| Budget Amount *help |
¥45,110,000 (Direct Cost: ¥34,700,000、Indirect Cost: ¥10,410,000)
Fiscal Year 2016: ¥12,480,000 (Direct Cost: ¥9,600,000、Indirect Cost: ¥2,880,000)
Fiscal Year 2015: ¥12,480,000 (Direct Cost: ¥9,600,000、Indirect Cost: ¥2,880,000)
Fiscal Year 2014: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2013: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2012: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
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| Outline of Final Research Achievements |
In this study, development of carbon dioxide fixation reactions with carbon-carbon bond formation was extensively studied based on the results obtained in our laboratory. Development of hydrocarboxylation reactions of styrene and electron deficient alkenes, direct C-H bond carboxylation of simple arenes, use of formate salt as a reductant in the hydrocarboxylation reaction, utilization of visible light for the reduction of carboxylate salt to metal hydride or low valent metal for catalytic hydrocarboxylation reaction and caboxylation of aryl halides were achieved by this study. These results would afford new possibilities in carbon dioxide fixation chemistry.
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