Synthesis and controllable structural interconversions of multidentate dipyrrin- typical element complexes
| Project/Area Number |
24350020
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | University of Tsukuba |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
AKINE Shigehisa 筑波大学, 数理物質系, 准教授 (30323265)
YAMAMURA Masaki 筑波大学, 数理物質系, 講師 (40524426)
NAKAMURA Takashi 筑波大学, 数理物質系, 助教 (90734103)
RICHARDS Gary James 筑波大学, 数理物質系, 助教 (00708620)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥18,590,000 (Direct Cost: ¥14,300,000、Indirect Cost: ¥4,290,000)
Fiscal Year 2014: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2013: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
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| Keywords | 超分子化学 / 発光性分子 / 典型元素錯体 / 応答性 / 超分子 / チオフェン / 蛍光 / ジピリン / ホウ素錯体 / ゲルマニウム錯体 |
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| Outline of Final Research Achievements |
In this study we investigated organic molecules that would be applied for a fluorescent unit for bioimaging, laser dyes, electrogenerated chemiluminescence materials, photovoltaic cells, etc. In particular, we have synthesized dipyrrin complexes with silicon, germanium, tin, etc. to develop novel luminescent molecules with excellent photophysical properties. In addition, linear dipyrrin-boron complexes bearing thiophene units and macrocyclic dipyrrin-boron complexes were prepared to create a new series of luminescent molecular devices.
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Report
(4 results)
Research Products
(161 results)
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[Journal Article] Detection of Ethanol in Alcoholic Beverages or Vapor Phase using Fluorescent Molecules embedded in a Nanofibrous Polymer2015
Author(s)
M. Akamatsu, T. Mori, K. Okamoto, H. Komatsu, K. Kumagai, S. Shiratori, M. Yamamura, T. Nabeshima, H. Sakai, M. Abe, J. Hill and K. Ariga
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Journal Title
ACS Appl. Mater. Interfaces
Volume: 7
Issue: 11
Pages: 6189-6194
DOI
Related Report
Peer Reviewed
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