Development of High Performance Polyoxometalate-Based Catalysts‒From Molecular Catalysts to Nano-Structured Catalysts ‒
Project/Area Number |
24350026
|
Research Category |
Grant-in-Aid for Scientific Research (B)
|
Allocation Type | Partial Multi-year Fund |
Section | 一般 |
Research Field |
Inorganic chemistry
|
Research Institution | The University of Tokyo |
Principal Investigator |
MIZUNO Noritaka 東京大学, 工学(系)研究科(研究院), 教授 (50181904)
|
Project Period (FY) |
2012-04-01 – 2015-03-31
|
Project Status |
Completed (Fiscal Year 2014)
|
Budget Amount *help |
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2013: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2012: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
|
Keywords | ポリオキソメタレート / 分子触媒 / ナノ構造体 / 酸化反応 / 新反応開発 |
Outline of Final Research Achievements |
In this study, we have designed an organic solvent-soluble tungstate monomer. The tungstate monomer could act as an efficient catalyst for N-silylation of indoles. By using the tungstate monomer as the precursor, we have successfully synthesized various kinds of lacunary polyoxometalate-based molecular catalysts. They exhibited the high catalytic performance for acylation of alcohols and dehydration of primary amides to nitriles. Furthermore, several high performance solid catalysts could be developed through immobilization or heterogenization of the molecular catalysts.
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Report
(4 results)
Research Products
(24 results)