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Development of gold nanocluster catalysts with cooperative support materials composed of boron-containing self-assemblies

Research Project

Project/Area Number 24350075
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Functional materials chemistry
Research InstitutionTokyo Metropolitan University

Principal Investigator

KUBO Yuji  首都大学東京, 都市環境科学研究科, 教授 (80186444)

Co-Investigator(Renkei-kenkyūsha) NISHIYABU Ryuhei  首都大学東京, 都市環境科学研究科, 助教 (00432865)
Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,590,000 (Direct Cost: ¥14,300,000、Indirect Cost: ¥4,290,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2013: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2012: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
Keywordsボロン酸 / 自己組織 / 金属ナノ粒子 / 不均一触媒 / 白色発光 / ケモセンサー / ナノサーモメーター / トレーガー塩基 / シンコニジン / シンコニン / 不斉反応 / 貴金属触媒 / バイオリファイナリー / レブリン酸 / 凝集誘起発光 / 白色発光粒子 / ナノサーモメター / 金ナノ粒子 / パラジウムナノ粒子 / 触媒 / グリーン反応 / ホウ素 / ボロン酸エステル
Outline of Final Research Achievements

Sequential dehydration of diboronic acids with polyhydric alcohols gave mono-dispersed boronate fine particles. In this study, our interest for functionalization of the surface led us to deposit nano-metals (Au, Pd, Ru, etc) by deposition reduction method in the presence of polyethyleneimine. The resultant hybrids show efficient catalytic activities for fine chemical reactions. Furthermore, such a reactive surface of boronate fine particles motivated us to graft dyes on the surface, allowing the development white light emissive particles. For this approach, the introduction of cation binding site into the dye grafted endowed the particles with chemosensing capabilities for metal ions. In addition, the use of aggregation-induced emission (AIE)-active units for the particle formation was found to be profitable for the functionalization.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (34 results)

All 2016 2015 2014 2013 2012 Other

All Journal Article (7 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 3 results,  Open Access: 1 results) Presentation (22 results) (of which Invited: 3 results) Book (1 results) Remarks (2 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Water-dispersible boronate self-assemblies as support materials for noble metals in the hydrogenation of levulinic acid to γ-valerolactone2016

    • Author(s)
      Yuji Kubo, Daiki Kakizaki, Makiko Kogo and Yasuhiro Magatani
    • Journal Title

      Supramolecular Chemistry

      Volume: 28 Issue: 1-2 Pages: 91-97

    • DOI

      10.1080/10610278.2015.1086764

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] ボロン酸ユニットを利用した階層化超分子の創製と機能創出2016

    • Author(s)
      久保 由治
    • Journal Title

      超分子研究会アニュアルレビュー

      Volume: 36 Pages: 6-7

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Thermo-responsive white-light emission based on tetraphenylethylene- and rhodamine B-containing boronate nanoparticles2015

    • Author(s)
      Ayumi Ozawa, Ai Shimizu, Ryuhei Nishiyabu and Yuji Kubo
    • Journal Title

      Chemical Communications

      Volume: 51 Issue: 1 Pages: 118-121

    • DOI

      10.1039/c4cc07405j

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hierarchical supramolecules and organization using boronic acids building blocks2015

    • Author(s)
      Yuji Kubo, Ryuhei Nishiyabu and Tony D. James
    • Journal Title

      Chemical Communications

      Volume: 51 Issue: 11 Pages: 2005-2020

    • DOI

      10.1039/c4cc07712a

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Boronate microparticle-supported nano-palladium and nano-gold catalysts for chemoselective hydrogenation of cinnamaldehyde in environmentally preferable solvents2014

    • Author(s)
      Seika Fujiwara, Naoto Takanashi, Ryuhei Nishiyabu and Yuji Kubo
    • Journal Title

      Green Chemistry

      Volume: 16 Issue: 6 Pages: 3230-3236

    • DOI

      10.1039/c4gc00383g

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] White-light emitting boronate microparticles for potential use as reusable bright chemosensors in water2013

