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Creation of self-assembled paramagnetic fullerene and extending its functionality

Research Project

Project/Area Number 24350019
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Organic chemistry
Research InstitutionTokyo Gakugei University (2013-2014)
University of Tsukuba (2012)

Principal Investigator

AKASAKA Takeshi  東京学芸大学, 教育学部, 客員教授 (60089810)

Co-Investigator(Kenkyū-buntansha) TSUCHIYA Takahiro  筑波大学, 数理物質系, 講師 (10375412)
MIZOROGI Naomi  筑波大学, 生命領域学際研究センター, 研究員 (60462199)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000)
Fiscal Year 2014: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2012: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Keywordsフラーレン / 金属内包フラーレン / 内包フラーレン / 磁性内包フラーレン / 磁性金属内包フラーレン / ナノロッド / 薄膜 / 自己組織化
Outline of Final Research Achievements

Research into the synthesis, characterization, and functionalization of compounds with π-electron systems, as typified by endofullerenes and metallofullerenes, is showing steady progress, and the momentum of this area is rising on new evolution. Through the investigation on the active nanocarbons, we focused on the unique characteristics of paramagnetic endohedral metallofullerenes that give functionalized molecules a diverse range of structural and functional variations, as we attempt to construct highly elaborated π-systems with more sophisticated and complex orders and functionality.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (67 results)

All 2015 2014 2013 2012 Other

All Journal Article (42 results) (of which Peer Reviewed: 42 results,  Acknowledgement Compliant: 4 results) Presentation (17 results) (of which Invited: 9 results) Book (5 results) Remarks (3 results)

  • [Journal Article] Hiding and Recovering Electrons in a Dimetallic Endohedral Fullerene : Air-Stable Products from Radical Additions2015

    • Author(s)
      M. Yamada, H. Kurihara, M. Suzuki, M. Saito, Z. Slanina, F. Uhlik, T. Aizawa, T. Kato, M.M. Olmstead, A.L. Balch, Y. Maeda, S. Nagase, X. Lu, and T. Akasaka
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 137 Issue: 1 Pages: 232-238

    • DOI

      10.1021/ja509956y

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regioselective Cage Opening of La_2@D_2(10611)-C_<72> with 5,6-Diphenyl-3-(2-pyridyl)-1,2,4-triazine2015

    • Author(s)
      M. Yamada, Y. Muto, H. Kurihara, Z. Slanina, M. Suzuki, Y. Maeda, Y. Rubin, M.M. Olmstead, A.L. Balch, S. Nagase, X. Lu, and T. Akasak
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 54 Issue: 7 Pages: 2232-2235

    • DOI

      10.1002/anie.201410012

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In-Depth Understanding of the Chemical Properties of Rarely Explored Carbide Cluster Metallofullerenes: A Case Study of Sc2C2@C3v(8)-C82 that Reveals as General Rule2015

    • Author(s)
      W. Cai, M. Chen, L. Bao, Y. Xie, T. Akasaka, X. Lu
    • Journal Title

      Chem. Eur. J.

      Volume: 21 Issue: 8 Pages: 3449-3454

    • DOI

      10.1002/chem.201405493

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Tuning intramolecular electron and energy transfer processes in novel conjugates of La2@C80 and electron accepting subphthalocyanines2015

    • Author(s)
      L. Feng, M. Rudolf, O. Trukhina, Z. Slanina, F. Uhlik, X. Lu, T. Torres, D. M. Guldi, T. Akasaka
    • Journal Title

      Chem. Commun.

