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Study on the deposition of functionalized membrane with high-molecular-weight radicals and ions during hydroicarbon plasma

Research Project

Project/Area Number 24340144
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Plasma science
Research InstitutionNagasaki University

Principal Investigator

SHINOHARA Masanori  長崎大学, 工学研究科, 助教 (80346931)

Co-Investigator(Renkei-kenkyūsha) MATSUDA Yoshinobu  長崎大学, 工学研究科, 准教授 (60199817)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥14,430,000 (Direct Cost: ¥11,100,000、Indirect Cost: ¥3,330,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2012: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Keywords炭化水素プラズマ / アモルファス炭素膜 / 高分子量のラジカル・イオン / 成膜 / 反応過程 / 赤外分光 / 付加反応 / 高次のラジカル・イオン / プラズマ-固体表面相互作用 / 赤外吸収分光 / 高分子量 / 炭素膜 / ベンゼン環 / 原料分子 / 赤外吸収分光法 / 堆積速度
Outline of Final Research Achievements

The amorphous carbon film deposition was investigated during plasma-enhanced chemical vapor deposition with a deuterated benzene as a source, by using in situ and real-time infrared absorption spectroscopy. A prominent peak attributed to the deuterated phenyl group was observed, indicating that the benzene ring structure is retained during the adsorption. The evolution of peaks observed during the plasma exposure suggested that the addition reaction occurs during the adsorption. The addition reaction occurs, even with applying negative bias to the substrate, while a lot of the benzene ring structures in the film were disrupted and the amount of alkane components increased, with the negative bias applied.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (35 results)

All 2015 2014 2013 2012

All Journal Article (12 results) (of which Peer Reviewed: 10 results,  Acknowledgement Compliant: 3 results,  Open Access: 3 results) Presentation (23 results) (of which Invited: 1 results)

  • [Journal Article] Infrared spectroscopic study on reactions of octadecyltrichlorosilane self-assembled monolayer with Plasmas2015

    • Author(s)
      Masanori Shinohara, Naoki Maruno, Yuta Yoshida, Yujiro Taniguchi, Kazuki Ito, Yamato Nakano, Yoshinobu Matsuda, Hiroshi Fujiyama
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 54 Issue: 1S Pages: 01AB04-01AB04

    • DOI

      10.7567/jjap.54.01ab04

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Infrared Absorption Spectroscopic Study on Reaction between Self-Assembled Monolayers and Atmospheric-Pressure Plasma2015

    • Author(s)
      Masanori Shinohara, Katsuhiro Amano, Naoki Maruno, Yuta Yoshida, Yoshinobu Matsuda and Hiroshi Fujiyama
    • Journal Title

      Journal of Spectroscopy

      Volume: 2015 Pages: 1-7

    • DOI

      10.1155/2015/417024

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] シリコン表面のSi-Hの結合の赤外分光解析2015

    • Author(s)
      篠原正典,木村康男,庭野道夫,松田良信,藤山 寛
    • Journal Title

      プラズマ・核融合学会誌

      Volume: 91

    • Related Report
      2014 Annual Research Report
    • Open Access
  • [Journal Article] Adsorption of hydrocarbon components generated in deuterated benzene plasma studied by in situ real-time infrared absorption spectroscopy2014

    • Author(s)
      Masanori Shinohara, Yujiro Taniguchi, Yuya Takaki, Yoshinobu Matsuda, Hiroshi Fujiyama
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 9 Pages: 096202-096202

    • DOI

      10.7567/jjap.53.096202

    • NAID

      210000144458

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Reactions of Surface Hydrogen on Amorphous Carbon Films with Hydrogen Plasma2014

    • Author(s)
      Masanori Shinohara, Taka-aki Kawakami, Ko-jiro Hara, Shohei Yagi, Yoshinobu Matsuda, Hiroshi Fujiyama
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 1 Pages: 10204-10204

    • DOI

      10.7567/jjap.53.010204

    • NAID

      210000143216

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of an in-situ infrared spectroscopic measurement of plasma-induced reactions in ethanol2014

