Creation of self-assembled paramagnetic fullerene and extending its functionality

• Project/Area Number: 24350019
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Organic chemistry
• Research Institution: Tokyo Gakugei University (2013-2014); University of Tsukuba (2012)
• Principal Investigator: AKASAKA Takeshi 東京学芸大学, 教育学部, 客員教授 (60089810)
• Co-Investigator(Kenkyū-buntansha): TSUCHIYA Takahiro 筑波大学, 数理物質系, 講師 (10375412) ; MIZOROGI Naomi 筑波大学, 生命領域学際研究センター, 研究員 (60462199)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000); Fiscal Year 2014: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000); Fiscal Year 2013: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000); Fiscal Year 2012: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
• Keywords: フラーレン / 金属内包フラーレン / 内包フラーレン / 磁性内包フラーレン / 磁性金属内包フラーレン / ナノロッド / 薄膜 / 自己組織化

Outline of Final Research Achievements

Research into the synthesis, characterization, and functionalization of compounds with π-electron systems, as typified by endofullerenes and metallofullerenes, is showing steady progress, and the momentum of this area is rising on new evolution. Through the investigation on the active nanocarbons, we focused on the unique characteristics of paramagnetic endohedral metallofullerenes that give functionalized molecules a diverse range of structural and functional variations, as we attempt to construct highly elaborated π-systems with more sophisticated and complex orders and functionality.

Research Products

• [Journal Article] Hiding and Recovering Electrons in a Dimetallic Endohedral Fullerene : Air-Stable Products from Radical Additions (2015)
  • Author(s): M. Yamada, H. Kurihara, M. Suzuki, M. Saito, Z. Slanina, F. Uhlik, T. Aizawa, T. Kato, M.M. Olmstead, A.L. Balch, Y. Maeda, S. Nagase, X. Lu, and T. Akasaka
  • Journal Title: J. Am. Chem. Soc. Volume: 137 Issue: 1 Pages: 232-238
  • DOI: 10.1021/ja509956y
  • Peer Reviewed
• [Journal Article] Regioselective Cage Opening of La_2@D_2(10611)-C_<72> with 5,6-Diphenyl-3-(2-pyridyl)-1,2,4-triazine (2015)
  • Author(s): M. Yamada, Y. Muto, H. Kurihara, Z. Slanina, M. Suzuki, Y. Maeda, Y. Rubin, M.M. Olmstead, A.L. Balch, S. Nagase, X. Lu, and T. Akasak
  • Journal Title: Angew. Chem. Int. Ed. Volume: 54 Issue: 7 Pages: 2232-2235
  • DOI: 10.1002/anie.201410012
  • Peer Reviewed
• [Journal Article] In-Depth Understanding of the Chemical Properties of Rarely Explored Carbide Cluster Metallofullerenes: A Case Study of Sc2C2@C3v(8)-C82 that Reveals as General Rule (2015)
  • Author(s): W. Cai, M. Chen, L. Bao, Y. Xie, T. Akasaka, X. Lu
  • Journal Title: Chem. Eur. J. Volume: 21 Issue: 8 Pages: 3449-3454
  • DOI: 10.1002/chem.201405493
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Tuning intramolecular electron and energy transfer processes in novel conjugates of La2@C80 and electron accepting subphthalocyanines (2015)
  • Author(s): L. Feng, M. Rudolf, O. Trukhina, Z. Slanina, F. Uhlik, X. Lu, T. Torres, D. M. Guldi, T. Akasaka
  • Journal Title: Chem. Commun. Volume: 51 Issue: 2 Pages: 330-333
  • DOI: 10.1039/c4cc08072f
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Regioselective Benzyl Radical Addition to an Open-Shell Cluster Metallofullerene. Crystallographic Studies of Cocrystallized Sc_3C_2@Ih-C_<80> and Its Singly Bonded Derivativ (2014)