      Volume: 51 Issue: 2 Pages: 330-333

    • DOI

      10.1039/c4cc08072f

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Regioselective Benzyl Radical Addition to an Open-Shell Cluster Metallofullerene. Crystallographic Studies of Cocrystallized Sc_3C_2@Ih-C_<80> and Its Singly Bonded Derivativ2014

    • Author(s)
      H. Fang, H. Cong, M. Suzuki, L. Bao, B. Yu, Y. Xie, N. Mizorogi, M.M. Olmstead, A.L. Balch, S. Nagase, T. Akasaka, and X. Lu
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Issue: 29 Pages: 10534-10540

    • DOI

      10.1021/ja505858y

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sc_2C_<66> Revised : An Endohedral Fullerene with Scandium Ions Nestled within Two Unsaturated Linear Triquinanes2014

    • Author(s)
      M. Yamada, H. Kurihara, M. Suzuki, J.-D. Guo, M. Waelchli, M.M. Olmstead, A.L. Balch, S. Nagase, Y. Maeda, T. Hasegawa, X. Lu, and T. Akasaka
    • Journal Title

      J. Am. Chem, Soc.

      Volume: 136 Issue: 21 Pages: 7611-7614

    • DOI

      10.1021/ja5035649

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Partial Charge Transfer in the Shortest Possible Metallofullerene Peapod, La@C_<82>・[11]Cycloparaphenylene2014

    • Author(s)
      T. Iwamoto, Z. Slanina, N. Mizorogi, J.-D. Guo, T. Akasaka, S. Nagase, H. Takaya, N. Yasuda, T. Kato, and S. Yamagao
    • Journal Title

      Chem. Eur. J.

      Volume: 20 Issue: 44 Pages: 14403-14409

    • DOI

      10.1002/chem.201403879

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Isolation and Characterization of [5,6]-Pyrrolidino-Sc_3N@Ih-C_<80> Diastereomers2014

    • Author(s)
      Y. Maeda, M. Kimura, C. Ueda, M. Yamada, T. Kikuchi, M. Suzuki, W.-W. Wang, N. Mizorogi, N. Karousis, N. Tagmatarchis, T. Hasegawa, M.M. Olmstead, A.L. Balch, S. Nagase, and T. Akasaka
    • Journal Title

      Chem. Commun.

      Volume: 50 Issue: 83 Pages: 12552-12555

    • DOI

      10.1039/c4cc04946b

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regioselective Synthesis and Molecular Structure of the First Derivative of Praseodymium-Containing Metallofullerenes2014

    • Author(s)
      Q. Zhou, H. Li, Y. Lian, M. Suzuki, L. Bao, W. Cai, W.-W. Wang, S. Nagase, X. Lu, and T. Akasaka
    • Journal Title

      Chem. Commun.

      Volume: 50 Issue: 69 Pages: 9876-9878

    • DOI

      10.1039/c4cc02949f

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal Reactions of Fullerenes with Cyclic Organosilicon and Organogermanium Compounds: Silylation and Germylation of C60 and C702014

    • Author(s)
      M. Kako, D. Inaba, K. Minami, R. Iida, T. Nakahodo, T. Akasaka
    • Journal Title

      Heteroatom Chem.

      Volume: 25 Issue: 6 Pages: 584-591

    • DOI

      10.1002/hc.21230

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Chemical Properties of Divalent Metallofullerenes Yb@D3h(1)-C74 and Yb@C2(13)-C842014

    • Author(s)
      J. Ruan, Y. Xie, W. Cai, Z. Slanina, N. Mizorogi, S. Nagase, T. Akasaka, X. Lu
    • Journal Title

      Fulleren. Nanotub. Carb. Nanostruct.

      Volume: 22 Issue: 1-3 Pages: 138-146

    • DOI

      10.1080/1536383x.2013.794344

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Recent Progress in the Chemistry of Endohedral Metallofullere2014

    • Author(s)
      X. Lu, L. Bao, T. Akasaka, and S. Nagase
    • Journal Title

      Chem. Commun. (Feature Article)

      Volume: 50 Issue: 94 Pages: 14701-14715

    • DOI

      10.1039/c4cc05164e

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Improbable Monometallic Cluster Entrapped in a Popular Fullerene Cage: YCN@Cs(6)-C822013

    • Author(s)
      Yang, S.; Chen, C.; Liu, F.; Xie, Y.; Li, F.; Jiao, M.; Suzuki, M.; Wei, T.; Wang, S.; Chen, Z.; Lu, X.; Akasaka, T.
    • Journal Title

