Synthesis of Porous Two-Dimensional Polymers Utilizing Self-Assembled Monolayers Formed at Solid-Liquid and Air-Liquid Interfaces
| Project/Area Number |
24350046
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (B)
|
| Allocation Type | Partial Multi-year Fund |
|---|
| Section | 一般 |
|---|
| Research Field |
Synthetic chemistry
|
|---|
| Research Institution | Osaka University |
|---|
Principal Investigator |
TOBE Yoshito 大阪大学, 基礎工学研究科, 教授 (60127264)
|
|---|
| Co-Investigator(Renkei-kenkyūsha) |
TAHARA Kazukuni 大阪大学, 大学院基礎工学研究科, 助教 (40432463)
|
|---|
| Project Period (FY) |
2012-04-01 – 2015-03-31
|
| Project Status |
Completed (Fiscal Year 2014)
|
| Budget Amount *help |
¥18,590,000 (Direct Cost: ¥14,300,000、Indirect Cost: ¥4,290,000)
Fiscal Year 2014: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2012: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
|
|---|
| Keywords | 二次元ポリマー / 自己集合単分子膜 / 固液界面 / 気液界面 / 共有結合形成 / 自己集合 / 単分子膜 |
|---|
| Outline of Final Research Achievements |
Sheet-like materials of single atom thickness with periodical internal structures are called two-dimensional polymers and have been attracting a great deal of interest with respect to potential applications. In this project, we investigated the synthesis of two-dimensional polymers via three different pathways, (1) C-C bond formation between the butadiyne units of porous molecular networks formed by self-assembly at the liquid-solid interfaces, (2) imine bond formation between the amino groups installed in the porous network formed at the liquid-solid interfaces and the formyl groups of the co-adsorbed guest molecules, (3) linking the monomers having styryl groups self-assembled at the air-water interfaces forming Langmuir membranes. We found positive results indicative of the formation of two-dimensional polymers in the approaches (2) and (3).
|
Report
(4 results)
Research Products
(67 results)
-
-
-
-
[Journal Article] Multicomponent Self-Assembly with a Shape Persistent N-Heterotriangulene Macrocycle on Au(111)2015
Author(s)
Kang Cui, Florian Schlutter, Oleksandr Ivasenko, Milan Kivala, Matthias G. Schwab, Shern-Long Lee, Stijn F. L. Mertens, Kazukuni Tahara, Yoshito Tobe, Klaus Mullen, Kunal S. Mali, Steven De Feyter
-
Journal Title
Chemistry: A European Journal
Volume: 21
Issue: 4
Pages: 1652-1659
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
