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Fabrication of Capsule Reactor Type Artificial Photosynthesis System for the Direct Formation of Methanol from CO2

Research Project

Project/Area Number 24310052
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionUtsunomiya University

Principal Investigator

SUZUKI Noboru  宇都宮大学, 工学(系)研究科(研究院), 教授 (40134259)

Co-Investigator(Renkei-kenkyūsha) SATO Masahide  宇都宮大学, 大学院工学研究科, 准教授 (10261504)
FURUSAWA Takeshi  宇都宮大学, 大学院工学研究科, 助教 (50375523)
Research Collaborator KURAYAMA Fumio  
Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥14,690,000 (Direct Cost: ¥11,300,000、Indirect Cost: ¥3,390,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
Keywords人工光合成 / マイクロカプセル / 酵素 / 光触媒 / 電子伝達物質 / 二酸化炭素 / メタノール / カプセル / 亜鉛テトラフェニルポルフィリン / ポルフィリン
Outline of Final Research Achievements

Photochemical enzymatic synthesis has received considerable attention for artificial photosynthesis. In this work, the preparation of novel photoactive organic-inorganic hybrid microcapsules with photosensitizer and enzyme for visible-light driven photoenzymatic synthesis was studied. In this system, light energy converts to chemical energy though a visible-light induced electron-transfer (ET) from excited zinc tetraphenyl-porphyrin (ZnTPP) located in an capsule shell to a redox enzyme inside the capsule with the assistance of methyl viologen (MV) as an electron mediator. Consequently, higher encapsulation yield of enzyme was achieved by alginate and 3-(2-aminoethylamino)propyltrimethoxysilane based capsules, and the formate was formed from carbon dioxide. Also, using kappa-carrageenan and 3-aminopropyltriethoxysilane based capsules followed by the crosslinking with glutaraldehyde had the reusability and the experimental results suggested the formation of a small amount of methanol.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (8 results)

All 2016 2015 2014 2013 2012

All Journal Article (1 results) (of which Acknowledgement Compliant: 1 results) Presentation (5 results) Book (2 results)

  • [Journal Article] 有機-無機マイクロカプセルへの酵素等のナノ触媒の固定化(解説)2015

    • Author(s)
      倉山文男, 古澤毅, 佐藤正秀, 鈴木昇
    • Journal Title

      化学工業

      Volume: 66 Pages: 46-50

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Presentation] カッパ-カラギーナンとシランカップリング剤による新規カプセルの調製2016

    • Author(s)
      宮本 翔,田村 弘幸,倉山 文男,古澤 毅,佐藤 正秀,鈴木 昇
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学千里山キャンパス
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 亜鉛ポルフィリン/酵素複合型マイクロカプセルを用いた人工光合成の検討2015

    • Author(s)
      田村 弘幸,倉山 文男,古澤 毅,佐藤 正秀,鈴木 昇
    • Organizer
      化学工学会群馬大会2015
    • Place of Presentation
      桐生市市民文化会館
    • Year and Date
      2015-11-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] Preparation of photoactive organic-inorganic hybrid microcapsules with zinc porphyrin and enzyme2014

    • Author(s)
      F. Kurayama, H. Tamura, S. Miyamoto, K. Kimura, T. Furusawa, M. Sato, N. Suzuki
    • Organizer
      2014 International Conference on Artificial Photosynthesis (ICARP2014)
    • Place of Presentation
      Awaji, Hyogo
    • Year and Date
      2014-11-24 – 2014-11-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] 酵素を内包した有機-無機ハイブリッドビーズの新しい作成法2014

    • Author(s)
      倉山文男, 田村弘幸, 江田沙也加, 古澤毅, 佐藤正秀, 鈴木昇
    • Organizer
      第79回化学工学会年会
    • Place of Presentation
      岐阜大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] アミノシラン-アルギン酸複合カプセルの調製と光触媒/酵素複合系人工光合成への応用2013

    • Author(s)
      太田元, 木藤潤成, 倉山文男, 古潭毅, 佐藤正秀, 鈴木昇
    • Organizer
      第78回化学工学会年会
    • Place of Presentation
      第78回化学工学会年会
    • Year and Date
      2013-03-18
    • Related Report
      2012 Annual Research Report
  • [Book] Silane : Chemistry, Applications and Performance (第6章担当)2012

    • Author(s)
      Fumio Kurayama, Takeshi Furusawa, Masahide Sato, Newaz Mohammed Bahadur, Noboru Suzuki(編集者:Manuel E. Molina, Andres J. Quiroga)
    • Total Pages
      21
    • Publisher
      Nova Science Publishers Inc.
    • Related Report
      2012 Annual Research Report
  • [Book] Alginates : Production, Types and Applications (第7章 担当)2012

    • Author(s)
      Fumio Kurayama, Takeshi Furusawa, Masahide Sato, Newaz Mohammed Bahadur, Noboru Suzuki(編集者:Katsuo Moriguchi, Susumu Utagawa)
    • Total Pages
      21
    • Publisher
      Nova Science Publishers Inc.
    • Related Report
      2012 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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