Fabrication of new materials from biomass by meso crystalization

• Project/Area Number: 24350119
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Polymer/Textile materials
• Research Institution: Kyoto University
• Principal Investigator: KIMURA Tsunehisa 京都大学, (連合)農学研究科(研究院), 教授 (40264593)
• Co-Investigator(Renkei-kenkyūsha): KUSUMI Ryosuke 京都大学, 大学院農学研究科, 助教 (70546530) ; KIMURA Fumiko 京都大学, 大学院農学研究科, 研究員 (40425559)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥12,480,000 (Direct Cost: ¥9,600,000、Indirect Cost: ¥2,880,000); Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000); Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000); Fiscal Year 2012: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
• Keywords: 擬単結晶 / セルロース / 磁気プロセッシング / 三次元配向 / 結晶構造解析 / 中性子回折 / メソクリスタル

Outline of Final Research Achievements

Fabrication of anisotropic new materials using biomass and biomaterial was carried out by the means of magnetic processing. (1)Basic data for cellulose crystal structure was obtained. We elucidated that corelation length of cellulose whisker is different depending on their origins. Alignment of cellulose chiral nematic phase using magnetic processing was performed and we also carried out three dimensional alignment of cellulose nanocrystals. (2)A new method for fabrication of pseudo single crystals has been established. We changed the dispersive materials from UV curable monomer to gel material and we succeeded to determine the crystal structure of a protein. We also obtained high-resolution X-ray diffraction images without solidification of samples. Determination of the crystal structure using pseudo single crystal without solidification of suspended media was also achieved successfully.

