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Development of the measurement system to characterize the atomic and electronic structures of the single molecular junction

Research Project

Project/Area Number 24245027
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

Manabu Kiguchi  東京工業大学, 理工学研究科, 教授 (70313020)

Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥36,530,000 (Direct Cost: ¥28,100,000、Indirect Cost: ¥8,430,000)
Fiscal Year 2015: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2014: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Fiscal Year 2013: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Fiscal Year 2012: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000)
Keywords単分子接合 / 振動分光 / 表面増強ラマン散乱 / 電気伝導度 / 単分子化学 / マイクロ・ナノデバイス / ナノコンタクト
Outline of Final Research Achievements

We have developed the new system to characterize the atomic and electronic structures of the single molecular junction by measuring the surface enhanced Raman scattering, inelastic electron tunneling spectroscopy, thermopower measurement. We also succeeded to fabricate the single molecular switch showing multiple conductance states, and single molecular devices whose functionality can be freely replaced. The working mechanism is revealed by the characterization with newly developed system.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (48 results)

All 2016 2015 2014 2013 2012

All Journal Article (30 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 30 results,  Acknowledgement Compliant: 13 results,  Open Access: 2 results) Presentation (18 results) (of which Int'l Joint Research: 2 results,  Invited: 12 results)

  • [Journal Article] Site selection in single-molecule junction for highly reproducible molecular electronics2016

    • Author(s)
      S. Kaneko, D. Murai, S. Marques-Gonzalez, H. Nakamura, Y. Komoto, S. Fujii, T. Nishino, K. Ikeda, K. Tsukagoshi, M. Kiguchi
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 138 Issue: 4 Pages: 1294-1300

    • DOI

      10.1021/jacs.5b11559

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of the Molecule-Metal Interface on Surface Enhanced Raman Scattering of 1,4-Benzenedithiol Molecule2016

    • Author(s)
      S. Suzuki, S. Kaneko, S. Fujii, S. Marques-Gonzalez, T. Nishino, M. Kiguchi
    • Journal Title

      J. Phys. Chem. C

      Volume: 120 Issue: 2 Pages: 1038-1042

    • DOI

      10.1021/acs.jpcc.5b10385

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Surface enhanced Raman scattering of a single molecular junction2015

    • Author(s)
      R. Matsushita, M. Kiguchi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 印刷中 Issue: 33 Pages: 21363-21371

    • DOI

      10.1039/c4cp04906c

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] High electronic couplings of single mesitylene molecular junctions2015

    • Author(s)
      Y. Komoto, S. Fujii, T. Nishino, M. Kiguchi
    • Journal Title

      Beilstein J. Nanotech.

      Volume: 6 Pages: 2431-2437

    • DOI

      10.3762/bjnano.6.251

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Electrical conduction and structure of copper atomic junctions in the presence of water molecules2015

    • Author(s)
      Y. Li, F. Demir, S. Kaneko, S. Fujii, T. Nishino, A. Saffarzadeh, G. Kirczenow, M. Kiguchi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 17 Issue: 48 Pages: 32436-32442

    • DOI

      10.1039/c5cp05227k

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Effect of Mechanical Strain on Electric Conductance of Molecular Junctions2015

    • Author(s)
      J. Inatomi, S. Fujii, S. M. Gonzalez, H. Masai, Y. Tsuji, J. Terao, M. Kiguchi
    • Journal Title

      J. Phys. Chem. C

      Volume: 119 Issue: 33 Pages: 19452-19457

    • DOI

      10.1021/acs.jpcc.5b04386

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Symmetry of Single Hydrogen Molecular Junction with Au, Ag and Cu Electrodes2015

    • Author(s)
      Y. Li, S. Kaneko, S. Fujii, M. Kiguchi
    • Journal Title

      J. Phys. Chem. C

      Volume: 119 Issue: 33 Pages: 19143-19148

    • DOI

      10.1021/acs.jpcc.5b04720

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Single naphthalene and anthracene molecular junctions using Ag and Cu electrodes in ultra high vacuum2015

    • Author(s)
      S. Fujii, S. Kaneko, L. Chenyang, and M. Kiguchi
    • Journal Title

