| Budget Amount *help |
¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
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| Outline of Final Research Achievements |
In this study, we developed novel sulfur-containing functional polymers by controlled radical polymerization of non-conjugated S-vinyl monomers. Thermoresponsive block copolymers and organic-inorganic hybrids having sulfonic acid groups were synthesized by RAFT polymerization of vinyl sulfonate ester derivatives, followed by deprotection. RAFT polymerization of S-vinyl sulfide derivatives afforded novel sulfur-containing polymers having well-defined structures, block copolymers having two distinct optoelectronic functionalities, alternating copolymers with alternating arrangement of specific functional groups, core cross-linked nanoparticles with π-conjugate cores and thermoresponsive shell, thiazole-containing polymers having the ability to form metal complexations.
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