Research Products

• [Journal Article] Magnetic Alignments of Endohedral Metallofullerene Nanorods under Magnetic Fields (2015)
  • Author(s): M. O. Ishitsuka, H. Nikawa, N. Mizorogi, F. Kimura, T. Kimura, T. Kato, S. Nagase, T. Akasaka
  • Journal Title: Fullerenes, Nanotubes, Carbon Nanostruct. Volume: 23 Issue: 1 Pages: 35-39
  • DOI: 10.1080/1536383x.2012.749461
  • Peer Reviewed
• [Journal Article] etermination of anisotropic magnetic susceptibility of a biaxial crystal via orientational fluctuation of its microcrystalline suspension under magnetic field (2014)
  • Author(s): K. Matsumoto, K. Fujita, T. Tanaka, F. Kimura, and T. Kimura
  • Journal Title: Jpn. J. Appl. Phys. Volume: 53 Issue: 5 Pages: 055501-055501
  • DOI: 10.7567/jjap.53.055501
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Crystal System Determination from X‐ray Diffraction of Magnetically Oriented Microcrystal Suspensions (2014)
  • Author(s): K. Matsumoto, F. Kimura, G. Song, S. Yamane, H. Kikuchi, T. Tanaka, S. Higuchi, N. Kitamura, and T. Kimura
  • Journal Title: Cryst. Growth Des. Volume: 14 Issue: 12 Pages: 6486-6491
  • DOI: 10.1021/cg501357b
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Single crystal structure analysis via magnetically oriented microcrystal arrays (2014)
  • Author(s): F. Kimura, W. Oshima, H. Matsumoto, H. Uekusa, K. Aburaya, M. Maeyama, and T. Kimura
  • Journal Title: CrystEngComm Volume: 16 Issue: 29 Pages: 6630-6634
  • DOI: 10.1039/c4ce00839a
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Anisotropic Polymer Composites Synthesized by Immobilizing Cellulose Nanocrystal Suspensions Specifically Oriented under Magnetic Fields (2014)
  • Author(s): M. Tatsumi, F. Kimura, T. Kimura, Y. Teramoto, and Y. Nishio
  • Journal Title: Biomacromolecules Volume: 15 Issue: 12 Pages: 4579-4589
  • DOI: 10.1021/bm501629g
  • Peer Reviewed
• [Journal Article] Strong Highly Anisotropic Magnetocellulose Nanocomposite Films Made by Chemical Peeling and In Situ Welding at the Interface Using an Ionic Liquid (2014)
  • Author(s): M. Mashkour, M. Tajvidi, F. Kimura, H. Yousefi, and T. Kimura
  • Journal Title: ACS Appl. Mater. Interfaces Volume: 5 Issue: 11 Pages: 8165-8172
  • DOI: 10.1021/am500709t
  • Peer Reviewed
• [Journal Article] One-dimensional core-shell cellulose-akaganeite hybrid nanocrystals: synthesis, characterization, and magnetic field induced self-assembly (2014)
  • Author(s): M. Mashkour, T. Kimura, F. Kimura, M. Mashkour, and M. Tajvidi
  • Journal Title: RSC Adv. Volume: 4 Issue: 94 Pages: 52542-52549
  • DOI: 10.1039/c4ra09468a
  • Peer Reviewed
• [Journal Article] Tunable Self-Assembly of Cellulose Nanowhiskers and Polyvinyl Alcohol Chains Induced by Surface Tension Torque (2014)
  • Author(s): M. Mashkour, T. Kimura, F. Kimura, M. Mashkour, and M. Tajvidi
  • Journal Title: Biomacromolecules Volume: 15 Issue: 1 Pages: 60-65
  • DOI: 10.1021/bm401287s
  • Peer Reviewed
• [Journal Article] Synchrotron Microscopic Fourier Transform Infrared Spectroscopy Analyses of Biogenic Guanine Crystals Along Axes of Easy Magnetization (2014)
  • Author(s): Y. Mizukawa, Y. Ikemoto, T. Moriwaki, T. Kinoshita, F. Kimura, T. Kimura and M. Iwasaka
  • Journal Title: IEEE Transactions on Magnetics Volume: 50 Issue: 11 Pages: 5001804-5001804
  • DOI: 10.1109/tmag.2014.2329239
  • Peer Reviewed
• [Journal Article] Orientational Distribution of Cellulose Nanocrystals in a Cellulose Whisker As Studied by Diamagnetic Anisotropy (2013)
  • Author(s): G. Song, F. Kimura, T. Kimura, and G. Piao
  • Journal Title: Macromolecules Volume: 46 Pages: 8957-8963
  • Peer Reviewed
• [Journal Article] Optimum Conditions of Dynamic Fields for the Three-Dimensional Magnetic Alignment of Magnetically Biaxial Particles (2013)
  • Author(s): M. Yamaguchi, I. Yamamoto, and T. Kimura
  • Journal Title: Jpn. J. Appl. Phys. Volume: 52 Pages: 98003-98003
  • NAID: 40019796455
  • Peer Reviewed
• [Journal Article] Orientation Fluctuation of Microcrystals under Three-Dimensionally Constraining Dynamic Magnetic Fields (2013)
  • Author(s): T. Kimura, T. Tanaka, G.J. Song, K. Matsumoto, K. Fujita, and F. Kimura
  • Journal Title: Cryst. Growth Des. Volume: 13 Pages: 1815-1819
  • Peer Reviewed
• [Journal Article] Characterization of Three-Dimensional Magnetic Alignment for Magnetically Biaxial Particles (2013)
  • Author(s): M. Yamaguchi, S. Ozawa, I. Yamamoto, and T. Kimura
  • Journal Title: Jpn. J. Appl. Phys. Volume: 52 Pages: 13003-13003
  • NAID: 210000141732
  • Peer Reviewed
• [Journal Article] Determination of Anisotropic Diamagnetic Susceptibility Using X-ray Diffraction (2012)
  • Author(s): T. Kimura, G. Song, K. Matsumoto, K. Fujita, and F. Kimura
  • Journal Title: Jpn. J. Appl. Phys. Volume: 51 Issue: 4R Pages: 40202-4