      Scientific Reports

      Volume: 3 Pages: 1487-1492

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Structure and Chemical Property of a Divalent Metallofullerene Yb@C2(13)-C842013

    • Author(s)
      Zhang, W.; Suzuki, M.; Xie, Y.; Bao, L.; Cai, W.; Slanina, Z.; Nagase, S.; Xu, M.; Akasaka, T.; Lu
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 135 Issue: 34 Pages: 12730-12735

    • DOI

      10.1021/ja405223t

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Metallofullerene Electron Donor that Powers an Efficient Spin Flip in a Linear Electron Donor Acceptor Conjugate2013

    • Author(s)
      Rudolf, M.; Feng, L.; Slanina, Z.; Akasaka, T.; Nagase, S.; Guldi, D.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 135 Issue: 30 Pages: 11165-11174

    • DOI

      10.1021/ja403763e

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanistic Study of the Diels-Alder Reaction of Paramagnetic Endohedral Metallofullerene: Reaction of La@C82 with 1,2,3,4,5-Pentamethylcyclopentadiene2013

    • Author(s)
      Sato, S.; Maeda, Y.; Guo, J. -D.; Yamada, M.; Mizorogi, N.; Nagase, S.; Akasaka, T.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 135 Issue: 15 Pages: 5582-5587

    • DOI

      10.1021/ja309763f

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Regioselective Addition of Admantylidene Carbene to Yb@C2v(3)-C80 Affords the First Derivative of Divalent Metallofullerenes2013

    • Author(s)
      Xie, Y.; Suzuki, M.; Cai, W.; Mizorogi, N.; Nagase, S.; Akasaka, T.; Lu, X.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 52 Issue: 19 Pages: 5142-5145

    • DOI

      10.1002/anie.201210164

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intramolecular versus Intermolecular Electronic Interactions between [5,6]-open and [6,6]-closed C60 Adducts with exTTF2013

    • Author(s)
      Takano, Y.; Schubert, C.; Mizorogi, N.; Feng, L.; Iwano, A.; Katayama, M.; Herranz, M. A.; Guldi, D.; Martin, N.; Nagase, S.; Akasaka, T.
    • Journal Title

      Chem. Sci.

      Volume: 4 Issue: 8 Pages: 3166-3171

    • DOI

      10.1039/c3sc00004d

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical and Magnetic Properties of a Surface-grafted Novel Endohedral Metallofullerene Derivative2013

    • Author(s)
      Crivillers, N.; Takano, Y.; Matsumoto, Y.; Casado-Montenegro, J.; Mas-Torrent, M.; Rovira, C.; Akasaka, T.; Veciana, J.
    • Journal Title

      Chem. Commun.

      Volume: 49 Issue: 74 Pages: 8145-8147

    • DOI

      10.1039/c3cc43578d

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] X-ray observation of a helium atom and placing a nitrogen atom inside He@C_60 and He@C_702013

    • Author(s)
      森中裕太
    • Journal Title

      Nature Communications

      Volume: 4 Issue: 1 Pages: 1554-1554

    • DOI

      10.1038/ncomms2574

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Application of MCD Spectroscopy and TD-DFT to Endohedral Metallofullerenes for Characterization of Their Electronic Transitions2013

    • Author(s)
      Yamada, M.; Slanina, Z.; Mizorogi, N.; Muranaka, A.; Maeda, Y.; Nagase, S.; Akasaka, T.; Kobayashi, N.
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 15 Issue: 10 Pages: 3593-3601

    • DOI

      10.1039/c3cp44096f

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Coordinative Interactions between Porphyrins and C60, La@C82, and La2@C802013

    • Author(s)
      Tsuchiya, T.; Rudolf, M.; Wolfrum, S.; Radhakrishnan, S. G.; Aoyama, R.; Yokosawa, Y.; Oshima, A.; Akasaka, T.; Nagase, S.; Guldi, D. M.
    • Journal Title

      Chem. Eur. J.