  • Author(s): H. Fang, H. Cong, M. Suzuki, L. Bao, B. Yu, Y. Xie, N. Mizorogi, M.M. Olmstead, A.L. Balch, S. Nagase, T. Akasaka, and X. Lu
  • Journal Title: J. Am. Chem. Soc. Volume: 136 Issue: 29 Pages: 10534-10540
  • DOI: 10.1021/ja505858y
  • Peer Reviewed
• [Journal Article] Sc_2C_<66> Revised : An Endohedral Fullerene with Scandium Ions Nestled within Two Unsaturated Linear Triquinanes (2014)
  • Author(s): M. Yamada, H. Kurihara, M. Suzuki, J.-D. Guo, M. Waelchli, M.M. Olmstead, A.L. Balch, S. Nagase, Y. Maeda, T. Hasegawa, X. Lu, and T. Akasaka
  • Journal Title: J. Am. Chem, Soc. Volume: 136 Issue: 21 Pages: 7611-7614
  • DOI: 10.1021/ja5035649
  • Peer Reviewed
• [Journal Article] Partial Charge Transfer in the Shortest Possible Metallofullerene Peapod, La@C_<82>・[11]Cycloparaphenylene (2014)
  • Author(s): T. Iwamoto, Z. Slanina, N. Mizorogi, J.-D. Guo, T. Akasaka, S. Nagase, H. Takaya, N. Yasuda, T. Kato, and S. Yamagao
  • Journal Title: Chem. Eur. J. Volume: 20 Issue: 44 Pages: 14403-14409
  • DOI: 10.1002/chem.201403879
  • Peer Reviewed
• [Journal Article] Isolation and Characterization of [5,6]-Pyrrolidino-Sc_3N@Ih-C_<80> Diastereomers (2014)
  • Author(s): Y. Maeda, M. Kimura, C. Ueda, M. Yamada, T. Kikuchi, M. Suzuki, W.-W. Wang, N. Mizorogi, N. Karousis, N. Tagmatarchis, T. Hasegawa, M.M. Olmstead, A.L. Balch, S. Nagase, and T. Akasaka
  • Journal Title: Chem. Commun. Volume: 50 Issue: 83 Pages: 12552-12555
  • DOI: 10.1039/c4cc04946b
  • Peer Reviewed
• [Journal Article] Regioselective Synthesis and Molecular Structure of the First Derivative of Praseodymium-Containing Metallofullerenes (2014)
  • Author(s): Q. Zhou, H. Li, Y. Lian, M. Suzuki, L. Bao, W. Cai, W.-W. Wang, S. Nagase, X. Lu, and T. Akasaka
  • Journal Title: Chem. Commun. Volume: 50 Issue: 69 Pages: 9876-9878
  • DOI: 10.1039/c4cc02949f
  • Peer Reviewed
• [Journal Article] Thermal Reactions of Fullerenes with Cyclic Organosilicon and Organogermanium Compounds: Silylation and Germylation of C60 and C70 (2014)
  • Author(s): M. Kako, D. Inaba, K. Minami, R. Iida, T. Nakahodo, T. Akasaka
  • Journal Title: Heteroatom Chem. Volume: 25 Issue: 6 Pages: 584-591
  • DOI: 10.1002/hc.21230
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Chemical Properties of Divalent Metallofullerenes Yb@D3h(1)-C74 and Yb@C2(13)-C84 (2014)
  • Author(s): J. Ruan, Y. Xie, W. Cai, Z. Slanina, N. Mizorogi, S. Nagase, T. Akasaka, X. Lu
  • Journal Title: Fulleren. Nanotub. Carb. Nanostruct. Volume: 22 Issue: 1-3 Pages: 138-146
  • DOI: 10.1080/1536383x.2013.794344
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Recent Progress in the Chemistry of Endohedral Metallofullere (2014)
  • Author(s): X. Lu, L. Bao, T. Akasaka, and S. Nagase
  • Journal Title: Chem. Commun. (Feature Article) Volume: 50 Issue: 94 Pages: 14701-14715
  • DOI: 10.1039/c4cc05164e
  • Peer Reviewed
• [Journal Article] An Improbable Monometallic Cluster Entrapped in a Popular Fullerene Cage: YCN@Cs(6)-C82 (2013)
  • Author(s): Yang, S.; Chen, C.; Liu, F.; Xie, Y.; Li, F.; Jiao, M.; Suzuki, M.; Wei, T.; Wang, S.; Chen, Z.; Lu, X.; Akasaka, T.
