiacetylene Chains2014

    • Author(s)
      Marina Makarova, Yuji Okawa, Takashi Taniguchi and Masakazu Aono
    • Organizer
      MANA International Symposium 2014
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Interconnects with Single Conjugated Polymers2013

    • Author(s)
      Yuji Okawa, Swapan K. Mandal, Marina Makarova and Masakazu Aono
    • Organizer
      2013 IEEE International Interconnect Technology Conference (IITC 2013)
    • Place of Presentation
      京都リサーチパーク(京都府京都市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Single Molecular Wiring Toward Single Molecular Electronics2013

    • Author(s)
      Yuji Okawa
    • Organizer
      2013 CMOS Emerging Technologies Research Symposium
    • Place of Presentation
      Hilton Whistler Resort and Spa(カナダ ブリティッシュコロンビア州 ウィスラー)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Single Polymer Connection to Single Molecules and Metal Nanoclusters2013

    • Author(s)
      Yuji Okawa, Swapan K. Mandal, Marina Makarova and Masakazu Aono
    • Organizer
      2013 NIMS Conference
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Diacetylene Self-Assembled Monolayer as a Template for the Linear Arrangement of Ligand-Free Gold Nanoparticles2013

    • Author(s)
      Marina Makarova, Yuji Okawa, Swapan K. Mandal and Masakazu Aono
    • Organizer
      2013 NIMS Conference
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Ordered Arrays of Gold Nanoparticles on a Diacetylene Self-Assembled Monolayer Template2013

    • Author(s)
      Marina Makarova, Yuji Okawa, Swapan K. Mandal and Masakazu Aono
    • Organizer
      ACSIN12 & ICSPM21
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Single molecule wiring by single polymer chain

    • Author(s)
      大川祐司
    • Organizer
      12th International Workshop on Stress-Induced Phenomena in Microelectronics (Stress Workshop 2012)
    • Place of Presentation
      コープイン京都(京都府)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Chemical Soldering: New Method for Single Molecular Interconnects

    • Author(s)
      大川祐司
    • Organizer
      2012 International Conference on Solid State Devices and Materials (SSDM 2012)
    • Place of Presentation
      国立京都国際会館(京都府)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Chemical Soldering for Single Molecule Electronics

    • Author(s)
      大川祐司
    • Organizer
      1st International Conference on Emerging Advanced Nanomaterials (ICEAN-2012)
    • Place of Presentation
      Mercure Hotel Brisbane(ブリスベン, オーストラリア)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Single Molecular Interconnects by Controlling Chain Polymerization

    • Author(s)
      大川祐司
    • Organizer
      2013 MRS Spring Meeting & Exhibit
    • Place of Presentation
      Moscone Center(サンフランシスコ, アメリカ合衆国)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 単一高分子配線技術

    • Author(s)
      大川祐司
    • Organizer
      日本学術振興会 半導体界面制御技術第154委員会 第86回研究会
    • Place of Presentation
      東京大学生産技術研究所(東京都)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Selective adsorption and subsequent dissociation of thiol derivatives at sulfur vacancies on MoS2(0001)

    • Author(s)
      Marina Makarova
    • Organizer
      20th International Colloquium on Scanning Probe Microscopy (ICSPM20)
    • Place of Presentation
      沖縄かりゆしアーバンリゾート・ナハ(沖縄県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Selective Adsorption of Thiol Molecules to Sulfur Vacancies on MoS2(0001), and Repair of the Vacancies via S-C Dissociation

    • Author(s)
      Marina Makarova
    • Organizer
      MANA International Symposium 2013
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Related Report
      2012 Annual Research Report
  • [Book] On-Surface Synthesis, Advances in Atom and Single Molecular Machines2016

    • Author(s)
      Yuji Okawa, Swapan K. Mandal, Marina Makarova, Elisseos Verveniotis and Masakazu Aono
    • Total Pages
      287
    • Publisher
      Springer
    • Related Report
      2015 Annual Research Report
  • [Book] 導電性ポリマー材の高機能化と用途開発最前線2014

    • Author(s)
      大川祐司、青野正和
    • Total Pages
      265
    • Publisher
      株式会社エヌ・ティー・エス
    • Related Report
      2014 Annual Research Report
  • [Remarks] NIMS Researchers Database SAMURAI

    • URL

      http://samurai.nims.go.jp/OKAWA_Yuji-j.html

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
  • [Remarks] NIMS Researchers Database SAMURAI

    • URL

      http://samurai.nims.go.jp/OKAWA_Yuji-j.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] Nano-System Organization group

    • URL

      http://www.nims.go.jp/nano_sys_org_gr/top.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] NIMS Researchers Database SAMURAI

    • URL

      http://samurai.nims.go.jp/OKAWA_Yuji-j.html

    • Related Report
      2012 Annual Research Report
  • [Remarks] Nano-System Organization group

    • URL

      http://www.nims.go.jp/nano_sys_org_gr/top.html

    • Related Report
      2012 Annual Research Report

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Published: 2013-05-15   Modified: 2019-07-29  

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