    • Author(s)
      M. Shinohara, A. Fuakae, K. Amano, Y. Yoshida, Y. Matsuda, H. Fujiyama
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: Vol. 52, No.11 Issue: 11S Pages: 11NC06-11NC06

    • DOI

      10.7567/jjap.52.11nc06

    • NAID

      210000143109

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recent Trends of Plasma Engineering2014

    • Author(s)
      篠原 正典, 金 載浩
    • Journal Title

      IEEJ Transactions on Fundamentals and Materials

      Volume: 134 Issue: 1 Pages: 41-46

    • DOI

      10.1541/ieejfms.134.41

    • NAID

      130003382669

    • ISSN
      0385-4205, 1347-5533
    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of carbon sources on deposition process of amorphous carbon film with plasma enhanced chemical vapor deposition, investigated with infrared spectroscopy: benzene and naphthalene2014

    • Author(s)
      Shohei Yagi, Yujiro Taniguchi, Naoki Maruno, Masanori Shinohara, Yoshinobu Matsuda, Hiroshi Fujiyama
    • Journal Title

      Proceedoings of 8th International conference on reactive plasmas

      Volume: 1

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evolution of Hydride Components Generated by Hydrogen Plasma Irradiation of a Si(110) Surface Investigated With In Situ Infrared Absorption Spectroscopy in Multiple Internal Reflection Geometry2013

    • Author(s)
      M. Shinohara, Y. Takami, S. Takabayashi, A. Oda, Y. Matsuda, H. Fujiyama
    • Journal Title

      IEEE Trans. Plasma Sci.

      Volume: 41 Issue: 8 Pages: 1878-1883

    • DOI

      10.1109/tps.2013.2263850

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface modification of DLC film due to oxygen plasma exposure, observed by IR absorption spectroscopy in multipleinternal- reflection geometry2012

    • Author(s)
      M. Shinohara, Y. Takaki, Y. Takami, Y. Matuda, and H. Fujiyama
    • Journal Title

      IEEE Trans. of Plasma Science

      Volume: Vo l . 40, No. 10 Issue: 10 Pages: 2756-2761

    • DOI

      10.1109/tps.2012.2208766

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of the surface bond states in as-deposited DLC films on the incorporation of nitrogen and oxygen atoms into the DLC films2012

    • Author(s)
      Y. Nitta, K. Okamoto, T. Nakatani, M. Shinohara
    • Journal Title

      IEEE Transactions of Plasma Science

      Volume: 40 Issue: 8 Pages: 2073-2078

    • DOI

      10.1109/tps.2012.2203613

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 多重内部反射赤外吸収分光法を用いたプラズマが誘起する表面反応の解析~気相プラズマから液中プラズマ~2012

    • Author(s)
      篠原正典,松田良信,藤山 寛
    • Journal Title

      化学工業

      Volume: 63 Pages: 942-946

    • Related Report
      2012 Annual Research Report
  • [Presentation] チオール基を有する自己組織化単分子膜とプラズマの反応の赤外分光解析2014

    • Author(s)
      中野大和, 丸野尚紀, 谷口雄二郎, 吉田裕太, 伊東和樹, 篠原正典, 松田良信, 藤山寛
    • Organizer
      応用物理学会九州支部学術講演会
    • Place of Presentation
      大分大学 (大分市)
    • Year and Date
      2014-12-06 – 2014-12-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] アミノ基を有する自己組織化単分子膜とプラズマの反応の赤外分光2014

    • Author(s)
      丸野尚紀, 谷口雄二郎, 吉田裕太, 中野大和, 伊東和樹, 篠原正典, 松田良信, 藤山寛
    • Organizer
      応用物理学会九州支部学術講演会
    • Place of Presentation
      大分大学 (大分市)
    • Year and Date
      2014-12-06 – 2014-12-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] ベンゼンを用いたプラズマ化学的気相堆積過程の赤外吸収分光解析2014

    • Author(s)
      伊東 和樹, 谷口 雄二郎, 篠原 正典, 松田 良信, 藤山 寛
    • Organizer
      応用物理学会九州支部学術講演会
    • Place of Presentation
      大分大学 (大分市)
    • Year and Date
      2014-12-06 – 2014-12-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] Infrared Spectroscopic study on interaction between plasma and solid surface2014