    • Author(s)
      Ryuhei Nishiyabu, Yasuyuki Sugino and Yuji Kubo
    • Journal Title

      Chemical Communications

      Volume: 49 Pages: 9869-9871

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Boronate self-assemblies with embedded Au nanoparticles; preparation, characterization and their catalytic activities for the reduction of nitroaromatic compounds2012

    • Author(s)
      Y. Matsushima, R. Nishiyabu, N. Takanashi, M. Haruta, H. Kimura, and Y. Kubo
    • Journal Title

      Journal of Material Chemistry

      Volume: 22 Issue: 45 Pages: 24124-24131

    • DOI

      10.1039/c2jm34797k

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] AIE特性を持つボロネートナノ粒子の調製と白色発光ナノサーモメーターへの応用2015

    • Author(s)
      小澤歩未・西藪隆平・久保由治
    • Organizer
      第42有機典型元素化学討論会
    • Place of Presentation
      名古屋大学野依記念学術交流館(名古屋市千種区)
    • Year and Date
      2015-12-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] ルテニウム担持型ボロネートナノ粒子を触媒利用したレブリン酸の水素化反応2015

    • Author(s)
      柿崎大樹・藤原成香・西藪隆平久保由治・古後真紀子・萬ヶ谷康弘
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 光学活性酒石酸から誘導される AIE ボロン酸エステル会合体の性質2015

    • Author(s)
      中本昇吾・小澤歩未・藤原成香・西藪隆平・久保由治
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2015-03-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] 熱応答性を示す白色発光型ボロン酸エステル粒子の調製2015

    • Author(s)
      小澤歩未・清水藍・西藪隆平・久保由治
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2015-03-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] ボロン酸に基づく階層横断的自己集合現象とその機能化2014

    • Author(s)
      久保由治
    • Organizer
      平成26年度第2回材料・製造フォーラム「光分子工学」分科会
    • Place of Presentation
      産総研つくば中央第5事業所
    • Year and Date
      2014-12-15
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 水分散性ボロネートマイクロ粒子の表面機能化2014

    • Author(s)
      藤原成香・杉野康行・西藪隆平・久保由治
    • Organizer
      第12回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2014-06-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] AIE 型ボロネートナノ粒子の調製とその性質2014

    • Author(s)
      小澤歩未・杉野康行・西藪隆平・久保由治
    • Organizer
      第12回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2014-05-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] ニトロフェノール還元に対して触媒活性を有するナノゴールド担持ボロネート自己集合体2013

    • Author(s)
      高梨直人,西藪隆平,久保由治
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス
    • Year and Date
      2013-03-23
    • Related Report
      2012 Annual Research Report
  • [Presentation] 種々の形態をもつナノゴールド担持ボロネート自己集合体の調製2013

    • Author(s)
      関雄太,高梨直人,松島由祐,西藪隆平,久保由治
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス
    • Year and Date
      2013-03-23
    • Related Report
      2012 Annual Research Report
  • [Presentation] ボロネート自己組織体を担体利用する金ナノ粒子触媒の調製2012

    • Author(s)
      高梨直人,松島由祐,西藪隆平,久保由治
    • Organizer
      第2回CSJ化学フェスタ
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2012-10-15
    • Related Report
      2012 Annual Research Report
  • [Presentation] 金ナノ粒子担持型ボロネート自己組織体の調製とその触媒機能2012

    • Author(s)
      松島由祐,西藪隆平,高梨直人,春田正毅,久保由治
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2012-09-25
    • Related Report
      2012 Annual Research Report
  • [Presentation] Boronate self-assemblies with embedded Au nanoparticles that serve as chemoselective catalyst for the reduction of nitroaromatic compound2012

    • Author(s)
      Y. Matsushima, R. Nishiyabu, M.Haruta, Y. Kubo
    • Organizer
      The 6th International Conference of Gold Science and Its Applications
    • Place of Presentation
      Keio Plaza Hotel
    • Year and Date
      2012-09-06
    • Related Report
      2012 Annual Research Report
  • [Presentation] ボロネートマイクロ粒子担持金ナノクラスターの調製とその触媒機能2012