      Appl. Surf. Sci

      Volume: 354 Pages: 362-362

    • DOI

      10.1016/j.apsusc.2015.05.071

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface enhanced Raman scattering of molecules in metallic nanogaps2015

    • Author(s)
      S. M. Gonzalez, R. Matsushita, M. Kiguchi
    • Journal Title

      J. Optics

      Volume: 17 Issue: 11 Pages: 114001-114001

    • DOI

      10.1088/2040-8978/17/11/114001

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Rectifying electron-transport properties through stacks of aromatic molecules inserted into a self-assembled cage2015

    • Author(s)
      S. Fujii, T. Tada, Y. Komoto, T. Osuga, T. Murase, M. Fujita, M. Kiguchi
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 137 Issue: 18 Pages: 5939-5947

    • DOI

      10.1021/jacs.5b00086

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Simultaneous Measurement of Electrical Conductance and Thermopower of Single Benzeneditiol Molecular Junctions2015

    • Author(s)
      S.Kaneko, Y. Nakamura, R. Matsushita, S. Marques-Gonzalez, M. Kiguchi
    • Journal Title

      APEX

      Volume: 8 Issue: 6 Pages: 065201-065201

    • DOI

      10.7567/apex.8.065201

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly conductive single naphthalene and anthracene molecular junction with well-defined conductance2015

    • Author(s)
      C. Liu, S. Kaneko, Y. Komoto, S. Fujii, and M. Kiguchi
    • Journal Title

      Appl. Phys. Lett.

      Volume: 106 Issue: 10 Pages: 103103-103103

    • DOI

      10.1063/1.4914501

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Single Cu Atomic Chain in Nitrogen Atmosphere2015

    • Author(s)
      S. Kaneko, Y. Nakamura, M. Kiguchi, J. Zhang, X. Yang, J. Zhao
    • Journal Title

      J. Phys. Chem. C

      Volume: 119 Issue: 1 Pages: 862-866

    • DOI

      10.1021/jp510916h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photochromic reaction of the diarylethene derivative on Au nanoparticles2015

    • Author(s)
      R. Takahashi, S. Kaneko, S. Fujii and M. Kiguchi
    • Journal Title

      Adv. Nat. Sci.: Nanosci. Nanotechnol

      Volume: 6 Issue: 1 Pages: 015006-015006

    • DOI

      10.1088/2043-6262/6/1/015006

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Temperature dependence of the thermopower and its variation of the Au atomic contact2015

    • Author(s)
      Ryuji Matsushita, Satoshi Kaneko, Shintaro Fujii, Hisao Nakamura, Manabu Kiguchi
    • Journal Title

      Nanotechnology

      Volume: 26 Issue: 4 Pages: 045709-045709

    • DOI

      10.1088/0957-4484/26/4/045709

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Extension of photopolymerization region from the nanoscale to the macroscopic scale using a chemically amplified photoresist2014

    • Author(s)
      R. Takahashi, S. Kaneko, S. Fujii, M. Kiguchi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 印刷中 Issue: 2 Pages: 277-282

    • DOI

      10.1246/bcsj.20140243

    • NAID

      130004703939

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Single Linear Aromatic Molecule Junction with High Formation Probability2014

    • Author(s)
      C. Liu, S. Kaneko, Y. Komoto, S. Fujii, M. Kiguchi
    • Journal Title

      Appl. Phys. Exp

      Volume: 7 Issue: 10 Pages: 105201-105201

    • DOI

      10.7567/apex.7.105201

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Highly stable Au atomic contacts covered with benzenedithiol in ambient condition2014

    • Author(s)
      D. Murai, T. Nakazumi, S. Fujii, Y. Komoto, K. Tsukagoshi, C. Motta, M. Kiguchi
    • Journal Title

      PCCP

      Volume: 16 Issue: 29 Pages: 15662-15666

    • DOI

      10.1039/c4cp01950d

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Metal atomic contacts under defined environmental conditions2014

    • Author(s)
      T. Nakazumi, S. Kaneko, M. Kiguchi
    • Journal Title

      J. Phys. Chem. C

      Volume: 118 Issue: 14 Pages: 7489-7493

    • DOI

      10.1021/jp5012318

    • NAID

      130005004331

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Additive Electron Pathway and Non-additive Molecular Conductance by Using a Multipodal Bridging Compound2014