      Volume: 19 Issue: 2 Pages: 558-565

    • DOI

      10.1002/chem.201202661

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mapping the Metal Positions inside Spherical C80 Cages: Crystallographic and Theoretical studies of Ce2@D5h-C80 and Ce2@Ih-C802013

    • Author(s)
      Feng, L.; Suzuki, M.; Mizorogi, N.; Xing, L.; Yamada, M.; Akasaka, T.; Nagase, S.
    • Journal Title

      Chem. Eur. J.

      Volume: 19 Issue: 3 Pages: 988-993

    • DOI

      10.1002/chem.201202341

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Endohedral Metallofullerene as a Pure Electron Donor: Intramolecular Electron Transfer in Donor-Acceptor Conjugates of La2@C80 and 11,11,12,12-tetracyano-9,10-anthra-p-quinodimethane (TCAQ),2012

    • Author(s)
      Takano, Y.; Obuchi, S.; Mizorogi, N.; Garcia, R.; Herranz, M. A.; Rudolf, M.; Guldi, D. M.; Martin, N.; Nagase, S.; Akasaka, T
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 47 Pages: 19401-19408

    • DOI

      10.1021/ja307341g

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single Crystal X-ray Diffraction Study of Three Yb@C_<82> Isomers Cocrystallized with Ni^<II>(octaethylporphyrin)2012

    • Author(s)
      M. Suzuki, Z. Slanina, N. Mizorogi, X. Lu, S. Nagase, M. M. Olmstead, A. L. Balch, T. Akasaka
    • Journal Title

      J. Am. Chem. Soe

      Volume: 134 Issue: 45 Pages: 18772-18778

    • DOI

      10.1021/ja308706d

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Analysis of Functionalization Degree of Single-Walled Carbon Nanotubes Having Various Substituents2012

    • Author(s)
      Y. Maeda, K.Saito, N. Akanlatsu, Y. Chiba, S. Ohno, Y. Okui, M. Yamada, T. Hasegawa, M. Kako, T. Akasaka
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 43 Pages: 18101-18108

    • DOI

      10.1021/ja308969p

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stabilizing Ion and Radical Ion Pair States in a Paramagnetic Endohedral Metallofullerene and aπ-Extended Tetrathiafulvalene2012

    • Author(s)
      Y. Takano, S. Obuchi, N. Mizorogi, R. Garcia, M. A. Herranz, M. Rudolf, S. Wolfrum, D. M. Guldi, N. Martin,.S. Nagase, T. Akasaka
    • Journal Title

      J. Am. Chem

      Volume: 134 Issue: 39 Pages: 16103-16106

    • DOI

      10.1021/ja3055386

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of a Silylene-Bridged Endohedral Metallofullerene Lu_ 3N@J_h-C_<80>2012

    • Author(s)
      K.Sato, M. Kako, M. Suzuki, N. Mizorogi, T. Tsuchiya, M. Olmstead, A. Balch, T, Akasaka, S., Nagasaki
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 38 Pages: 16033-16039

    • DOI

      10.1021/ja3073929

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exceptional Chemical Properties of Sc@C_<2v>(9)-C_<82> Probed with Adamantylidine Carbene2012

    • Author(s)
      M. Hachiya, H. Nikawa, N. Mizorogi, T. Tsuchiya, X. Lu, T. Akasaka
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 37 Pages: 15550-15555

    • DOI

      10.1021/ja306890x

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Paradigmatic Change - Linking Fullerenes to Electron Acceptors2012

    • Author(s)
      L. Feng, M. Rudolf, S. Wolfrum, A. Troeger, Z. Slanina, T. Akasaka, S. Akasaka, S Nagase, N. Martin, T. Ameri, C. Brabec, D. Guldi
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 29 Pages: 12190-12197

    • DOI

      10.1021/ja3039695

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tunable Charge-transport Property of Ih-C80 Endohedral Metallofullerenes : Investigation of La2@C80, Sc3N@C80, and Sc3C2@C80.2012

