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NMR study on the internal structure of a quantum spin liquid state in the triangular lattice antiferromagnets

Research Project

Project/Area Number 24340082
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionKyoto University

Principal Investigator

MAEGAWA Satoru  京都大学, 人間・環境学研究科(研究院), 名誉教授 (40135489)

Co-Investigator(Kenkyū-buntansha) ITOU Tetsuaki  東京理科大学, 理学部, 准教授 (50402748)
OYAMADA Akira  京都大学, 大学院人間・環境学研究科, 助教 (60211835)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥19,760,000 (Direct Cost: ¥15,200,000、Indirect Cost: ¥4,560,000)
Fiscal Year 2014: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2012: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Keywordsスピン液体 / 三角格子 / 反強磁性体 / 核磁気共鳴 / フラストレーション / 量子スピン / 物性実験 / 磁性 / 量子スピン液体 / 有機物質 / 希土類 / 核スピン緩和 / 低温 / 低温物性
Outline of Final Research Achievements

We have performed NMR measurements on the organic triangular-lattice spin liquid system EtMe3Sb[Pd(dmit)2]2. The measurements were conducted on a single crystal at ultra-low temperatures and under applied pressures. We found that a slowly fluctuating electronic state is realized around the Mott boundary, which is situated around 5 kbar. This indicates that the charge degree of freedom and the randomness, which has been overlooked previously, play a vital role to realize the spin liquid state in EtMe3Sb[Pd(dmit)2]2.
We also discovered new rare-earth quantum-spin antiferromagnets on the triangular lattice, CeZn3P3 and YbCuGe. Our NMR measurements clarified that the magnetic diagram in CeZn3P3 is affected by the quantum spin fluctuation, and that in YbCuGe extremely slow spin fluctuation remains even below the ordering temperature. These results demonstrate that the quantum spin fluctuations are still important in the magnetically ordered state of the frustrated magnets.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (12 results)

All 2015 2014 2013 2012 Other

All Presentation (10 results) Remarks (2 results)

  • [Presentation] 量子スピン三角格子反強磁性体YbCuGeのスピンダイナミクス2015

    • Author(s)
      小山田明、前川覚、荒木幸治、加藤健一
    • Organizer
      日本物理学会 2015年第70回年次大会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      2015-03-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] 量子スピン三角格子反強磁性体YbCuGeの磁気秩序状態2014

    • Author(s)
      小山田明、前川覚、荒木幸治、加藤健一
    • Organizer
      日本物理学会 2014年秋季大会
    • Place of Presentation
      中部大学(愛知県春日井市)
    • Year and Date
      2014-09-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] 量子スピン液体物質EtMe3Sb[Pd(dmit)_2]_2の圧力下_<13>NMR2013

    • Author(s)
      渡辺恵里
    • Organizer
      日本物理学会 第68回年次大会
    • Place of Presentation
      広島大学(広島県)
    • Year and Date
      2013-03-28
    • Related Report
      2012 Annual Research Report
  • [Presentation] Spin liquid, superconductivity, and Mott transition observed in the triangular-lattice organic system X[Pd(dmit)_2]22013

    • Author(s)
      T. Itou
    • Organizer
      QS2C Theory Forum : International Symposium on"Strongly Correlated Quantum Science"
    • Place of Presentation
      東京大学(東京)
    • Year and Date
      2013-01-27
    • Related Report
      2012 Annual Research Report
  • [Presentation] NMR Study of Quantum Spin Liquid in an Organic Triangular Lattice Ant i f erromagnet EtMe3Sb[Pd (dmit)_2]_22012

    • Author(s)
      Satoru Maegawa
    • Organizer
      THE 19th INTERNATIONAL CONFERENCE ON MAGNETISM (ICM2012)
    • Place of Presentation
      Bexco, Busan (韓国)
    • Year and Date
      2012-07-09
    • Related Report
      2012 Annual Research Report
  • [Presentation] Quantum Spin Liquid State in the Triangular-Lattice Mott Insulator EtMe3Sb[Pd (dmit)2]2 Observed by ^<13>C-NMR2012

    • Author(s)
      T. Itou
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2012
    • Place of Presentation
      The Hyatt Regency Atlanta (アメリカ)
    • Year and Date
      2012-07-09
    • Related Report
      2012 Annual Research Report
  • [Presentation] Low energy magnetic excitation in the organic spin liquid material EtMe3Sb[Pd (dmit)2]2observed by 13c-NMR2012

    • Author(s)
      T. Itou
    • Organizer
      International Conference on Highly Frustrated Magnetism 2012
    • Place of Presentation
      McMaster University (カナダ)
    • Year and Date
      2012-06-06
    • Related Report
      2012 Annual Research Report
  • [Presentation] 量子スピン液体物質EtMe3Sb[Pd(dmit)2]2の圧力下13C-NMR II

    • Author(s)
      伊藤哲明,渡辺恵里,宮川和也,鹿野田一司,前川覚,久保和也,加藤礼三
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 4f電子系量子スピン三角格子反強磁性体CeZn3P3の磁気構造

    • Author(s)
      小山田明,村田瑞記、大前陽一,西山昌秀,伊藤哲明,前川覚,松田沙織,原克哉,落合明
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Ising型異方性を持つ三角格子反強磁性体YbCuGeの核磁気共鳴

    • Author(s)
      小山田明、前川覚、加藤健一
    • Organizer
      日本物理学会 2014年年次大会
    • Place of Presentation
      東海大学
    • Related Report
      2013 Annual Research Report
  • [Remarks] 前川研究室

    • URL

      http://nmr.jinkan.kyoto-u.ac.jp/maegawa-lab/

    • Related Report
      2013 Annual Research Report
  • [Remarks] 京都大学大学院人間・環境学研究科 大学院教員紹介 小山田明

    • URL

      http://www.h.kyoto-u.ac.jp/staff/341_oyamada_a_0_j.html

    • Related Report
      2013 Annual Research Report

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Published: 2012-04-24   Modified: 2020-05-15  

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