Electronic function of organic semiconductor mediated by weak perturbation:Elucidation of misterius properties of organic device interfaces
Project/Area Number |
24245034
|
Research Category |
Grant-in-Aid for Scientific Research (A)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Functional materials/Devices
|
Research Institution | Chiba University |
Principal Investigator |
UENO Nobuo 千葉大学, 融合科学研究科(研究院), 特任研究員 (40111413)
|
Co-Investigator(Kenkyū-buntansha) |
KERA Satoshi 分子科学研究所, 教授 (10334202)
|
Project Period (FY) |
2012-04-01 – 2015-03-31
|
Project Status |
Completed (Fiscal Year 2014)
|
Budget Amount *help |
¥44,200,000 (Direct Cost: ¥34,000,000、Indirect Cost: ¥10,200,000)
Fiscal Year 2014: ¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000)
Fiscal Year 2013: ¥13,130,000 (Direct Cost: ¥10,100,000、Indirect Cost: ¥3,030,000)
Fiscal Year 2012: ¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
|
Keywords | 有機半導体 / 有機デバイス / 界面 / エネルギー準位接合 / 電荷移動度 / 光電子分光 / 電子状態 / 電子-振動結合 / 移動度 / バンド分散 |
Outline of Final Research Achievements |
Ultrahigh-sensitivity ultraviolet photoelectron spectroscopy (UPS) was realized for radiation-sensitive organic materials and was used to investigate electronic states in band gap of organic semiconductors. The results show the striking effects for pentacene: exposure to inert gas (N2 and Ar) produces gap states and pushes the Fermi level closer to the valence band. The results demonstrate that these gap states originate from small imperfections in the molecular packing structure, which impact on the energy level alignment in various organic devices. Electronic band dispersions in insulating picene single crystals were measured by UPS coupled with laser-induced photoconductivity. Based on these fundamental studies, we fabricated C60 transistors using structure-controlled C60 thin film on DIP template/SiO2 gate insulator, and found that high electron mobility and high operational stability are achieved with the gap-states controlled C60 thin film transistors on the DIP/SiO2 gate.
|
Report
(4 results)
Research Products
(109 results)
-
-
-
-
-
-
-
-
-
[Journal Article] Seleno groups control the energy-level alignment between conjugated organic molecules and metals2014
Author(s)
J.Niederhausen, S.Duhm, G.Heimel, C.Burker, Q.Xin, A.Wilke, A.Vollmer, F.Schreiber, S.Kera, J.P.Rabe, N.Ueno, and N.Koch
-
Journal Title
J. Chem. Phys.
Volume: 140
Issue: 1
DOI
Related Report
Peer Reviewed
-
-
[Journal Article] Charged and Metallic Molecular Monolayers through Surface-Induced Aromatic Stabilisation2013
Author(s)
G. Heimel, S. Duhm, I. Salzmann, A.Gerlach, A.Strozecka, J.Niederhausen, C.Burker, T.Hosokai, I.Fernandez-Torrente, G.Schulze, S.Winkler, A.Wilke, R.Schlesinger, J.Frisch, B.Broker, A.Vollmer, B.Detlefs, J.Pflaum, S.Kera,K.J.Franke, N.Ueno, J.I.Pascual, F.Schreiber, and N.Koch
-
Journal Title
Nature Chemistry
Volume: 5
Issue: 3
Pages: 187-194
DOI
Related Report
Peer Reviewed
-
-
-
[Journal Article] Inverted polymer solar cells integrated with small molecular electron collection layer2013
Author(s)