    • Author(s)
      Satoru Sato
    • Journal Title

      Journal of American Chemical Society

      Volume: 134 Issue: 28 Pages: 11681-11686

    • DOI

      10.1021/ja303660g

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Unexpected Formation of a Sc_3C_2@C_<80> Bisfulleroid Derivative2012

    • Author(s)
      H. Kurihara, Y. Iiduka, Y. Rubin, M. Waelchli, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nagase, T. kasaka
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 9 Pages: 4092-4095

    • DOI

      10.1021/ja300279x

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemical Understanding of Carbide Cluster Metallofullerenes : A Case Study on S_<c2>C_2@C_<2v>(5)-C_<80> with Complete X Ray Crystallographic Characterizations2012

    • Author(s)
      H. Kurihara, X. Lu, Y. Iiduka, H. Nikawa, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nagase, T. Akasaka
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 134 Pages: 3139-3144

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Long-Believed S_<c2>@C_<2v>(17)-C_<84> is Actually S_<c2>C_2@C_<2v>(9)-C_<82>. Unambiguous Structure Assignment and Chemical Functionalization2012

    • Author(s)
      X. Lu, K. Nakajima, Y. Iiduka, H. Nikawa, T. Tsuchiya, N. Mizorogi, Z. Slanina, S. Nagase, T. Akasaka
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 51 Issue: 24 Pages: 5889-5892

    • DOI

      10.1002/anie.201201325

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Co-Crystal Composed of the Paramagnetic Endohedral Metallofullerene La@C_<82> and Nickel Porphyrin with High Electron Mobility2012

    • Author(s)
      Satoru Sato
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 51 Issue: 7 Pages: 1589-1591

    • DOI

      10.1002/anie.201106912

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sc_2@C_<3v>(8)-C_<82> vs. Sc_2C_2@C_<3v>(8)-C_<82>: Drastic Effect of C_2 Capture on the Redox Properties of Scandium Metallofullerenes2012

    • Author(s)
      H. Kurihara, X. Lu, Y. Iiduka, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nagase, T. Akasaka
    • Journal Title

      Chem. Commmun

      Volume: 48 Issue: 9 Pages: 1290-1292

    • DOI

      10.1039/c2cc16422a

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Where Does the Metal Cation Stay in Gd@C_<2v>(9)-C_<82> A Single-Crystal X-Ray Diffraction Study2012

    • Author(s)
      M. Suzuki, X. Lu, S. Sato, H. Nikawa, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nagase, T. Akasaka
    • Journal Title

      Inorg. Chem.

      Volume: 51 Issue: 9 Pages: 5270-5273

    • DOI

      10.1021/ic300186y

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] X-Ray Structures of Sc2C2@C2n (n=40, 41, 42): In-Depth Understanding of the Core-Shell Interplay in Carbide Cluster Metallofullerenes2012

    • Author(s)
      H. Kurihara, X. Lu, Y. Iiduka, H. Nikawa, M. Hachiya, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nlaga.sg, T. kasaka
    • Journal Title

      Inorg. Chem

      Volume: 51 Issue: 1 Pages: 746-750

    • DOI

      10.1021/ic202438u

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron transport through Single Endohedral Ce@C_82 Metallofullerenes2012

    • Author(s)
      Satoshi Kaneko, Lu Wang, Guangfu Luo, Ling Lu, Shigeru Nagase, Satoru Sato, Michio Yamada, Zdenek Slanina, Takeshi Akasaka, and Manabu Kiguchi
    • Journal Title

      Physical Review B

      Volume: 86 Issue: 15

    • DOI

      10.1103/physrevb.86.155406

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stability Computations for Isomers of La@C_n(n = 72, 74, 76)2012

    • Author(s)
      Z. Slanina, F. Uhlik, S.-L. Lee, L. Adamowicz, T. Akasaka, S. Nagase
    • Journal Title

      Molecules

      Volume: 17 Issue: 11 Pages: 13146-13156

    • DOI

      10.3390/molecules171113146

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bis-Silylation of Lu_3N@I_h-C_<80> : Considerable Variation in the Electronic Structures2012

    • Author(s)
      K. Sato, M. Kako, N. Mizorogi, T. Tsuchiya, T. Akasaka
    • Journal Title

      Org. Lett

      Volume: 15 Issue: 23 Pages: 5908-5911

    • DOI

      10.1021/ol302832k

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Diameter-Selective Purification of Carbon Nanotubes by Microwave-Assisted Acid Processing2012

    • Author(s)
      H. Qiu, Y. Maeda, T. Akasaka, J. Yang
    • Journal Title

      Sep. Purif. Technol.

