Design of metal complexes with organic ligand bearing photo-sensitive moieties and its application to catalytic transformations
| Project/Area Number |
24350068
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
Yasuda Makoto 大阪大学, 工学(系)研究科(研究院), 教授 (40273601)
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| Project Period (FY) |
2012-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥12,220,000 (Direct Cost: ¥9,400,000、Indirect Cost: ¥2,820,000)
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| Keywords | 錯体 / 光反応 / 反応場 / ルイス酸 / 共役 / 有機合成反応 |
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| Outline of Final Research Achievements |
The boron compounds are abundant but less effective for catalyst. We have synthesized a new boron compounds with cage-shaped organic framework with photo-sensitive moieties. The newly synthesized cage-shaped boron compounds acted as a catalyst for some organic reactions. The selective reaction of aromatic compounds over aliphatic compounds was accomplished due to the pi-pocket moiety around the boron center in the complex. Introduction of benzofuran moiety into cage-shaped borate led to the photo-sensitive catalyst. In fact, irradiation of UV light to the reaction of silly enolate with aldehyde in the presence of the benzofuran-based catalyst made the increased catalytic activity. Irradiation of black-light also increased the yield of the product. The synthesized complexes were fully analyzed by X-ray crystallography and theoretical calculation.
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Report
(5 results)
Research Products
(40 results)
