| Budget Amount *help |
¥47,450,000 (Direct Cost: ¥36,500,000、Indirect Cost: ¥10,950,000)
Fiscal Year 2014: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2013: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Fiscal Year 2012: ¥32,760,000 (Direct Cost: ¥25,200,000、Indirect Cost: ¥7,560,000)
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| Outline of Final Research Achievements |
The aim of the research project is to establish multi-functional molecular materials using electron-donor/-acceptor-based conductive molecular magnets or highly redox-active molecular framework compounds, in which not only ‘physical responses’ such as magnetic ordering, electron transporting, and dielectric responses resulted from their frameworks, but also ‘chemical reactions’ involving chemical adsorption/desorption of gaseous molecules in nano-sized pores are synergistically functioned. We discovered tunable selective NO adsorption behavior in a series of electron-donor-type chain compounds based on paddlewheel-type diruthenium(II, II) complexes, and succeeded to capture modifications involving gas adsorptions as gate-opening gas adsorption transitions and chemical interactions caused by host-guest interactions as electric signals by applying ac electric fields in situ gas handling.
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