  • Journal Title: Scientific Reports Volume: 3 Pages: 1487-1492
  • Peer Reviewed
• [Journal Article] Molecular Structure and Chemical Property of a Divalent Metallofullerene Yb@C2(13)-C84 (2013)
  • Author(s): Zhang, W.; Suzuki, M.; Xie, Y.; Bao, L.; Cai, W.; Slanina, Z.; Nagase, S.; Xu, M.; Akasaka, T.; Lu
  • Journal Title: J. Am. Chem. Soc. Volume: 135 Issue: 34 Pages: 12730-12735
  • DOI: 10.1021/ja405223t
  • Peer Reviewed
• [Journal Article] A Metallofullerene Electron Donor that Powers an Efficient Spin Flip in a Linear Electron Donor Acceptor Conjugate (2013)
  • Author(s): Rudolf, M.; Feng, L.; Slanina, Z.; Akasaka, T.; Nagase, S.; Guldi, D.
  • Journal Title: J. Am. Chem. Soc. Volume: 135 Issue: 30 Pages: 11165-11174
  • DOI: 10.1021/ja403763e
  • Peer Reviewed
• [Journal Article] Mechanistic Study of the Diels-Alder Reaction of Paramagnetic Endohedral Metallofullerene: Reaction of La@C82 with 1,2,3,4,5-Pentamethylcyclopentadiene (2013)
  • Author(s): Sato, S.; Maeda, Y.; Guo, J. -D.; Yamada, M.; Mizorogi, N.; Nagase, S.; Akasaka, T.
  • Journal Title: J. Am. Chem. Soc. Volume: 135 Issue: 15 Pages: 5582-5587
  • DOI: 10.1021/ja309763f
  • Peer Reviewed
• [Journal Article] Highly Regioselective Addition of Admantylidene Carbene to Yb@C2v(3)-C80 Affords the First Derivative of Divalent Metallofullerenes (2013)
  • Author(s): Xie, Y.; Suzuki, M.; Cai, W.; Mizorogi, N.; Nagase, S.; Akasaka, T.; Lu, X.
  • Journal Title: Angew. Chem. Int. Ed. Volume: 52 Issue: 19 Pages: 5142-5145
  • DOI: 10.1002/anie.201210164
  • Peer Reviewed
• [Journal Article] Intramolecular versus Intermolecular Electronic Interactions between [5,6]-open and [6,6]-closed C60 Adducts with exTTF (2013)
  • Author(s): Takano, Y.; Schubert, C.; Mizorogi, N.; Feng, L.; Iwano, A.; Katayama, M.; Herranz, M. A.; Guldi, D.; Martin, N.; Nagase, S.; Akasaka, T.
  • Journal Title: Chem. Sci. Volume: 4 Issue: 8 Pages: 3166-3171
  • DOI: 10.1039/c3sc00004d
  • Peer Reviewed
• [Journal Article] Electrochemical and Magnetic Properties of a Surface-grafted Novel Endohedral Metallofullerene Derivative (2013)
  • Author(s): Crivillers, N.; Takano, Y.; Matsumoto, Y.; Casado-Montenegro, J.; Mas-Torrent, M.; Rovira, C.; Akasaka, T.; Veciana, J.
  • Journal Title: Chem. Commun. Volume: 49 Issue: 74 Pages: 8145-8147
  • DOI: 10.1039/c3cc43578d
  • Peer Reviewed
• [Journal Article] X-ray observation of a helium atom and placing a nitrogen atom inside He＠C_60 and He＠C_70 (2013)
  • Author(s): 森中裕太
  • Journal Title: Nature Communications Volume: 4 Issue: 1 Pages: 1554-1554
  • DOI: 10.1038/ncomms2574
  • Peer Reviewed
• [Journal Article] Application of MCD Spectroscopy and TD-DFT to Endohedral Metallofullerenes for Characterization of Their Electronic Transitions (2013)
  • Author(s): Yamada, M.; Slanina, Z.; Mizorogi, N.; Muranaka, A.; Maeda, Y.; Nagase, S.; Akasaka, T.; Kobayashi, N.
  • Journal Title: Phys. Chem. Chem. Phys. Volume: 15 Issue: 10 Pages: 3593-3601
  • DOI: 10.1039/c3cp44096f
  • Peer Reviewed
• [Journal Article] Coordinative Interactions between Porphyrins and C60, La@C82, and La2@C80 (2013)
  • Author(s): Tsuchiya, T.; Rudolf, M.; Wolfrum, S.; Radhakrishnan, S. G.; Aoyama, R.; Yokosawa, Y.; Oshima, A.; Akasaka, T.; Nagase, S.; Guldi, D. M.