A.-L.Shi, Y.-Q.Li, Z.-Q.Xu, F.-Z.Sun, J.Li,X.-B.Shi, H.-X.Wei, S.-T.Lee, S.Kera, N.Ueno, and J.-X.Tang
-
Journal Title
Org. Electronics
Volume: 14
Issue: 7
Pages: 1844-1851
DOI
Related Report
Peer Reviewed
-
-
[Journal Article] Experimental reorganization energies of pentacene and perfluoropentacene : Effects of perfluorination2013
Author(s)
S.Kera, S.Hosoumi, K.Sato, H.Fukagawa, S.Nagamatsu, Y.Sakamoto, T.Suzuki, H.Huang, W.Chen, A.T.S.Wee, V.Coropceanu, and N.Ueno
-
Journal Title
J. Phys. Chem. C
Volume: 117
Issue: 43
Pages: 22428-22437
DOI
Related Report
Peer Reviewed
-
-
[Journal Article] Pentacene on Ag(111) : Correlation of bonding distance with intermolecular interaction and order2013
Author(s)
S.Duhm, C.Burker, J.Niederhausen, I.Salzmann, T.Hosokai, J.Duvernay, S.Kera, F.Schreiber, N.Koch, N.Ueno, and A.Gerlach
-
Journal Title
ACS Appl. Mater Interfaces
Volume: 5(19)
Issue: 19
Pages: 9377-9381
DOI
Related Report
Peer Reviewed
-
[Journal Article] Quantitatively identical orientation-dependent ionization energy and electron affinity of diindenoperylene2013
Author(s)
W. N. Han, K. Yonezawa, R. Makino, K. Kato, A. Hinderhofer, R. Murdey, R. Shiraishi, H. Yoshida, N. Sato, N. Ueno, and S. Kera
-
Journal Title
Appl. Phys. Lett.
Volume: 103
Issue: 25
Pages: 253301-253301
DOI
NAID
Related Report
Peer Reviewed
-
-
-
-
[Journal Article] Correlating Temperature Dependent Electrical Transport Through Alkyl Monolayers with vibrational and Photoelectron Spectroscopies, Shpaisman2012
Author(s)
H.Shpaisman, O.Seitz, O.Yaffe, K.Roodenko, L.Scheres, H.Zuilhof, Y.J.Chabal, T.Sueyoshi, S.Kera, N.Ueno, A.Vilan, D.Cahen
-
Journal Title
Chemical Science
Volume: 3
Issue: 3
Pages: 851-862
DOI
Related Report
Peer Reviewed
-
-
-
-
-
[Journal Article] Post-growth surface smoothing of thin fims of diindenoperylene2012
Author(s)
A. Hinderhofer, T. Hosokai, K.Yonezawa, A. Gerlach, K. Broch, C. Frank, K. Kato, J. Novak, S. Kera, N. Ueno, and F. Schreiber
-
Journal Title
Appl. Phys. Lett.
Volume: 101
Issue: 3
DOI
Related Report
Peer Reviewed
-
-
-
-
-
-
[Presentation] Charged and metallic molecular monolayers through surface-induced aromatic stabilisation2014
Author(s)
G. Heime, S. Duhm, I. Salzmann, A. Gerlach, A. Strozecka, J. Niederhausen, C. Broeker, T. Hosokai, I. Fernandez-Torrente, G. Schulze, S. Winkler, A. Wilke, R. Schlesinger, J. Frisch, B. Bröker, A. Vollmer, B. Detlefs, J. Pflaum, S. Kera, K. J. Franke, N. Ueno, J. I. Pascual, F. Schreiber, and N. Koch
Organizer
578th Wilhelm and Else Heraeus-Seminar (WEH seminar) on “Charge-Transfer Effects in Organic Heterostructures: Fundamentals and Applications”
Place of Presentation
Bad Honnef, Germany
Year and Date
2014-12-09 – 2014-12-12
Related Report
-
-
-
-
-
-
-
-
-
-
-
-
-
-
[Presentation] Origin of the energy-level alignment at binary molecular monolayer2014
Author(s)
K. Yonezawa, J. L. Zhang, S. Yanagisawa, T. Matsushita, R. Makino, K. Kato, A. Hinderhofer, A. T. S. Wee, W. Chen, N. Ueno, and S. Kera
Organizer
7th Swedish-Japanese-German Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications
Place of Presentation
Lund, Sweden
Year and Date
2014-06-08 – 2014-06-11
