| Budget Amount *help |
¥37,570,000 (Direct Cost: ¥28,900,000、Indirect Cost: ¥8,670,000)
Fiscal Year 2014: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
Fiscal Year 2013: ¥12,220,000 (Direct Cost: ¥9,400,000、Indirect Cost: ¥2,820,000)
Fiscal Year 2012: ¥14,690,000 (Direct Cost: ¥11,300,000、Indirect Cost: ¥3,390,000)
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| Outline of Final Research Achievements |
Highly selective and efficient functionalizations of unsaturated substrates such as alkynes and 1,2-dienes (allenes) have been developed by utilizing acid chlorides, aldehydes, formamides, and carbon dioxides as functionality sources. Unlike former transformations, proper choice of central metals and ligands of the catalyst prevent loss of the functionalities during the catalytic reactions. Further addition of hydrosilanes, silylboranes, and diboranes to the catalytic systems realized reductive, silylative, and borylative functionalizations.
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