  • Journal Title: Chem. Eur. J. Volume: 19 Issue: 2 Pages: 558-565
  • DOI: 10.1002/chem.201202661
  • Peer Reviewed
• [Journal Article] Mapping the Metal Positions inside Spherical C80 Cages: Crystallographic and Theoretical studies of Ce2@D5h-C80 and Ce2@Ih-C80 (2013)
  • Author(s): Feng, L.; Suzuki, M.; Mizorogi, N.; Xing, L.; Yamada, M.; Akasaka, T.; Nagase, S.
  • Journal Title: Chem. Eur. J. Volume: 19 Issue: 3 Pages: 988-993
  • DOI: 10.1002/chem.201202341
  • Peer Reviewed
• [Journal Article] An Endohedral Metallofullerene as a Pure Electron Donor: Intramolecular Electron Transfer in Donor-Acceptor Conjugates of La2@C80 and 11,11,12,12-tetracyano-9,10-anthra-p-quinodimethane (TCAQ), (2012)
  • Author(s): Takano, Y.; Obuchi, S.; Mizorogi, N.; Garcia, R.; Herranz, M. A.; Rudolf, M.; Guldi, D. M.; Martin, N.; Nagase, S.; Akasaka, T
  • Journal Title: J. Am. Chem. Soc Volume: 134 Issue: 47 Pages: 19401-19408
  • DOI: 10.1021/ja307341g
  • Peer Reviewed
• [Journal Article] Single Crystal X-ray Diffraction Study of Three Yb@C_<82> Isomers Cocrystallized with Ni^<II>(octaethylporphyrin) (2012)
  • Author(s): M. Suzuki, Z. Slanina, N. Mizorogi, X. Lu, S. Nagase, M. M. Olmstead, A. L. Balch, T. Akasaka
  • Journal Title: J. Am. Chem. Soe Volume: 134 Issue: 45 Pages: 18772-18778
  • DOI: 10.1021/ja308706d
  • Peer Reviewed
• [Journal Article] Analysis of Functionalization Degree of Single-Walled Carbon Nanotubes Having Various Substituents (2012)
  • Author(s): Y. Maeda, K.Saito, N. Akanlatsu, Y. Chiba, S. Ohno, Y. Okui, M. Yamada, T. Hasegawa, M. Kako, T. Akasaka
  • Journal Title: J. Am. Chem. Soc Volume: 134 Issue: 43 Pages: 18101-18108
  • DOI: 10.1021/ja308969p
  • Peer Reviewed
• [Journal Article] Stabilizing Ion and Radical Ion Pair States in a Paramagnetic Endohedral Metallofullerene and aπ-Extended Tetrathiafulvalene (2012)
  • Author(s): Y. Takano, S. Obuchi, N. Mizorogi, R. Garcia, M. A. Herranz, M. Rudolf, S. Wolfrum, D. M. Guldi, N. Martin,.S. Nagase, T. Akasaka
  • Journal Title: J. Am. Chem Volume: 134 Issue: 39 Pages: 16103-16106
  • DOI: 10.1021/ja3055386
  • Peer Reviewed
• [Journal Article] Synthesis of a Silylene-Bridged Endohedral Metallofullerene Lu_ 3N@J_h-C_<80> (2012)
  • Author(s): K.Sato, M. Kako, M. Suzuki, N. Mizorogi, T. Tsuchiya, M. Olmstead, A. Balch, T, Akasaka, S., Nagasaki
  • Journal Title: J. Am. Chem. Soc Volume: 134 Issue: 38 Pages: 16033-16039
  • DOI: 10.1021/ja3073929
  • Peer Reviewed
• [Journal Article] Exceptional Chemical Properties of Sc@C_<2v>(9)-C_<82> Probed with Adamantylidine Carbene (2012)
  • Author(s): M. Hachiya, H. Nikawa, N. Mizorogi, T. Tsuchiya, X. Lu, T. Akasaka
  • Journal Title: J. Am. Chem. Soc Volume: 134 Issue: 37 Pages: 15550-15555
  • DOI: 10.1021/ja306890x
  • Peer Reviewed
• [Journal Article] A Paradigmatic Change - Linking Fullerenes to Electron Acceptors (2012)
  • Author(s): L. Feng, M. Rudolf, S. Wolfrum, A. Troeger, Z. Slanina, T. Akasaka, S. Akasaka, S Nagase, N. Martin, T. Ameri, C. Brabec, D. Guldi
  • Journal Title: J. Am. Chem. Soc Volume: 134 Issue: 29 Pages: 12190-12197
  • DOI: 10.1021/ja3039695
  • Peer Reviewed
