• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

A novel reaction and separation technology for simultaneous production of bioactive compounds and biofuels from oil biomass

Research Project

Project/Area Number 24246127
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionTohoku University

Principal Investigator

YONEMOTO Toshikuni  東北大学, 工学(系)研究科(研究院), 教授 (40125688)

Co-Investigator(Kenkyū-buntansha) KITAKAWA Naomi (SHIBASAKI Naomi)  東北大学, 大学院工学研究科, 准教授 (00261503)
NAKASHIMA Kazunori  北海道大学, 大学院工学研究科, 准教授 (50540358)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥46,670,000 (Direct Cost: ¥35,900,000、Indirect Cost: ¥10,770,000)
Fiscal Year 2014: ¥16,120,000 (Direct Cost: ¥12,400,000、Indirect Cost: ¥3,720,000)
Fiscal Year 2013: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Fiscal Year 2012: ¥19,630,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥4,530,000)
Keywordsプロセスシステム設計 / 反応・分離技術
Outline of Final Research Achievements

Oil biomass contains triglyceride, its hydrolysate (free fatty acid, FFA) and lipid-soluble bioactive compounds such as vitamin E (tocopherol and tocotrienol) and phytosterol. However, no industrial technology to efficiently recover bioactive compounds with lower thermal stability has been established. We have proposed a novel reaction and separation technology at 50 ℃ and atmospheric pressure using ion-exchange resins as catalysts and adsorbents. The technology enables the complete conversions of both triglyceride and FFA to biodiesel and selective recovery of vitamin E from oils. Especially, tocotrienol has succeeded to be recovered at the highest ratio, more than 60 %. The solubility of phytosterol in biodiesel becomes lower than that in oils, so that phytosterol has been crystallized at room temperature and easily recovered. Therefore, this novel technology to simultaneously produce vitamin E, phyrosterol and biodiesel from biomass gives profitability to the enterprise.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (34 results)

All 2015 2014 2013 2012 2011 Other

All Journal Article (6 results) (of which Peer Reviewed: 5 results) Presentation (26 results) (of which Invited: 4 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Production of high quality biodiesel from waste acid oil obtained during edible oil refining using ion-exchange resin catalysts2015

    • Author(s)
      N.Shibasaki-Kitakawa, K.Hiromori, T.Ihara, K.Nakashima, T.Yonemoto
    • Journal Title

      Fuel

      Volume: 139 Pages: 11-17

    • DOI

      10.1016/j.fuel.2014.08.024

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A fusion enzyme consisting of bacterial expansin and endoglucanase for the degradation of highly crystalline cellulose2014

    • Author(s)
      K.Nakashima, K.Endo, N.Shibasaki-Kitakawa, T.Yonemoto
    • Journal Title

      RSC ADVANCES

      Volume: 4 Issue: 83 Pages: 43815-43820

    • DOI

      10.1039/c4ra05891g

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 脂肪酸100%の油をも原料利用可能な高品質バイオディーゼル連続製造プロセスの開発2014

    • Author(s)
      北川尚美、 中島一紀、 米本年邦
    • Journal Title

      ケミカルエンジニアリング

      Volume: 59 Pages: 20-26

    • Related Report
      2013 Annual Research Report
  • [Journal Article] Simultaneous production of high quality biodiesel and glycerin from Jatropha oil using ion-exchange resins as catalysts and adsorbent2013

    • Author(s)
      N.Shibasaki-Kitakawa, K.Kanagawa, K.Nakashima, T.Yonemoto
    • Journal Title

      Bioresource Technology

      Volume: 142 Pages: 732-736

    • DOI

      10.1016/j.biortech.2013.05.111

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Production of human secreted alkaline phosphatase in suspension and immobilization cultures of tobacco NT1 cell2013

    • Author(s)
      K.Nakashima, N.Shibasaki-Kitakawa, T.Miyamoto, M.Kubo, T.Yonemoto
    • Journal Title

      Biochemical Engineering Journal

      Volume: 77 Pages: 177-182

    • DOI

      10.1016/j.bej.2013.06.004

    • NAID

      210000003269

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Kinetic Model Describing Antioxidation and Prooxidation of .-Carotene in the Presence of .-Tocopherol and Ascorbic Acid2011

    • Author(s)
      N. Shibasaki-Kitakawa, M. Murakami, M. Kubo, T. Yonemoto
    • Journal Title

      Journal of the American Oil Chemists' Society

      Volume: 89 Issue: 5 Pages: 815-824

    • DOI

      10.1007/s11746-011-1980-z

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Pilot scale production of high quality biodiesel from vegetable oils with high free fatty acid content using ion-exchange resin catalysts2015