    • Author(s)
      松島由祐,西藪隆平,春田正毅,久保由治
    • Organizer
      第9回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      北海道大学
    • Year and Date
      2012-05-26
    • Related Report
      2012 Annual Research Report
  • [Presentation] Boronate microparticles: preparation, characterization, and functionalization

    • Author(s)
      Yuji Kubo
    • Organizer
      Third Biannual Conference on Catalysis and Sensing for the Environment (CASE)
    • Place of Presentation
      Austin, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] A boronate self-assemble with embedded Au nanoparticles: preparation, characterization, and the catalytic activity

    • Author(s)
      Ryuhei Nishiyabu and Yuji Kubo
    • Organizer
      15th Asian Chemical Congress 2013
    • Place of Presentation
      Singapore
    • Related Report
      2013 Annual Research Report
  • [Presentation] ボロネートマイクロ粒子の界面機能化に基づく白色発光ケモセンサーの開発

    • Author(s)
      杉野康行・藤原成香・西藪隆平・久保由治
    • Organizer
      第24回基礎有機化学論会
    • Place of Presentation
      学習院大学目白キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] Boronate self-assembles; from sensor ensembles to microparticles

    • Author(s)
      Yuji Kubo
    • Organizer
      Chemonostics: Chemical receptors in the development of simple diagnostic devices
    • Place of Presentation
      Bath, UK
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] ボロネートマイクロ粒子の界面機能化に基づく白色発光ケモセンサー

    • Author(s)
      杉野康行・西藪隆平・久保由治
    • Organizer
      第40回 有機典型元素化学討論会
    • Place of Presentation
      近畿大学11月ホール
    • Related Report
      2013 Annual Research Report
  • [Presentation] AIE 型ボロネートナノ粒子の調製と物性評価

    • Author(s)
      小澤歩未・杉野康行・西藪隆平・久保由治
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] 蛍光色素をグラフトさせたボロネートマイクロ粒子の合成と性質

    • Author(s)
      神谷夕夏・杉野康行・善積貴也・西藪隆平・久保由治
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] パラジウム担持型ボロネートマイクロ粒子の合成とその触媒機能

    • Author(s)
      藤原成香・西藪隆平・久保由治
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] テトラフェニルエチレンを成分とするボロネートナノロッドの調製とマルチカラー発光

    • Author(s)
      杉野康行・清水藍・西藪隆平・久保由治
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Related Report
      2013 Annual Research Report
  • [Book] Boron; Sensing, Synthesis and Supramolecular Self-assembly2016

    • Author(s)
      Yuji Kubo and Ryuhei Nishiyabu
    • Total Pages
      416
    • Publisher
      The Royal Society of Chemistry
    • Related Report
      2015 Annual Research Report
  • [Remarks] 首都大学東京 大学院都市環境科学研究科 分子応用化学域 久保研究室

    • URL

      http://www.comp.tmu.ac.jp/kubolab/kubolabtop.html

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
  • [Remarks] 首都大学東京 都市環境科学研究科 都市環境科学環 分子応用化学域 久保研究室

    • URL

      http://www.comp.tmu.ac.jp/kubolab/kubolabtop.html

    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] ボロン酸エステル型高分子を担体とする触媒及びそれを用いたγ-バレロラクトン等の製造2015

    • Inventor(s)
      久保由治・西藪隆平・萬ヶ谷康弘
    • Industrial Property Rights Holder
      公立大学法人首都大学東京・日本化薬株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-041342
    • Filing Date
      2015-03-03
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] パラジウム粒子を有機高分子化合物に担持した複合体2014

    • Inventor(s)
      久保由治,西藪隆平,酒井亮,海寳篤志,萬ヶ谷康弘
    • Industrial Property Rights Holder
      公立大学法人首都大学東京,日本化薬株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-047843
    • Filing Date
      2014-03-11
    • Related Report
      2013 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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