| Budget Amount *help |
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2014: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2012: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
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| Outline of Final Research Achievements |
The amphiphilic liquid crystalline diblock copolymers having a porphyrin or a rhenium complex at the junction of hydrophilic/hydrophobic segments were synthesized. In this copolymer film, the pigments were arranged along the normally oriented cylindrical phase segregation interfaces to form the periodically standing circular pigment arrays which were subject to the smectic layer structure of hydrophobic liquid crystalline domain. The blend film of these copolymers also gave normally oriented cylindrical nanostructure, in which the photo-induced electron transfer from porphyrins to rhenium complexes was observed.
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