    • Author(s)
      N.Shibasaki-Kitakawa
    • Organizer
      化学工学会 第80年会
    • Place of Presentation
      芝浦工業大学豊洲キャンパス(東京都, 江東区)
    • Year and Date
      2015-03-21
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 分子蒸留を必要としない樹脂を吸着剤としたトコトリエノールの高効率回収2015

    • Author(s)
      廣森浩祐, 北川尚美, 米本年邦
    • Organizer
      第26回ビタミンE研究会
    • Place of Presentation
      北里大学薬学部(東京都, 港区)
    • Year and Date
      2015-01-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] 容量可変式樹脂充填反応器を用いたバイオディーゼルの連続合成2014

    • Author(s)
      山﨑功大, 北川尚美, 中島一紀, 米本年邦
    • Organizer
      化学工学会 第46回秋季大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡, 福岡)
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] イオン交換樹脂法によるパイロットプラントを用いた高品質バイオディーゼルの連続製造2014

    • Author(s)
      北川尚美, 大柳友克, 斯琴高娃, 中島一紀, 米本年邦
    • Organizer
      第23回日本エネルギー学会大会
    • Place of Presentation
      九州大学箱崎キャンパス(福岡, 福岡)
    • Year and Date
      2014-07-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] A Novel Method for Selective Recovery of Tocotrienol from Rice Bran Deodorizer Distillate Using Ion-exchange Resin without Molecular Distillation2014

    • Author(s)
      K.Hiromori, N.Shibasaki-Kitakawa, K.Nakashima, T.Yonemoto
    • Organizer
      105th AOCS Annual Meeting & Expo
    • Place of Presentation
      Henry B. Gonzalez Convention Center (San Antonio, TX, USA)
    • Year and Date
      2014-05-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Continuous Production of Fatty Acid Ethyl Ester from Crude Jatrpha Oil Using Ion-exchange Resin Catalystsand Evaluation of Fuel Quality2014

    • Author(s)
      N.Shibasaki-Kitakawa, T.Oyanagi, S.Borjigin, K.Nakashima, T.Yonemoto
    • Organizer
      105th AOCS Annual Meeting & Expo
    • Place of Presentation
      Henry B. Gonzalez Convention Center (San Antonio, TX, USA)
    • Year and Date
      2014-05-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] イオン交換樹脂を触媒としたバイオディーゼル燃料の連続製造技術2013

    • Author(s)
      北川尚美、米本年邦
    • Organizer
      東北大学イノベーションフェア
    • Place of Presentation
      仙台
    • Related Report
      2012 Annual Research Report
  • [Presentation] 廃棄脂肪酸油からの高品質バイオディーゼル連続合成プロセスの開発2013

    • Author(s)
      井原亨、北川尚美、中島一紀、米本年邦
    • Organizer
      化学工学会第78年会
    • Place of Presentation
      大阪
    • Related Report
      2012 Annual Research Report
  • [Presentation] 生体膜系におけるリン脂質とコレステロールの共酸化速度論2013

    • Author(s)
      鮏川祐子、北川尚美、中島一紀、米本年邦
    • Organizer
      化学工学会第78年会
    • Place of Presentation
      大阪
    • Related Report
      2012 Annual Research Report
  • [Presentation] High Quality Biodiesel Production from Waste Acid Oil Using Ion-exchange Resins as Catalysts and Adsorbents2012

    • Author(s)
      N. Shibasaki-Kitakawa, T. Ihara, K. Nakashima, T. Yonemoto
    • Organizer
      103rd AOCS Annual Meeting & Expo
    • Place of Presentation
      Long Beach, CA, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] A New Biodiesel Production Process Using Ion-exchange Resins as Catalysts and Adsorbents2012

    • Author(s)
      N. Shibasaki-Kitakawa, T. Yonemoto
    • Organizer
      ACHEMA (International Powder and Nanotechnology Forum 2012)
    • Place of Presentation
      Frankfurt, Germany
    • Related Report
      2012 Annual Research Report
  • [Presentation] Simple Production Process of High Quality Biodiesel and Glycerin from Jatropha Oil Using Cation-and Anion-exchange Resins2012

    • Author(s)
      N. Shibasaki-Kitakawa, K. Kanagawa, K. Nakashima, T. Yonemoto
    • Organizer
      World Congress on Oleo Science (WCOS 2012) & 29th ISF Congress
    • Place of Presentation
      Sasebo, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] セルロースの酵素分解における超音波前処理の効果2012

    • Author(s)
      中島一紀、佐藤拓海、北川尚美、米本年邦
    • Organizer
      第64回日本生物工学会大会
    • Place of Presentation
      神戸
    • Related Report
      2012 Annual Research Report
  • [Presentation] 食用油製造工程で排出する遊離脂肪酸残渣油を原料とした高品質バイオディーゼル燃料の連続製造技術の開発

