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Creation of Highly Efficient Environmental Remediation Materials using Metabolic-functional Photocatalysts

Research Project

Project/Area Number 24310063
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionKanagawa Academy of Science and Technology

Principal Investigator

TAKAGI Katsuhiko  公益財団法人神奈川科学技術アカデミー, イノベーションセンター、高度計測センター, 研究顧問兼プロジェクトリーダー (60023264)

Co-Investigator(Kenkyū-buntansha) SAKAI Munetoshi  山口東京理科大学, 工学部, 助教 (00392928)
NAKATA Kazuya  東京理科大学, 理工学部, 准教授 (70514115)
KATSUMATA Kenichi  東京理科大学, 研究推進機構, 准教授 (70550242)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2014: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2012: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Keywordsモノリス型チタニア光触媒 / 新陳代謝性光触媒 / 銅、窒素ドープ型チタニア / ソルボサーマル法 / ナノチューブチタニア / 自己エッチング / PEG添加効果 / 環境負荷低減 / 光触媒 / モノリス構造体
Outline of Final Research Achievements

Copper or Nitrogen-doped TiO2 powder samples with a monolith structure were synthesized and evaluated for their photocatalytic activities. The samples were modified into a nanotube structure (TNT) by a solvo-thermal method, leading to an improvement in their photocatalytic properties. Without TNT modification, light scattering caused the TiO2 powder samples to become opaque so that a preparation method for a monolith-structured, transparent organic membrane was established for use as a self-cleaning membrane. Sustainability of their transparency was confirmed by weathering tests of the metabolic function and durability of the adsorbed dyes. Moreover, the monolith structure of the TiO2 powder surfaces was investigated in detail by neutron scattering spectroscopic analysis. Transparent and self-etching monolith TiO2 membranes were also prepared by the optimal addition of PEG.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (26 results)

All 2015 2014 2013 2012 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (18 results) (of which Invited: 3 results) Remarks (1 results)

  • [Journal Article] Comparative study of the impact and sliding behavior of water droplets on two different hydrophobic silane coatings2014

    • Author(s)
      A. Nakajima, T. Miyamoto, M. Sakai, T. Isobe, S. Matsushita
    • Journal Title

      Appl. Surf. Sci

      Volume: 305

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visible-light-driven photodegradation of acetaldehyde gas catalyzed by aluminosilicate nanotubes and Cu(II)-grafted TiO2 composites2013

    • Author(s)
      K. Katsumata, X. Houa, M. Sakai, A. Nakajima, A. Fujishima, N. Matsushita, K. J.D. MacKenziee, Kiyoshi Okada
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: 138 Pages: 243-252

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sliding of Water Droplets on Smooth Hydrophobic Silane Coatings with Regular Triangle Hydrophilic Regions2013

    • Author(s)
      A. Nakajima, Y. Nakagawa, T. Furuta, M. Sakai, T. Isobe, S. Matsushita
    • Journal Title

      Langmuir

      Volume: 29 Pages: 9269-9275

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Factors Affecting UV-Induced Superhydrophilic Conversion of a TiO2 Surface2013

    • Author(s)
      A. V. Emeline, A. V. Rudakova, M. Sakai, T. Murakami, A. Fujishima
    • Journal Title

      J. Phys. Chem. C

      Volume: 117 Pages: 12086-12092

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Partial UV Illumination on a Mixture of Water and a Methylene Blue Solution in a Micro Channel Coated with TiO22013

    • Author(s)
      M. Sakai, et. al.
    • Journal Title

      Applied Surface Science

      Volume: 265 Pages: 925-928

    • DOI

      10.1016/j.apsusc.2012.11.043

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and Photocatalytic Activity of Robust Titania Monoliths for Water Remediation2013

    • Author(s)
      K. Nakata, T. Kagawa, M. Sakai, S. Liu, T. Ochiai, H. Sakai, T. Murakami, M. Abe, A. Fujishima
    • Journal Title

      ACS Applied Mater. Interfaces

      Volume: 5 Issue: 3 Pages: 500-504

    • DOI

      10.1021/am302654r

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visible-light-driven photodegradation of acetaldehyde gas catalyzed by al uminosilicate nanotubes and Cu(II)-grafted TiO2 composites2013

    • Author(s)
      K. Katsumata, et. al.
    • Journal Title

      Applied Catalysis B : Environmental

      Volume: 138-139 Pages: 243-252

    • DOI

      10.1016/j.apcatb.2013.03.004

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Design and Application of Functional Materials for Energy and Material Conversion2015

    • Author(s)
      中田一弥
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部 船橋キャンパス
    • Year and Date
      2015-03-28
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Synthesis of TiO2 monolith structure modified nanotubes2014

    • Author(s)
      Ken-ichi Katsumata, Momoko Yamamoto, Nobuhiro Matsushita, Kiyoshi Okada
    • Organizer
      Pacific Rim Symposium on Surface, Coating and Interfaces
    • Place of Presentation
      Hpuna Beach Prince Hotel, Kohala Coast,
    • Year and Date
      2014-12-07 – 2014-12-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] 機能性材料を用いたエネルギー・物質変換2014

    • Author(s)
      中田一弥
    • Organizer
      次世代産業カレッジ
    • Place of Presentation
      東京理科大学森戸記念館
    • Year and Date
      2014-10-24
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 光機能性材料の開発と光エネルギー変換への応用2014

    • Author(s)
      中田一弥
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-10-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Photocatalytic Activity of Porous TiO2 Monoliths2014

    • Author(s)
      Momoko Yamamoto, Ken-ichi Katsumata, Hiroko Takei, Munetoshi Sakai, Kazuya Nakata, Nobuhiro Matsushita, Katsuhiko Takagi, Kiyoshi Okada
    • Organizer
      IUMRS International Conference in Asia 2014
    • Place of Presentation
      Fukuoka University
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] ゾルゲル法により合成した酸化チタンモノリスの光触媒活性評価2014

    • Author(s)
      山本桃子、勝又健一、竹井寛子、酒井宗寿、中田一弥、松下伸広、高木克彦、岡田清
    • Organizer
      第3回 JACI/GSCシンポジウム
    • Place of Presentation
      東京国際フォーラム
    • Year and Date
      2014-05-22 – 2014-05-23
    • Related Report
      2014 Annual Research Report 2013 Annual Research Report
  • [Presentation] Synthesis and Photocatalytic Activity of Porous TiO2 Monoliths2014

    • Author(s)
      Momoko Yamamoto, Ken-ichi Katsumata, Hiroko Takei, Munetoshi Sakai, Kazuya Nakata, Nobuhiro Matsushita, Katsuhiko Takagi, Kiyoshi Okada
    • Organizer
      The 15th IUMRS-International Conference in Asia (IUMRS-ICA 2014)
    • Place of Presentation
      Fukuoka University, Fukuoka, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] 環境負荷低減に資する光触媒機能界面の創成と応用2012

    • Author(s)
      中田一弥
    • Organizer
      横浜国立大学大学院工学研究院グループ研究セミナー
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2012-12-21
    • Related Report
      2012 Annual Research Report
  • [Presentation] チタニアモノリスを用いた水中有機化合物の光触媒分解2012

    • Author(s)
      香川智哉, 他
    • Organizer
      第19回シンポジウム 光触媒反応の最近の展開
    • Place of Presentation
      東京大学生産技術研究所
    • Year and Date
      2012-12-10
    • Related Report
      2012 Annual Research Report
  • [Presentation] 有機モノリスを用いた表面維持機能を有するセルフクリーニング膜の開発2012

    • Author(s)
      吉川弘大, 他
    • Organizer
      第19回シンポジウム 光触媒反応の最近の展開
    • Place of Presentation
      東京大学生産技術研究所
    • Year and Date
      2012-12-10
    • Related Report
      2012 Annual Research Report
  • [Presentation] 酸化チタンの光誘起親水性を利用した円管内の流動性制御2012

    • Author(s)
      守井泰士, 他
    • Organizer
      日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      愛知
    • Year and Date
      2012-09-19
    • Related Report
      2012 Annual Research Report
  • [Presentation] 酸化チタンをコーティングしたマイクロ流路内での水の流動性に及ぼす光照射の影響2012

    • Author(s)
      小林大斗, 他
    • Organizer
      日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      愛知
    • Year and Date
      2012-09-19
    • Related Report
      2012 Annual Research Report
  • [Presentation] 光触媒薄膜の光誘起親水性とナノ構造を利用した応用展開2012

    • Author(s)
      勝又健一
    • Organizer
      熊本大学拠点形成研究B ソフト溶液プロセスをベースとした階層的ナノ組織集積材料の創成 第5回講演会
    • Place of Presentation
      熊本大学
    • Year and Date
      2012-07-13
    • Related Report
      2012 Annual Research Report
  • [Presentation] 特異ナノ構造を利用した光触媒材料の作製2012

    • Author(s)
      勝又健一
    • Organizer
      神戸大学 創製光分子科学セミナー
    • Place of Presentation
      神戸大学
    • Year and Date
      2012-06-19
    • Related Report
      2012 Annual Research Report
  • [Presentation] ナノ構造を利用した光機能材料の作製2012

    • Author(s)
      勝又健二
    • Organizer
      高知大学 第一回グリーンサイエンス講演会
    • Place of Presentation
      高知大学
    • Year and Date
      2012-05-25
    • Related Report
      2012 Annual Research Report
  • [Presentation] 有機モノリス構造体を利用した高液滴転落性を有する撥水性表面

    • Author(s)
      酒井宗寿、加藤智也、林美緒、中島章、藤嶋昭
    • Organizer
      第20回記念シンポジウム「光触媒反応の最近の展開」
    • Place of Presentation
      東京大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] モノリス構造を有するTiO2の作製と光触媒活性評価

    • Author(s)
      山本桃子、勝又健一、岡田清、松下伸広
    • Organizer
      第12回 無機材料合同研究会
    • Place of Presentation
      山梨大学 甲府キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] 新陳代謝機能を有する透明セルフクリーニング膜の開発

    • Author(s)
      吉川弘大、中田一弥、酒井宗寿、寺島千晶、酒井秀樹、阿部正彦、藤嶋昭
    • Organizer
      第20回記念シンポジウム「光触媒反応の最近の展開」
    • Place of Presentation
      東京大学
    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.newkast.or.jp/innovation/labo/fujishima_project.html

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2012-04-24   Modified: 2019-07-29  

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