| Budget Amount *help |
¥18,590,000 (Direct Cost: ¥14,300,000、Indirect Cost: ¥4,290,000)
Fiscal Year 2014: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2012: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
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| Outline of Final Research Achievements |
Sheet-like materials of single atom thickness with periodical internal structures are called two-dimensional polymers and have been attracting a great deal of interest with respect to potential applications. In this project, we investigated the synthesis of two-dimensional polymers via three different pathways, (1) C-C bond formation between the butadiyne units of porous molecular networks formed by self-assembly at the liquid-solid interfaces, (2) imine bond formation between the amino groups installed in the porous network formed at the liquid-solid interfaces and the formyl groups of the co-adsorbed guest molecules, (3) linking the monomers having styryl groups self-assembled at the air-water interfaces forming Langmuir membranes. We found positive results indicative of the formation of two-dimensional polymers in the approaches (2) and (3).
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