Development of Supramolecular Block Copolymers via Unique Molecular Recognition
| Project/Area Number |
24350060
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Hiroshima University |
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Principal Investigator |
HAINO Takeharu 広島大学, 理学(系)研究科(研究院), 教授 (80253053)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2014: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2013: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2012: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
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| Keywords | 超分子化学 / 分子認識 / 高分子化学 / フラーレン / ポルフィリン / 交互共重合体 / ポリマー / 超分子ポリマー / 配列制御 / ブロック共重合体 |
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| Outline of Final Research Achievements |
We developed a methodology that employed our unique host-guest motifs to achieve supramolecular block polymeric assemblies with a high degree of organization. The calix[5]arene-fullerene "ball-and-socket" interaction and molecular associations of bisresorcinarenes were demonstrated to be key intermolecular connections that facilitated supramolecular block copolymerization of monomeric building blocks. We also synthesized white-light-emitting graphene quantum dots via the peripheral functionalization as a new carbon-based functional material.
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Report
(4 results)
Research Products
(145 results)
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[Journal Article] Formation of Host-Guest Complexes on Gold Surface Investigated by Surface-Enhanced IR Absorption Spectroscopy2014
Author(s)
Inokuchi, Y., Mizuuchi, T., Ebata, T., Ikeda, T., Haino, T., Kimura, T., Guo, H., Furutani, Y
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Journal Title
Chem. Phys. Lett
Volume: 592
Pages: 90-95
DOI
NAID
Related Report
Peer Reviewed / Open Access
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[Presentation] 超分子ポリマーの創製2012
Author(s)
灰野岳晴
Organizer
第61回高分子学会年次大会
Place of Presentation
パシフィコ横浜 (神奈川)(招待講演)
Year and Date
2012-05-29
Related Report
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