    • Author(s)
      Masanori Shinohara, Yuta Yoshida, Naoki Maruno, Yujiro Taniguchi, Kazuki Ito, Yamato Nakano, Yoshinobu Matsuda and Hiroshi Fujiyama
    • Organizer
      Plasma Conference
    • Place of Presentation
      Toki Messe, Niigata, Japan
    • Year and Date
      2014-11-18 – 2014-11-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] 炭化水素プラズマによる膜形成初期過程の赤外分光解析2014

    • Author(s)
      篠原正典,谷口雄二郎,伊東和樹,丸野尚紀,中野大和,吉田裕太,松田良信,藤山 寛
    • Organizer
      表面科学学術講演会
    • Place of Presentation
      くにびきメッセ,(松江市)
    • Year and Date
      2014-11-06 – 2014-11-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] Consideration of Adsorption Process of Benzene Plasma with Isotope Effect2014

    • Author(s)
      M. Shinohara, K. Ito, Y. Taniguchi, Y. Matsuda and H. Fujiyam
    • Organizer
      The 7th International Symposium on Surface Science
    • Place of Presentation
      Kunibiki Messe, Matsue, Shimane, Japan
    • Year and Date
      2014-11-02 – 2014-11-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] 炭化水素プラズマによる膜堆積過程の赤外分光反応解析2014

    • Author(s)
      篠原正典,高木雄也,谷口雄二郎,伊東和樹,丸野尚紀,吉田裕太,中野大和,松田良信,藤山 寛
    • Organizer
      電気学会プラズマ研究会
    • Place of Presentation
      大阪府立大学 (羽曳野市)
    • Year and Date
      2014-09-08 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] アモルファス炭素膜とプラズマの反応の赤外分光解析2014

    • Author(s)
      篠原 正典,谷口 雄二郎,丸野 尚紀,松田 良信,藤山 寛
    • Organizer
      電気学会A部門大会
    • Place of Presentation
      信州大学 (長野市)
    • Year and Date
      2014-08-21 – 2014-08-22
    • Related Report
      2014 Annual Research Report
  • [Presentation] Infrared Absorption Spectroscopic Study on Deposition Process Induced by Benzene Plasma Exposure2014

    • Author(s)
      Masanori Shinohara, Yujiro Taniguchi, Kazuki Ito, Naoki Maruno, Yoshinobu Matsuda, and Hiroshi Fujiyama
    • Organizer
      International Conference on Microelectronics and Plasma Technology 2014
    • Place of Presentation
      Gunsan, Korea
    • Year and Date
      2014-07-08 – 2014-07-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Hydrogen Plasma Induced Hydrogen Insertion into Si Subsurface, Investigated with Infrared Absorption Spectroscopy2014

    • Author(s)
      Masanori Shinohara, Naoki Maruno, Yoshinobu Matsuda, and Hiroshi Fujiyama
    • Organizer
      International Conference on Microelectronics and Plasma Technology
    • Place of Presentation
      Gunsan, Korea
    • Year and Date
      2014-07-08 – 2014-07-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] プラズマ-シリコン表面相互作用で誘起される欠陥生成メカニズムの解明,Ⅳ族元素を基盤とした膜とプラズマとの反応解析によるプラズマ応用プロセスの最適化2014

    • Author(s)
      篠原正典,丸野 尚紀,吉田 裕太,堺 廣治,谷口 雄二郎,伊東 和樹,中野 大和,松田 良信
    • Organizer
      第18回 応用物理学会 プラズマエレクトロニクス分科会 プラズマ新領域研究会
    • Place of Presentation
      名古屋大学東山キャンパス (名古屋市)
    • Year and Date
      2014-06-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Diagnostics for Plasma-Induced Surface Reactions with Infrared Spectroscopy2013

    • Author(s)
      Masanori Shinohara, Yoshinobu Matsuda, and Hiroshi Fujiyama
    • Organizer
      5rd International Workshop on Plasma Scientech for All Something (June 21-22, 2013, )
    • Place of Presentation
      東京工業大学 (東京都目黒区))
    • Related Report
      2013 Annual Research Report
  • [Presentation] Infrared Spectroscopic Study on Reaction Process during Plasma Enhanced Chemical Vapor Deposition with Hydrocarbon Molecules as Source Gases2013