• [Journal Article] Tunable Charge-transport Property of Ih-C80 Endohedral Metallofullerenes : Investigation of La2@C80, Sc3N@C80, and Sc3C2@C80. (2012)
  • Author(s): Satoru Sato
  • Journal Title: Journal of American Chemical Society Volume: 134 Issue: 28 Pages: 11681-11686
  • DOI: 10.1021/ja303660g
  • Peer Reviewed
• [Journal Article] Unexpected Formation of a Sc_3C_2@C_<80> Bisfulleroid Derivative (2012)
  • Author(s): H. Kurihara, Y. Iiduka, Y. Rubin, M. Waelchli, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nagase, T. kasaka
  • Journal Title: J. Am. Chem. Soc Volume: 134 Issue: 9 Pages: 4092-4095
  • DOI: 10.1021/ja300279x
  • Peer Reviewed
• [Journal Article] Chemical Understanding of Carbide Cluster Metallofullerenes : A Case Study on S_<c2>C_2@C_<2v>(5)-C_<80> with Complete X Ray Crystallographic Characterizations (2012)
  • Author(s): H. Kurihara, X. Lu, Y. Iiduka, H. Nikawa, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nagase, T. Akasaka
  • Journal Title: J. Am. Chem. Soc. Volume: 134 Pages: 3139-3144
  • Peer Reviewed
• [Journal Article] The Long-Believed S_<c2>@C_<2v>(17)-C_<84> is Actually S_<c2>C_2@C_<2v>(9)-C_<82>. Unambiguous Structure Assignment and Chemical Functionalization (2012)
  • Author(s): X. Lu, K. Nakajima, Y. Iiduka, H. Nikawa, T. Tsuchiya, N. Mizorogi, Z. Slanina, S. Nagase, T. Akasaka
  • Journal Title: Angew. Chem. Int. Ed. Volume: 51 Issue: 24 Pages: 5889-5892
  • DOI: 10.1002/anie.201201325
  • Peer Reviewed
• [Journal Article] A Co-Crystal Composed of the Paramagnetic Endohedral Metallofullerene La@C_<82> and Nickel Porphyrin with High Electron Mobility (2012)
  • Author(s): Satoru Sato
  • Journal Title: Angewandte Chemie International Edition Volume: 51 Issue: 7 Pages: 1589-1591
  • DOI: 10.1002/anie.201106912
  • Peer Reviewed
• [Journal Article] Sc_2@C_<3v>(8)-C_<82> vs. Sc_2C_2@C_<3v>(8)-C_<82>: Drastic Effect of C_2 Capture on the Redox Properties of Scandium Metallofullerenes (2012)
  • Author(s): H. Kurihara, X. Lu, Y. Iiduka, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nagase, T. Akasaka
  • Journal Title: Chem. Commmun Volume: 48 Issue: 9 Pages: 1290-1292
  • DOI: 10.1039/c2cc16422a
  • Peer Reviewed
• [Journal Article] Where Does the Metal Cation Stay in Gd@C_<2v>(9)-C_<82> A Single-Crystal X-Ray Diffraction Study (2012)
  • Author(s): M. Suzuki, X. Lu, S. Sato, H. Nikawa, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nagase, T. Akasaka
  • Journal Title: Inorg. Chem. Volume: 51 Issue: 9 Pages: 5270-5273
  • DOI: 10.1021/ic300186y
  • Peer Reviewed
• [Journal Article] X-Ray Structures of Sc2C2@C2n (n=40, 41, 42): In-Depth Understanding of the Core-Shell Interplay in Carbide Cluster Metallofullerenes (2012)
  • Author(s): H. Kurihara, X. Lu, Y. Iiduka, H. Nikawa, M. Hachiya, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nlaga.sg, T. kasaka
  • Journal Title: Inorg. Chem Volume: 51 Issue: 1 Pages: 746-750
  • DOI: 10.1021/ic202438u
  • Peer Reviewed
• [Journal Article] Electron transport through Single Endohedral Ce@C_82 Metallofullerenes (2012)
  • Author(s): Satoshi Kaneko, Lu Wang, Guangfu Luo, Ling Lu, Shigeru Nagase, Satoru Sato, Michio Yamada, Zdenek Slanina, Takeshi Akasaka, and Manabu Kiguchi
