Fabrication of Capsule Reactor Type Artificial Photosynthesis System for the Direct Formation of Methanol from CO2
| Project/Area Number |
24310052
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Environmental technology/Environmental materials
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| Research Institution | Utsunomiya University |
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Principal Investigator |
SUZUKI Noboru 宇都宮大学, 工学(系)研究科(研究院), 教授 (40134259)
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| Co-Investigator(Renkei-kenkyūsha) |
SATO Masahide 宇都宮大学, 大学院工学研究科, 准教授 (10261504)
FURUSAWA Takeshi 宇都宮大学, 大学院工学研究科, 助教 (50375523)
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| Research Collaborator |
KURAYAMA Fumio
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| Project Period (FY) |
2012-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥14,690,000 (Direct Cost: ¥11,300,000、Indirect Cost: ¥3,390,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
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| Keywords | 人工光合成 / マイクロカプセル / 酵素 / 光触媒 / 電子伝達物質 / 二酸化炭素 / メタノール / カプセル / 亜鉛テトラフェニルポルフィリン / ポルフィリン |
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| Outline of Final Research Achievements |
Photochemical enzymatic synthesis has received considerable attention for artificial photosynthesis. In this work, the preparation of novel photoactive organic-inorganic hybrid microcapsules with photosensitizer and enzyme for visible-light driven photoenzymatic synthesis was studied. In this system, light energy converts to chemical energy though a visible-light induced electron-transfer (ET) from excited zinc tetraphenyl-porphyrin (ZnTPP) located in an capsule shell to a redox enzyme inside the capsule with the assistance of methyl viologen (MV) as an electron mediator. Consequently, higher encapsulation yield of enzyme was achieved by alginate and 3-(2-aminoethylamino)propyltrimethoxysilane based capsules, and the formate was formed from carbon dioxide. Also, using kappa-carrageenan and 3-aminopropyltriethoxysilane based capsules followed by the crosslinking with glutaraldehyde had the reusability and the experimental results suggested the formation of a small amount of methanol.
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Report
(5 results)
Research Products
(8 results)