    • Author(s)
      M. Kiguchi, Y. Takahashi, S. Fujii, M. Takase, T. Narita, M. Iyoda, M. Horikawa, Y. Naitoh, H. Nakamura
    • Journal Title

      J. Phys. Chem. C

      Volume: 118 Issue: 10 Pages: 5275-5283

    • DOI

      10.1021/jp4100262

    • Related Report
      2014 Annual Research Report 2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single molecular resistive switch obtained via sliding multiple anchoring points and varying effective wire length2014

    • Author(s)
      M. Kiguchi, T. Ohto, S. Fujii, K. Sugiyasu, S. Nakajima, M. Takeuchi, and H. Nakamura
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Issue: 20 Pages: 7327-7332

    • DOI

      10.1021/ja413104g

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single Molecular Bridging of Au Nanogap using Aryl Halide Molecules2013

    • Author(s)
      Yuki Komoto, Shintaro Fujii, Kenji Hara, Manabu Kiguchi
    • Journal Title

      J. Phys. Chem. C

      Volume: 117 Issue: 46 Pages: 24277-24282

    • DOI

      10.1021/jp404858x

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Investigation on the Pyrazine Molecular Junction Studied by Conductance Measurement and Near Edge X-ray Absorption Fine Structure2013

    • Author(s)
      Satoshi Kaneko, Manabu Kiguchi
    • Journal Title

      Fullerenes, Nanotubes and Carbon Nanostructures

      Volume: 22 Issue: 1-3 Pages: 166-172

    • DOI

      10.1080/1536383x.2013.798723

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Conductive [3×n] Gold-Ion Clusters Enclosed within Self-Assembled Cages2013

    • Author(s)
      Kiguchi, M ; Inatomi, J ; Takahashi, Y ; Tanaka, R ; Osuga, T ; Murase, T ; Fujita, M ; Tada, T ; Watanabe S.
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 52 Issue: 24 Pages: 6202-6205

    • DOI

      10.1002/anie.201301665

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conductance and SERS Measurement of Benzenedithiol Molecules Bridging Between Au Electrodes2013

    • Author(s)
      R. Matsushita, M. Horikawa, Y. Naitoh, H. Nakamura, M. Kiguchi
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 117 Issue: 4 Pages: 1791-1795

    • DOI

      10.1021/jp3112638

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electric Conductance of Single Ethylene and Acetylene Molecules Bridging between Pt Electrodes2012

    • Author(s)
      Tomoka Nakazumi, Satoshi Kaneko, Ryuuji Matsushita and Manabu Kiguchi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 116 Pages: 18250-18255

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication and Characterization of Decanedithiol Molecule Junction using Nano Gap Electrodes2012

    • Author(s)
      Yuuta Takahashi, Manabu Kiguchi*, Masayo Horikawa, Yasuhisa Naitoh, Ken Tsutsui, Hitoshi Takagi, Masayuki Morita, Masahide Tokuda, Yoshitoshi Ito, Yasuo Wada
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 51 Pages: 75201-75201

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron transport through single π-conjugated molecules bridging between metal electrodes2012

    • Author(s)
      Manabu Kiguchi and Satoshi Kaneko
    • Journal Title

      Chem Phys Chem

      Volume: 13 Pages: 1116-1126

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metal atomic contact under electrochemical potential control2012

    • Author(s)
      Manabu Kiguchi and Kei Murakoshi
    • Journal Title

      Journal of Physics: Condensed Matter

      Volume: 24 Pages: 164212-164212

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single Molecule Conductance of π-Conjugated Rotaxane: New Method for Measuring Stipulated Electric Conductance of π-Conjugated Molecular Wire Using STM Break Junction2012

    • Author(s)
      Manabu Kiguchi, Shigeto Nakashima, Tomofumi Tada, Satoshi Watanabe, Susumu Tsuda, Yasushi Tsuji, Jun Terao
    • Journal Title

      Small

      Volume: 8 Pages: 726-730

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] SERSとI-Vの同時計測による金属―分子局所界面構造の決定2016