  • Journal Title: Physical Review B Volume: 86 Issue: 15
  • DOI: 10.1103/physrevb.86.155406
  • Peer Reviewed
• [Journal Article] Stability Computations for Isomers of La@C_n(n = 72, 74, 76) (2012)
  • Author(s): Z. Slanina, F. Uhlik, S.-L. Lee, L. Adamowicz, T. Akasaka, S. Nagase
  • Journal Title: Molecules Volume: 17 Issue: 11 Pages: 13146-13156
  • DOI: 10.3390/molecules171113146
  • Peer Reviewed
• [Journal Article] Bis-Silylation of Lu_3N@I_h-C_<80> : Considerable Variation in the Electronic Structures (2012)
  • Author(s): K. Sato, M. Kako, N. Mizorogi, T. Tsuchiya, T. Akasaka
  • Journal Title: Org. Lett Volume: 15 Issue: 23 Pages: 5908-5911
  • DOI: 10.1021/ol302832k
  • Peer Reviewed
• [Journal Article] Diameter-Selective Purification of Carbon Nanotubes by Microwave-Assisted Acid Processing (2012)
  • Author(s): H. Qiu, Y. Maeda, T. Akasaka, J. Yang
  • Journal Title: Sep. Purif. Technol. Volume: 96 Pages: 182-186
  • DOI: 10.1016/j.seppur.2012.06.001
  • Peer Reviewed
• [Presentation] New Vistas in Fullerene World: Endohedral Metallofullerenes (2015)
  • Author(s): 赤阪 健
  • Organizer: 青島大学 School Lecture
  • Place of Presentation: School of Material Science and Engineering, Qingdao University, Qingdao, China
  • Year and Date: 2015-01-09
  • Invited
• [Presentation] New Vistas in Fullerene World: Endohedral Metallofullerenes (2014)
  • Author(s): 赤阪 健
  • Organizer: エルランゲン大学 Department Lecture
  • Place of Presentation: Department of Chemistry and Pharmacy, Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universitaet Erlangen-Nuernberg, Erlangen, Germany
  • Year and Date: 2014-12-09
  • Invited
• [Presentation] New Vistas in Fullerene World: Endohedral Metallofullerenes (2014)
  • Author(s): 赤阪 健
  • Organizer: 長春化学研究所 Institute Lecture
  • Place of Presentation: Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China
  • Year and Date: 2014-07-06
  • Invited
• [Presentation] New Vistas in Fullerene World: Endohedral Metallofullerenes (2014)
  • Author(s): 赤阪 健
  • Organizer: 蘇州大学 School Lecture
  • Place of Presentation: School of Material Science and Engineering, Soochow University, Soochow, China
  • Year and Date: 2014-06-16
  • Invited
• [Presentation] フラーレンを鍵物質とする高次π空間の創発と機能開拓 (2013)
  • Author(s): 赤阪 健
  • Organizer: 科研費新学術領域研究「融合マテジアル」第6回公開シンポジウム
  • Place of Presentation: TKPガーデンシティ仙台,仙台市(招待講演)
  • Year and Date: 2013-01-28
• [Presentation] New Vistas in Fullerene Endohedrals (2013)
  • Author(s): T. Akasaka
  • Organizer: 1st International Symposium on Nanocarbons -- Fullerenes, Endofullerenes, Carbon Nanotubes and Carbon Nanostructures (ISNC2013)
  • Place of Presentation: University of Science and Technology of China, Hefei, China
  • Invited
• [Presentation] New Vistas in Fullerene Endohedrals (2013)
  • Author(s): T. Akasaka
  • Organizer: The 3rd Symposium on Carbon Nanoforms
  • Place of Presentation: IMDEA-Nanoscience, Madrid, Spain
  • Invited
• [Presentation] フラーレンを鍵物質とする高次π空間の創発と機能開拓 (2012)
  • Author(s): 赤阪 健
  • Organizer: 第6回有機π電子系シンポジウム
  • Place of Presentation: 道後温泉 茶波瑠、松山市(招待講演)
  • Year and Date: 2012-12-14
• [Presentation] New Vistas in Chemistry of Nanocarbons : Organic Nanomaterials Based on Endohedral Metallofullerenes (2012)