Related Report
-
[Presentation] Band dispersion measurements of lead-phthalocyanine single crystal by angle-resolved time of flight spectroscopy2014
Author(s)
K. Sato, S. Duhm, T. Kaji, M. Hiramoto, R. Ovsyannikov, M. Gorgoi, S. Krause, M. Oehzelt, N. Maartensson, S. Svensson, N. Ueno, and S. Kera
Organizer
7th Swedish-Japanese-German Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications
Place of Presentation
Lund, Sweden
Year and Date
2014-06-08 – 2014-06-11
Related Report
-
-
-
-
-
-
-
-
-
-
-
[Presentation] Geometric and Electronic Structure of Templated C60 on DIP, the 11th China-Japan Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena2013
Author(s)
A. Hinderhofer, A. Gerlach, K. Broch, T. Hosokai, K. Yonezawa, K. Kato, J. Yang, Q. Sun, S. D. Wang, S. Kera, N. Ueno, F. Schreiber
Organizer
The 11th China-Japan Joint Symp. on Conduction and Photoconduction in Organic Solids and Related Phenomena
Place of Presentation
Changchun, China
Related Report
-
-
-
-
-
-
[Presentation] Surface-induced aromatic stabilization of disc-like conjugated molecules2013
Author(s)
Steffen Duhm, Benjamin Broker, Alexander Gerlach, Christoph Burker, Jens Niederhausen, Ingo Salzmann, Takuya Hosokai, Jorg Zegenhagen, Antje Vollmer, Ralph Rieger, Satoshi Kera, Klaus Mullen, Nobuo Ueno, Frank Schreiber and Norbert Koch
Organizer
The Kyoto JSAP-MRS joint meeting
Place of Presentation
Kyoto, Japan
Related Report
-
-
-
-
-
-
[Presentation] Temperature dependent growth and dewetting behavior of tetraseleno-tetracene on Au(111) and Ag(111) studied by photoelectron spectroscopy2013
Author(s)
J. Niederhausen, S. Duhm, C. Bürker, Q. Xin, A. Wilke, A. Vollmer, F. Schreiber, S. Kera, N. Ueno, and N. Koch
Organizer
DPG Spring Meeting
Place of Presentation
Regensburg, Germany
Related Report
-
-
-
-
-
[Presentation] 有機分子薄膜の電子状態への分子間分極効果の影響2013
Author(s)
米澤 恵一朗,Jia-Lin Zhang , Swee Liang Wong, Tianchao Niu, Alexander Hinderhofer, Wei Chen, 上野 信雄, 解良 聡
Organizer
第60回応用物理学関係連合講演会
Place of Presentation
神奈川工科大学
Related Report
-
-
-
-
-
[Presentation] Geometric and Electronic Structure of Templated C60 on Diindenoperylene Thin Films2012
Author(s)
A. Hinderhofer, K. Yonezawa, K. Kato, S. Kera, N. Ueno, T. Hosokai, A. Gerlach, K. Broch, F. Schreiber
Organizer
10th International Conference on Nano-Molecular Electronics (ICNME2012)
Place of Presentation
Awaji, Hyogo, Japan
Related Report
-
-
-
-
-
-
[Presentation] Accessing Surface Brillouin Zone and Band Structure of Insulating Picene Single Crystals2012
Author(s)
S. Kera, Q. Xin, S. Duhm, F. Bussolotti, Y. Liu, K. Akaike, Y. Kubozono, H.Aoki, T. Kosugi, N. Ueno
Organizer
The 12th International Conference on Electron Spectroscopy and Structure (ICESS12)
Place of Presentation
Saint-Malo, France
Related Report
-
-
-
-
-
-
[Presentation] Post-growth surface smoothing of thin films of diindenoperylene2012
Author(s)
A. Hinderhofer, T. Hosokai, K. Yonezawa, A. Gerlach, K. Kato, K. Broch, C. Frank, J. Novák, S. Kera, N. Ueno, F. Schreiber
Organizer
2012年秋季第73回応用物理学会学術講演会
Place of Presentation
愛媛大学
Related Report
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-