| Project/Area Number |
24350073
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Kobe University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
TAKAHASHI Kazuyuki 神戸大学, 大学院理学研究科, 准教授 (60342953)
KUWAHARA Daisuke 電気通信大学, 研究設備センター, 准教授 (50270468)
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| Co-Investigator(Renkei-kenkyūsha) |
TAKAHASHI Masashi 東邦大学, 理学部, 教授 (30171523)
FUJIMORI Hiroki 日本大学, 文理学部, 教授 (80297762)
KATO Keisuke 東邦大学, 薬学部, 教授 (80276609)
HAYASHI Masahiko 神戸大学, 大学院理学研究科, 教授 (60192704)
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| Project Period (FY) |
2012-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2012: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
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| Keywords | イオン液体 / 金属錯体 / メタロセン / キレート錯体 / 磁気物性 / 結晶構造 / 熱的性質 / 熱的物性 / 外場応答性 / スピンクロスオーバー / 柔粘性結晶 |
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| Outline of Final Research Achievements |
Functional metal-containing ionic liquids were synthesized from various cationic metal complexes. First, ionic liquids exhibiting vapochromic, magnetic, and other properties were developed from chelate complexes. Second, a series of ionic liquids were synthesized from metallocenium complexes, and their physical properties and chemical reactivities investigated. Correlations between the crystal structures and thermal properties of metallocenium salts were also investigated.
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