  • Author(s): Takeshi Akasaka
  • Organizer: The Symposium on Material Chemistry in Heilongjiang University
  • Place of Presentation: Harbin, China(招待講演)
  • Year and Date: 2012-09-14
• [Presentation] New Vistas in fullerene Endohedrals (2012)
  • Author(s): Takeshi Akasaka
  • Organizer: XXIst International Symposium on Jahn-Teller Effect
  • Place of Presentation: Univ. of Tsukuba, Japan(招待講演)
  • Year and Date: 2012-08-26
• [Presentation] New Vistas in Chemistry of Nanocarbons : Organic Nanomaterials Based on Endohedral Metallofullerenes (2012)
  • Author(s): 赤阪 健
  • Organizer: 岡山大学異分野研究連携コア講演会
  • Place of Presentation: 岡山大学、岡山(招待講演)
  • Year and Date: 2012-08-07
• [Presentation] New Vistas in Chemistry of Synthetic Carbon Allotropes : Organic Nanomaterials Based on Endohedral Metallofullerenes (2012)
  • Author(s): Takeshi Akasaka
  • Organizer: 9th International Conference on Nanosciences & Nanotechnologies
  • Place of Presentation: Thessaloniki, Greece(招待講演)
  • Year and Date: 2012-07-03
• [Presentation] New Vistas in Fullerene Chemistry : Oraganosulfur Compounds Expand the Performance of Carbon Nanomaterials (2012)
  • Author(s): Takeshi Akasaka
  • Organizer: 25th International Symposium Oil the Organic Chemistry of Sulfur
  • Place of Presentation: Czestochowa, Poland(招待講演)
  • Year and Date: 2012-06-24
• [Presentation] New Vistas in Chemistry of Synthetic Carbon Allotropes : Organic Nanomaterials Based on Endohedral Metallofullerenes (2012)
  • Author(s): Takeshi Akasaka
  • Organizer: 49th Outstanding Scholors Forum in Huazhong University of Science and Technology
  • Place of Presentation: Wuhan, China(招待講演)
  • Year and Date: 2012-05-06
• [Presentation] New Vistas in Fullerene Endohedrals
  • Author(s): T. Akasaka
  • Organizer: Department Lecture
  • Place of Presentation: Xiamen University, Xiamen, China
  • Invited
• [Presentation] New Vistas in Fullerene Endohedrals
  • Author(s): T. Akasaka
  • Organizer: Workshop on Emerging Materials
  • Place of Presentation: University of Trieste, Trieste, Italy
  • Invited
• [Presentation] ナノカーボンを基軸とする高次π空間の創製と機能開拓
  • Author(s): 赤阪 健
  • Organizer: 日本化学会第９４春季年会
  • Place of Presentation: 名古屋大学、名古屋
  • Invited
• [Book] フラーレン誘導体・内包技術の最前線 (2014)
  • Author(s): 前田優、赤阪健,
  • Total Pages: 12
  • Publisher: シーエムシー出版
• [Book] 未来材料を創出するπ電子系の科学、カレントレビュー No. 12 (2013)
  • Author(s): 前田 優、赤阪 健
  • Total Pages: 9
  • Publisher: 化学同人出版
• [Book] 高次π空間の創発と機能開発 (2013)
  • Author(s): 土屋敬広、溝呂木直美、永瀬 茂、赤阪 健
  • Total Pages: 5
  • Publisher: シーエムシー出版
• [Book] Stability Computations for Fullerenes and Metallofullerenes In "Handbook of Carbon Nano Materials" (2012)
  • Author(s): Z. Slanina, F. Uhlik, S-L. Lee, T. Akasaka, S. Nagase
  • Publisher: World Scientic
• [Book] Endohedral Metallofullerene Functionalization, In "Advances in Carbon Nanomate rials : Science and Applications" (2012)
  • Author(s): Y. Maeda, T. Akasaka, S. Nagase
  • Publisher: Pan Stanford Publishing
• [Remarks] 赤阪研究室ホームページ
  • URL: http://www.tara.tsukuba.ac.jp/~akasaka-lab/
• [Remarks] 赤阪研究室ホームページ
  • URL: http://www.tara.tsukuba.ac.jp/~akasaka-lab/
• [Remarks]
  • URL: http://www.tara.tsukuba.ac.jp/~akasaka-lab/