| Budget Amount *help |
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2014: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2013: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2012: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
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| Outline of Final Research Achievements |
Novel unsaturated compounds of boron, silicon, phosphorus, etc. have been synthesized by the introduction of the fused-ring bulky "Rind" groups, which we have recently developed. Their molecular structures and chemical bonding have been elucidated by the experimental and theoretical studies. We have also examined the reactivity of the resulting unsaturated main group elements compounds. Especially, we have focused on the synthesis of new hydroboron compounds, and their structures clearly confirmed by X-ray crystallography. The reactions of the dihydrodiborane(4) with small molecules such as dihydrogen and carbon monoxide have been investigated.
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