      Volume: 96 Pages: 182-186

    • DOI

      10.1016/j.seppur.2012.06.001

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] New Vistas in Fullerene World: Endohedral Metallofullerenes2015

    • Author(s)
      赤阪 健
    • Organizer
      青島大学 School Lecture
    • Place of Presentation
      School of Material Science and Engineering, Qingdao University, Qingdao, China
    • Year and Date
      2015-01-09
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] New Vistas in Fullerene World: Endohedral Metallofullerenes2014

    • Author(s)
      赤阪 健
    • Organizer
      エルランゲン大学 Department Lecture
    • Place of Presentation
      Department of Chemistry and Pharmacy, Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universitaet Erlangen-Nuernberg, Erlangen, Germany
    • Year and Date
      2014-12-09
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] New Vistas in Fullerene World: Endohedral Metallofullerenes2014

    • Author(s)
      赤阪 健
    • Organizer
      長春化学研究所 Institute Lecture
    • Place of Presentation
      Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China
    • Year and Date
      2014-07-06
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] New Vistas in Fullerene World: Endohedral Metallofullerenes2014

    • Author(s)
      赤阪 健
    • Organizer
      蘇州大学 School Lecture
    • Place of Presentation
      School of Material Science and Engineering, Soochow University, Soochow, China
    • Year and Date
      2014-06-16
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] フラーレンを鍵物質とする高次π空間の創発と機能開拓2013

    • Author(s)
      赤阪 健
    • Organizer
      科研費新学術領域研究「融合マテジアル」第6回公開シンポジウム
    • Place of Presentation
      TKPガーデンシティ仙台,仙台市(招待講演)
    • Year and Date
      2013-01-28
    • Related Report
      2012 Annual Research Report
  • [Presentation] New Vistas in Fullerene Endohedrals2013

    • Author(s)
      T. Akasaka
    • Organizer
      1st International Symposium on Nanocarbons -- Fullerenes, Endofullerenes, Carbon Nanotubes and Carbon Nanostructures (ISNC2013)
    • Place of Presentation
      University of Science and Technology of China, Hefei, China
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] New Vistas in Fullerene Endohedrals2013

    • Author(s)
      T. Akasaka
    • Organizer
      The 3rd Symposium on Carbon Nanoforms
    • Place of Presentation
      IMDEA-Nanoscience, Madrid, Spain
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] フラーレンを鍵物質とする高次π空間の創発と機能開拓2012

    • Author(s)
      赤阪 健
    • Organizer
      第6回有機π電子系シンポジウム
    • Place of Presentation
      道後温泉 茶波瑠、松山市(招待講演)
    • Year and Date
      2012-12-14
    • Related Report
      2012 Annual Research Report
  • [Presentation] New Vistas in Chemistry of Nanocarbons : Organic Nanomaterials Based on Endohedral Metallofullerenes2012

    • Author(s)
      Takeshi Akasaka
    • Organizer
      The Symposium on Material Chemistry in Heilongjiang University
    • Place of Presentation
      Harbin, China(招待講演)
    • Year and Date
      2012-09-14
    • Related Report
      2012 Annual Research Report
  • [Presentation] New Vistas in fullerene Endohedrals2012

    • Author(s)
      Takeshi Akasaka
    • Organizer
      XXIst International Symposium on Jahn-Teller Effect
    • Place of Presentation
      Univ. of Tsukuba, Japan(招待講演)
    • Year and Date
      2012-08-26
    • Related Report
      2012 Annual Research Report
  • [Presentation] New Vistas in Chemistry of Nanocarbons : Organic Nanomaterials Based on Endohedral Metallofullerenes2012

