Development of Functional Solid-state Materials having Molecular-Ordered Phase-Separated Nanostuructures by Designing of POSS-Core Dendrimers
| Project/Area Number |
24350058
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Kyoto Institute of Technology |
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Principal Investigator |
NAKA Kensuke 京都工芸繊維大学, 工芸科学研究科, 教授 (70227718)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2014: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2013: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2012: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000)
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| Keywords | ナノ材料 / 自己組織化 / 超分子化学 / 分子性固体 / 有機導体 |
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| Outline of Final Research Achievements |
We synthesized imidazolium-terminated POSS-core poly(amidoamine)-dendrimers and found that domains similar to a imidazolium-typed ionic lquid formed in the cast films of the dendrimers. They showed high ionic and electronic conductivities. We also synthesized POSS-core dendrimers bearing π-conjugated units on their terminal groups formed thermoplastic transparent free-standing films depending upon their spacer length at room temperature. These findings suggest that the POSS-core dendrimers are ideal candidates for the construction of ordered nano-sized network architectures for solid-sate materials.
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Report
(4 results)
Research Products
(48 results)
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[Journal Article] Synthesis of Imidazolium Salt-Terminated Poly(amidoamine)-Typed POSS-Core Dendrimers and Their Solution and Bulk Properties2014
Author(s)
Naka, K.; Shinke, R.; Yamada, M.; Belkada, F.; Aijo, Y.; Irie, Y. Shankar, S. R.; Smaran, K. S.; Matsumi, N.; Tomita, S.; Sakurai, S.
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Journal Title
Polym. J.
Volume: 46
Issue: 1
Pages: 42-51
DOI
NAID
Related Report
Peer Reviewed
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