    • Author(s)
      木口学
    • Organizer
      日本化学会
    • Place of Presentation
      大阪
    • Year and Date
      2016-03-27
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 界面制御に基づく単分子接合の新機能の開拓およびその発現機構の解明2016

    • Author(s)
      木口学
    • Organizer
      日本化学会
    • Place of Presentation
      大阪
    • Year and Date
      2016-03-26
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Single Molecular Devices using Supermolecules2015

    • Author(s)
      M. Kiguchi
    • Organizer
      Pacific Chem 2015
    • Place of Presentation
      ホノルル
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ベンゼンジチオール単分子のSERSと電流―電圧特性の同時計測2015

    • Author(s)
      木口学,金子哲, 村井大午
    • Organizer
      表面界面スペクトロスコピー2015
    • Place of Presentation
      埼玉
    • Year and Date
      2015-11-28
    • Related Report
      2015 Annual Research Report
  • [Presentation] 単分子接合のSERSと電流―電圧特性の同時計測2015

    • Author(s)
      木口学,金子哲, 村井大午
    • Organizer
      分子アーキテクトニクス研究会
    • Place of Presentation
      京都
    • Year and Date
      2015-10-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 金属と分子の界面構造を舞台とした単分子物性2015

    • Author(s)
      木口学
    • Organizer
      高分子討論会
    • Place of Presentation
      仙台
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] Single Molecular Device using STM2015

    • Author(s)
      M. Kiguchi
    • Organizer
      ECN-2015
    • Place of Presentation
      オデッサ(ウクライナ)
    • Year and Date
      2015-09-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 単分子接合におけるダイオード、スイッチング特性2015

    • Author(s)
      木口学
    • Organizer
      物性研究所短期研究会
    • Place of Presentation
      柏
    • Year and Date
      2015-06-24
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Investigation on nano scale molecular dynamics using enhanced field at the metal nano gap2014

    • Author(s)
      M.Kiguchi
    • Organizer
      The 7th International workshop on advanced materials science
    • Place of Presentation
      Halong (Vietnam)
    • Year and Date
      2014-11-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] 機能性分子を用いた単分子素子開発2014

    • Author(s)
      木口学
    • Organizer
      第1回資源研フォーラム
    • Place of Presentation
      東京
    • Year and Date
      2014-10-22
    • Related Report
      2014 Annual Research Report
  • [Presentation] Single molecular dynamics using the surface enhanced raman scattering2014

    • Author(s)
      M. Kiguchi
    • Organizer
      van der Waals colloquium
    • Place of Presentation
      Leiden (Netherlands)
    • Year and Date
      2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] 単一分子接合の化学2013

    • Author(s)
      木口学
    • Organizer
      第7回分子科学討論会2013
    • Place of Presentation
      京都
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 振動分光による電極間の架橋した単分子のダイナミクスの研究2013

    • Author(s)
      木口学
    • Organizer
      日本表面科学会第76回表面科学研究会
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 単分子計測を利用した電子輸送過程の解明2013

    • Author(s)
      木口学
    • Organizer
      第3回CSJ化学フェスタ2013
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 金属電極に架橋した単一分子の電気伝導度、振動スペクトル計測2012

    • Author(s)
      木口学
    • Organizer
      ナノ学会
    • Place of Presentation
      大阪大学(大阪)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 単一分子計測に基づくπスタック系における電子輸送過程の解明2012

    • Author(s)
      木口学
    • Organizer
      物理学会
    • Place of Presentation
      横浜国立大学(横浜)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Vibrational spectroscopy of a single molecule bridging between metal electrodes2012

    • Author(s)
      木口学
    • Organizer
      14th International Conference on Vibrations at Surfaces
    • Place of Presentation
      神戸ポートアイランドセンター(神戸)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 金属電極に架橋した単一pi共役分子の構造および伝導特性の解明2012

    • Author(s)
      木口学
    • Organizer
      表面科学会
    • Place of Presentation
      東北大学(仙台)
    • Related Report
      2012 Annual Research Report
    • Invited

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Published: 2013-05-15   Modified: 2019-07-29  

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