    • Author(s)
      米本年邦、北川尚美、木村俊之
    • Organizer
      平成25年度環境省社会形成推進研究発表会
    • Place of Presentation
      中央大学(東京)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] High Quality Biodiesel Production from Acid Oils Using Ion-exchange Resin as Catalysts and Adsorbent

    • Author(s)
      N.Shibasaki-Kitakawa, T.Yonemoto
    • Organizer
      The 13th The International Conference on QiR
    • Place of Presentation
      Sheraton Mustika Resort & Spa(Yogyakarta, Indonesia)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] A Kinetic Model Describing Antioxidation and Prooxidation of β-Carotene in the Presence of α-Tocopherol and Ascorbic Acid

    • Author(s)
      N.Shibasaki-Kitakawa, T.Yonemoto
    • Organizer
      104th AOCS Annual Meeting & Expo
    • Place of Presentation
      Palais des congress de Montreal(Montreal, Canada)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] セルロース吸着性タンパク質を融合したセルラーゼの吸着および反応特性

    • Author(s)
      遠藤 孝治、中島 一紀、北川 尚美、米本 年邦
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学(岐阜)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Process optimization of regeneration of anion-exchange resin catalyst for biodiesel production

    • Author(s)
      Umdu Emin Selahattin、N. Shibasaki-Kitakawa, K. Nakashima, T. Yonemoto
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学(岐阜)
    • Related Report
      2013 Annual Research Report
  • [Presentation] バイオ燃料と健康機能物質の同時製造を実現する反応分離技術

    • Author(s)
      北川 尚美、米本 年邦
    • Organizer
      東北大学イノベーションフェア2014
    • Place of Presentation
      仙台国際センター(仙台)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Pilot plant productin of high quality biodiesel without downstream purification process

    • Author(s)
      N. Shibasaki-Kitakawa, T.Oyanagi, K.Nakashima, T. Yonemoto
    • Organizer
      Asian Congress on Biotechnology2013
    • Place of Presentation
      Indian Institute of Technology Delhi (New Delhi, India)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Simultaneous Reaction and Purification Process for Continuous Production of High Quality Biodiesel From Acid Oils

    • Author(s)
      N. Shibasaki-Kitakawa, T. Ihara, T. Yonemoto
    • Organizer
      2013AIChE Annual Meeting
    • Place of Presentation
      San Francisco Union Square (San Franchisco, USA)
    • Related Report
      2013 Annual Research Report
  • [Presentation] セルロース系バイオマスの酵素分解における超音波前処理の影響

    • Author(s)
      海老友稀, 中島一紀, 北川尚美, 米本年邦
    • Organizer
      化学工学会第45回秋季大会
    • Place of Presentation
      岡山大学(岡山)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 陰イオン交換樹脂を吸着剤としたビタミンE類の回収

    • Author(s)
      廣森浩祐, 北川尚美, 中島一紀, 米本年邦
    • Organizer
      化学工学会第45回秋季大会
    • Place of Presentation
      岡山大学(岡山)
    • Related Report
      2013 Annual Research Report
  • [Presentation] フリーラジカル存在下での生体膜脂質の共酸化速度論

    • Author(s)
      北川尚美, 鮏川祐子,中島一紀, 米本年邦
    • Organizer
      日本油化学会第52回年会
    • Place of Presentation
      東北大学(仙台)
    • Related Report
      2013 Annual Research Report
  • [Presentation] パイロットプラントを用いたジャトロファ粗油から高品質バイオディーゼル製造

    • Author(s)
      北川尚美, 大柳友克, 中島一紀, 米本年邦
    • Organizer
      化学工学会盛岡大会2013
    • Place of Presentation
      岩手大学(盛岡)
    • Related Report
      2013 Annual Research Report
  • [Presentation] イオン交換樹脂を触媒・吸着剤とする高品質バイオディーゼルの連続合成プロセス

    • Author(s)
      北川尚美, 米本年邦
    • Organizer
      第2回JACI/GSCシンポジウム
    • Place of Presentation
      メルパルク大阪(大阪)
    • Related Report
      2013 Annual Research Report
  • [Remarks] (1)高品質バイオディーゼル連続製造装置紹介

    • URL

      http://www.youtube.com/watch?v=27JGXhWU2BA

    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] 油からビタミンE類の選択的な連続回収方法2014

    • Inventor(s)
      北川尚美, 米本年邦, 廣森浩祐
    • Industrial Property Rights Holder
      北川尚美, 米本年邦, 廣森浩祐
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-022613
    • Filing Date
      2014-02-07
    • Related Report
      2013 Annual Research Report

URL: 

Published: 2013-05-15   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi