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Molecular design and exploitation of emitting and spin transport single-molecular devices

Research Project

Project/Area Number 24310090
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionKyoto University

Principal Investigator

TANAKA KAZUYOSHI  京都大学, 工学(系)研究科(研究院), 教授 (90155119)

Co-Investigator(Kenkyū-buntansha) TANAKA Shoji  分子科学研究所, 分子スケールナノサイエンスセンター, 助教 (20192635)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥20,150,000 (Direct Cost: ¥15,500,000、Indirect Cost: ¥4,650,000)
Fiscal Year 2014: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2013: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2012: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Keywords1分子科学 / 分子発光素子 / 分子スピン素子 / 複合有機超分子 / ナノギャップ電極 / 1分子科学
Outline of Final Research Achievements

To exploit light-emitting and spin-transport single-molecular devices with nanoscale dimension, we have successfully prepared giant conjugated molecules containing strong light-emitting and/or spin-containing molecular core units and long oligothiophenes as molecular wires. Sequential coupling reactions gave a series of giant conjugated light-emitting molecules, the lengths of which reach over 10 nm. The electronic properties of these giant molecules were investigated by the electrochemical and electronic absorption and/or emission spectroscopic measurements.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (19 results)

All 2015 2014 2013 2012 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 2 results) Presentation (13 results) Remarks (2 results)

  • [Journal Article] Electronic Structure of Tetraaza[1.1.1.1]o,p,o,p-cyclophane and its Oxidized States2014

    • Author(s)
      Daisuke Sakamaki, Akihiro Ito, Takashi Matsumoto, and Kazuyoshi Tanaka
    • Journal Title

      RSC Advances

      Volume: 4 Issue: 74 Pages: 39476-39483

    • DOI

      10.1039/c4ra06065b

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fluorescent Triphenylamine Derivative: Theoretical Design Based on Reduced Vibronic Coupling2014

    • Author(s)
      Yuichiro Kameoka, Masashi Uebe, Akihiro Ito, Tohru Sato, and Kazuyoshi Tanaka
    • Journal Title

      Chemical Physics Letters

      Volume: 615 Pages: 44-49

    • DOI

      10.1016/j.cplett.2014.10.004

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Redox Modulation of para-Phenylenediamine by Substituted Nitr onyl Nitroxide Groups and Their Spin States2013

    • Author(s)
      A. Ito, R. Kurata, D. Sakamaki, S. Yano, Y. Kono, Y. Nakano, K. Furukawa, T. Kato, K. Tanaka
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 117 Issue: 48 Pages: 12858-12867

    • DOI

      10.1021/jp4095613

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Polymacrocyclic Oligoarylamine with a Pseudobeltane Motif : Towards a Cylindrical Multispin System2012

    • Author(s)
      Daisuke Sakamaki, Akihillo I to, KoFurukawa, Tatsuhisa Kato, Motoo Shiro, Kazuyoshi Tanaka
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 51 Pages: 12776-12781

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] アミノ基を有するピレン誘導体の合成と電子物性2015

    • Author(s)
      倉田亮平・酒巻大輔・伊藤彰浩・田中一義
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス/薬学部
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] カルボラン含有トリフェニル誘導体の合成と電子物性2015

    • Author(s)
      上辺将士・亀岡優一郎・伊藤彰浩・佐藤徹・田中一義
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス/薬学部
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] ニトロキシドラジカル置換カルボラン誘導体の合成とスピン状態2014

    • Author(s)
      風間達也・上辺将士・伊藤彰浩・田中一義
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学川内キャンパス・萩ホール
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] カルボラン含有芳香族アミンの合成と電子物性2014

    • Author(s)
      上辺将士・伊藤彰浩・田中一義
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学川内キャンパス・萩ホール
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] フェニレン架橋したテトラアザシクロファンダイマーの合成と電子物性2014

    • Author(s)
      大西亜維良・倉田亮平・伊藤彰浩・田中一義
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学川内キャンパス・萩ホール
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] 倉田亮平・伊藤彰浩・田中一義2014

    • Author(s)
      ヘキサベンゾコロネンからなるアザシクロファンの合成と電子物性
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学川内キャンパス・萩ホール
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] Macrocyclic Oligoarylamines as Versatile Hole and Spin-Transport Materials2014

    • Author(s)
      Akihiro Ito
    • Organizer
      International Conference on Synthetic Maetals (ICSM) 2014
    • Place of Presentation
      Turku, Finland
    • Year and Date
      2014-06-30 – 2014-07-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Preparation and Characterization of a Polymacrocyclic Arylamine Containing Localized Spins2014

    • Author(s)
      Ryohei Kurata, Daisuke Sakamaki, Akihiro Ito, and Kazuyoshi Tanaka
    • Organizer
      International Conference on Synthetic Maetals (ICSM) 2014
    • Place of Presentation
      Turku, Finland
    • Year and Date
      2014-06-30 – 2014-07-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Structural Change in Oxidized States of 9,10-Diaminoanthracenes and Their Electronic Structures2014

    • Author(s)
      Masashi Uebe, Akihiro Ito, and Kazuyoshi Tanaka
    • Organizer
      International Conference on Synthetic Maetals (ICSM) 2014
    • Place of Presentation
      Turku, Finland
    • Year and Date
      2014-06-30 – 2014-07-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] 特異な構造を有する芳香族アミン分子群の電荷輸送特性2013

    • Author(s)
      酒巻大輔・伊藤彰浩・田中一義・関修平
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学目白キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] ホウ素原子と窒素原子を含むアントラセン誘導体の光物性2013

    • Author(s)
      上辺将士・酒巻大輔・伊藤彰浩・田中一義
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学目白キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] 局在スピンを有する大環状芳香族アミンの合成と物性2013

    • Author(s)
      倉田亮平・酒巻大輔・伊藤彰浩・田中一義
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学目白キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] パイ共役ワイヤー部位と機能性部位を有する複合分子の合成と物性2012

    • Author(s)
      石川泰嗣・酒巻大輔・伊藤彰浩・笛野博之・和田恭雄・田中一義・田中彰治・阿部幸浩・佐藤万紀・小松陽子
    • Organizer
      分子科学討論会
    • Place of Presentation
      東京大学 本郷キャンパス
    • Year and Date
      2012-09-21
    • Related Report
      2012 Annual Research Report
  • [Remarks] 研究室ホームページ

    • URL

      http://www.moleng.kyoto-u.ac.jp/~moleng_03/index_J.html

    • Related Report
      2014 Annual Research Report
  • [Remarks]

    • URL

      http://moleng.kyoto-u.ac.jp/~moleng_03/index_j.html

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2012-04-24   Modified: 2019-07-29  

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