Development and Applications of Molecular Transformation by Carbon-Carbon Bond Cleavage on Transition Metals
| Project/Area Number |
24350043
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Hokkaido University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2014: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2013: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2012: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
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| Keywords | チタン錯体 / 反応機構 / カルベン / 炭素―炭素結合切断 / 炭素―炭素結合生成 / アゾベンゼン / インデン誘導体 / トリメチルホスフィン / シクロペンタジエニル / チタノセン / ジヒドロインデン / イソシアネート / 求電子剤 / カップリング / 選択的 / 炭素-炭素結合切断 / チタナサイクル / metathesis / カルビン錯体 / アミド / シクロヘプタトリエン |
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| Outline of Final Research Achievements |
Creating environmentally-friendly chemical processes is nowadays a much attractive issue of ‘Sustainable Chemistry’. Our Laboratory conducts basic research of developing high efficient construction processes for various carbon skeletons. This includes developing novel synthetic methodologies based on a combination of carbon-carbon bond cleavage and formation reactions.
In this research, we found novel carbon-carbon bond cleavage reactions of Cp ligand on titanium. Furthermore, by use Cp ligand as building blocks, via a combination of carbon-carbon bond cleavage and formation reactions, a variety of molecular transformations were realized successfully.
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Report
(4 results)
Research Products
(67 results)
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[Journal Article] Helically Chiral Diene in Asymmetric Catalysis: C2-Symmetric (Z,Z)-2,3-Bis[1-(diphenylphosphinyl)ethylidene]tetralin as Highly Active Lewis-Base Organocatalyst2013
Author(s)
Ogasawara, M.; Kotani, S.; Nakajima, H.; Furusho, H.; Miyasaka, M.; Shimoda, Y.; Wu, W.-Y.; Sugiura, M.; Takahashi, T.; Nakajima, M.
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Journal Title
Angewandte Chemie International Edition
Volume: 52
Issue: 51
Pages: 13798-13802
DOI
Related Report
Peer Reviewed
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