Development of NMR spectroscopy for mass-selected molecular ions
Project/Area Number |
24350009
|
Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Partial Multi-year Fund |
Section | 一般 |
Research Field |
Physical chemistry
|
Research Institution | Kobe University |
Principal Investigator |
Fuke Kiyokazu 神戸大学, 理学(系)研究科(研究院), 名誉教授 (00111766)
|
Co-Investigator(Kenkyū-buntansha) |
Ohshima Yasuhiro 東京工業大学, 大学院理学研究科, 教授 (60213708)
|
Project Period (FY) |
2012-04-01 – 2016-03-31
|
Project Status |
Completed (Fiscal Year 2015)
|
Budget Amount *help |
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2014: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2013: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2012: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
|
Keywords | 質量分析 / 気相イオン / 核磁気共鳴 / 極低温冷却 / 電子衝撃イオン化 / 光電子 |
Outline of Final Research Achievements |
The principal aim of this research project is the development of a new gas-phase nuclear magnetic resonance (NMR) detection method for mass-selected molecular ions, which we proposed recently. Since this method is based on a Stern-Gerlach type experiment by observing the nuclear spin states of the ions with different time-of-flights, ultra cold ions with less than 5 mK are required to detect a very weak nuclear spin polarization. We improve the apparatus to generate and manipulate very slow and cooled ions with a kinetic energy of less than 1 meV. We also develop a new ion source based on the photoionization of supersonically cooled molecules coupled with a multi stage decelerator. To cool the ions further down to mK order in a NMR cell, we invent a bunching ion optics using a velocity compensation method. Using this apparatus, we are conducting a proof of principle experiment and trying to measure the first NMR spectrum of the gas-phase closed shell molecular ions.
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Report
(5 results)
Research Products
(14 results)