    • Author(s)
      赤阪 健
    • Organizer
      岡山大学異分野研究連携コア講演会
    • Place of Presentation
      岡山大学、岡山(招待講演)
    • Year and Date
      2012-08-07
    • Related Report
      2012 Annual Research Report
  • [Presentation] New Vistas in Chemistry of Synthetic Carbon Allotropes : Organic Nanomaterials Based on Endohedral Metallofullerenes2012

    • Author(s)
      Takeshi Akasaka
    • Organizer
      9th International Conference on Nanosciences & Nanotechnologies
    • Place of Presentation
      Thessaloniki, Greece(招待講演)
    • Year and Date
      2012-07-03
    • Related Report
      2012 Annual Research Report
  • [Presentation] New Vistas in Fullerene Chemistry : Oraganosulfur Compounds Expand the Performance of Carbon Nanomaterials2012

    • Author(s)
      Takeshi Akasaka
    • Organizer
      25th International Symposium Oil the Organic Chemistry of Sulfur
    • Place of Presentation
      Czestochowa, Poland(招待講演)
    • Year and Date
      2012-06-24
    • Related Report
      2012 Annual Research Report
  • [Presentation] New Vistas in Chemistry of Synthetic Carbon Allotropes : Organic Nanomaterials Based on Endohedral Metallofullerenes2012

    • Author(s)
      Takeshi Akasaka
    • Organizer
      49th Outstanding Scholors Forum in Huazhong University of Science and Technology
    • Place of Presentation
      Wuhan, China(招待講演)
    • Year and Date
      2012-05-06
    • Related Report
      2012 Annual Research Report
  • [Presentation] New Vistas in Fullerene Endohedrals

    • Author(s)
      T. Akasaka
    • Organizer
      Department Lecture
    • Place of Presentation
      Xiamen University, Xiamen, China
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] New Vistas in Fullerene Endohedrals

    • Author(s)
      T. Akasaka
    • Organizer
      Workshop on Emerging Materials
    • Place of Presentation
      University of Trieste, Trieste, Italy
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] ナノカーボンを基軸とする高次π空間の創製と機能開拓

    • Author(s)
      赤阪 健
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学、名古屋
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] フラーレン誘導体・内包技術の最前線2014

    • Author(s)
      前田優、赤阪健,
    • Total Pages
      12
    • Publisher
      シーエムシー出版
    • Related Report
      2014 Annual Research Report
  • [Book] 未来材料を創出するπ電子系の科学、カレントレビュー No. 122013

    • Author(s)
      前田 優、赤阪 健
    • Total Pages
      9
    • Publisher
      化学同人出版
    • Related Report
      2013 Annual Research Report
  • [Book] 高次π空間の創発と機能開発2013

    • Author(s)
      土屋敬広、溝呂木直美、永瀬 茂、赤阪 健
    • Total Pages
      5
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Annual Research Report
  • [Book] Stability Computations for Fullerenes and Metallofullerenes In "Handbook of Carbon Nano Materials"2012

    • Author(s)
      Z. Slanina, F. Uhlik, S-L. Lee, T. Akasaka, S. Nagase
    • Publisher
      World Scientic
    • Related Report
      2012 Annual Research Report
  • [Book] Endohedral Metallofullerene Functionalization, In "Advances in Carbon Nanomate rials : Science and Applications"2012

    • Author(s)
      Y. Maeda, T. Akasaka, S. Nagase
    • Publisher
      Pan Stanford Publishing
    • Related Report
      2012 Annual Research Report
  • [Remarks] 赤阪研究室ホームページ

    • URL

      http://www.tara.tsukuba.ac.jp/~akasaka-lab/

    • Related Report
      2014 Annual Research Report
  • [Remarks] 赤阪研究室ホームページ

    • URL

      http://www.tara.tsukuba.ac.jp/~akasaka-lab/

    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.tara.tsukuba.ac.jp/~akasaka-lab/

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2012-04-24   Modified: 2019-07-29  

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