    • Author(s)
      S. Yagi, Y. Takaki, Y. Taniguchi, M. Shinohara, Y.Matsuda and H. Fujiyama
    • Organizer
      the 12th Joint Symposium of Jeju National University and Nagasaki University on Science and Technology
    • Place of Presentation
      ラマダホテル済州 (韓国済州市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] An infrared spectroscopic study on deposition process of amorphous carbon films using Benzene as a source molecule2013

    • Author(s)
      Y. Taniguchi, M. Shinohara, Y. Matsuda, H. Fujiyama
    • Organizer
      The 12th Asia Pacific Physics Conference
    • Place of Presentation
      幕張メッセ (千葉県千葉市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Deposition and surface modification process of amorphous carbon film, investigated with infrared spectroscopy2013

    • Author(s)
      Yujiro Taniguchi, Naoki Maruno, Shouhei Yagi, Masanori Shinohara, Yoshinobu Matsuda and Hiroshi Fujiyama
    • Organizer
      The 9th Asian-European International Conference on Plasma Surface Engineering
    • Place of Presentation
      ラマダホテル済州 (韓国済州市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Infrared spectroscopy of reactions induced by plasma2013

    • Author(s)
      Masanori Shinohara, Shohei Yagi, Yujiro Taniguchi, Naoki Maruno, Yuta Yoshida, Yoshinobu Matsuda, Hiroshi Fujiyama
    • Organizer
      原子分子データのフォーラム
    • Place of Presentation
      核融合科学研究所 (岐阜県土岐市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] ベンゼンを原料として用いたアモルファス炭素膜の堆積過程の赤外分光解析2013

    • Author(s)
      谷口  雄二郎,八木 翔平,篠原 正典,松田 良信,藤山 寛(
    • Organizer
      電気学会プラズマ研究会  9月5-7日
    • Place of Presentation
      長崎大学 (長崎県長崎市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ベンゼンを原料としたアモルファス状炭素膜の成膜反応の赤外分光解析2013

    • Author(s)
      高木雄也,高見佳生,津村高成,八木翔平,谷口雄二郎,丸野尚紀,篠原正典,松田良信,藤山寛
    • Organizer
      応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Plasma exposure effects on the behavior of hydrogen on amorphous carbon film2012

    • Author(s)
      Y. Takaki, S. Yagi, Y. Takami, T. Tsumura, M. Shinohara, Y. Matsuda, H. Fujiyama
    • Organizer
      Asia Pacific Conference on Plasma Science and Technology
    • Place of Presentation
      京都大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] エチレンプラズマを使ったアモルファス炭素膜堆積反応の赤外分光解析2012

    • Author(s)
      高木雄也,高見佳生,八木翔平,津村高成,篠原正典,松田良信,藤山寛
    • Organizer
      応用物理学会秋季学術講演会
    • Place of Presentation
      愛媛大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 赤外吸収分光法計測を用いたプラズマが誘起する表面反応の解析・解明2012

    • Author(s)
      原正典,高木雄也,高見佳生,深江陽大,天野勝裕,八木翔平,津村高成,松田良信,藤山寛
    • Organizer
      九州山口プラズマ研究会
    • Place of Presentation
      由布院倶楽部
    • Related Report
      2012 Annual Research Report
  • [Presentation] エチレンを原料としたプラズマ化学気相堆積の反応計測2012

    • Author(s)
      高木雄也、高見佳生、篠原正典、松田良信、藤山寛
    • Organizer
      表面科学会全国大会
    • Place of Presentation
      東北大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 炭化水素を原料としたプラズマ化学気相堆積の赤外分光解析2012

    • Author(s)
      高木雄也,高見佳生,八木翔平,津村高成,篠原正典,松田良信,藤山寛
    • Organizer
      プラズマ・核融合学会山口九州沖縄支部 第16回支部会
    • Place of Presentation
      九州大学
    • Related Report
      2012 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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