  • DOI: 10.1143/jjap.51.040202
  • NAID: 210000140392
  • Peer Reviewed
• [Journal Article] Magnetic Alignment of Magnetically Blaxial Diamagnetic Rods Under Rotating Magnetic Fields (2012)
  • Author(s): S. Tsukui and T. Kimura
  • Journal Title: Jpn. J. Appl. Phys. Volume: 51 Issue: 5R Pages: 57301-4
  • DOI: 10.1143/jjap.51.057301
  • Peer Reviewed
• [Journal Article] Determination of Ratio of Diamagnetic Anisotropy of a Biaxial Crystal by X-ray Diffraction Measurement (2012)
  • Author(s): Guangjie Song, Kenji Matsumoto, Keiji Fuiita, Fumikn Kimura, Tsunehisa.
  • Journal Title: Japanese Journal of Applied Physics Volume: 51 Issue: 6R Pages: 60203-5
  • DOI: 10.1143/jjap.51.060203
  • Peer Reviewed
• [Journal Article] Chemical shift tensor determination using magnetically oriented microcrystal array (MOMA): 13C solid-state CP NMR without MAS (2012)
  • Author(s): R. Kusumi, F. Kimura, G. Song, T. Kimura
  • Journal Title: Journal of Magnetic Resonance Volume: 223 Pages: 68-72
  • DOI: 10.1016/j.jmr.2012.08.006
  • Peer Reviewed
• [Presentation] 磁場配向微結晶試料を用いたセロビオースの単結晶NMR解析 (2014)
  • Author(s): 宋广杰, 久住亮介, 木村史子, 木村恒久, 出口健三, 大木忍, 藤戸輝昭, 清水禎
  • Organizer: 日本核磁気共鳴学会 第53回NMR討論会
  • Place of Presentation: 大阪
  • Year and Date: 2014-11-04 – 2014-11-06
• [Presentation] 磁場配向微結晶粉末を用いた単結晶NMR測定 (2014)
  • Author(s): 木全美香子, 久住亮介, 木村史子, 木村恒久
  • Organizer: 日本核磁気共鳴学会 第53回NMR討論会
  • Place of Presentation: 大阪
  • Year and Date: 2014-11-04 – 2014-11-06
• [Presentation] 三次元磁場配向した微結晶粉末からのX線単結晶構造解析手法の確立 (2014)
  • Author(s): 坪井千明, 樋口慎吾, 油家一晃, 木村史子, 前山正孝, 木村恒久
  • Organizer: 平成26年度日本結晶学会年会
  • Place of Presentation: 東京
  • Year and Date: 2014-11-01 – 2014-11-03
• [Presentation] 三次元磁場配向による生体高分子微結晶の構造解析 (2014)
  • Author(s): 津久井秀, 木村史子, 藤橋雅宏, 三上文三, 三木邦夫, 木村恒久
  • Organizer: 平成26年度日本結晶学会年会
  • Place of Presentation: 東京
  • Year and Date: 2014-11-01 – 2014-11-03
• [Presentation] 磁場配向を用いた粉末試料の結晶系、格子定数の推定法 (2014)
  • Author(s): 松本賢司, 木村史子, 宋广杰, 山根周平, 樋口慎悟, 北村直之, 木村恒久
  • Organizer: 平成26年度日本結晶学会年会
  • Place of Presentation: 東京
  • Year and Date: 2014-11-01 – 2014-11-03
• [Presentation] X-Ray Diffraction of Magnetically Oriented Microcrystals of Protein (2014)
  • Author(s): S. Tsukui, F. Kimura, K. Mizutani, B. Mikami, T. Kimura
  • Organizer: 23rd Congress and General Assembly of the International Union of Crystallography (IUCr2014)
  • Place of Presentation: Montreal, Canada
  • Year and Date: 2014-08-05 – 2014-08-12
• [Presentation] X-Ray Single Crystal Structural Analysis of Magnetically Oriented Microcrystals (2014)
  • Author(s): C. Tsuboi, K. Aburaya, S. Higuchi, F. Kimura, M. Maeyama, T. Kimura
  • Organizer: 23rd Congress and General Assembly of the International Union of Crystallography (IUCr2014)
  • Place of Presentation: Montreal, Canada
  • Year and Date: 2014-08-05 – 2014-08-12
• [Presentation] Determination of Crystal System from Microcrystalline Powde (2014)
  • Author(s): T. Kimura, K. Matsumoto, F. Kimura
  • Organizer: 23rd Congress and General Assembly of the International Union of Crystallography (IUCr2014)
  • Place of Presentation: Montreal, Canada
  • Year and Date: 2014-08-05 – 2014-08-12
• [Presentation] X-Ray Diffraction from Magnetically Oriented Microcrystal Suspension (2014)
  • Author(s): K. Aburaya, C. Tsuboi, F. Kimura, K. Matsumoto, M. Maeyama, T. Kimura
  • Organizer: 23rd Congress and General Assembly of the International Union of Crystallography (IUCr2014)
  • Place of Presentation: Montreal, Canada
  • Year and Date: 2014-08-05 – 2014-08-12
• [Presentation] Single Crystal Solid-State NMR of Magnetically Oriented Powder (2014)
  • Author(s): R. Kusumi, F. Kimura, T. Kimura
  • Organizer: 23rd Congress and General Assembly of the International Union of Crystallography (IUCr2014)
  • Place of Presentation: Monteal, Canada
  • Year and Date: 2014-08-05 – 2014-08-12
• [Presentation] Crystal Structure Analysis of Magnetically Oriented D-Arabinitol Microcrystal (2014)
  • Author(s): S. Yamane, K. Matsumoto, F. Kimura, T. Kimura
  • Organizer: 23rd Congress and General Assembly of the International Union of Crystallography (IUCr2014)
  • Place of Presentation: Montreal, Canada
  • Year and Date: 2014-08-05 – 2014-08-12
• [Presentation] Magnetically Oriented Powder Crystal to Indexing and Structure Determination (2014)
  • Author(s): F. Kimura, W. Oshima, H. Matsumoto, H. Uekusa, K. Aburaya, M. Maeyama, T. Kimura
  • Organizer: 23rd Congress and General Assembly of the International Union of Crystallography (IUCr2014)
  • Place of Presentation: Montreal, Canada
  • Year and Date: 2014-08-05
• [Presentation] セルロース微結晶の磁場による一軸配向化と化学シフトテンソル解析 (2014)
  • Author(s): 久住亮介, 木村史子, 木村恒久
  • Organizer: セルロース学会第21回年次大会
  • Place of Presentation: 鹿児島
  • Year and Date: 2014-07-17 – 2014-07-18
• [Presentation] セルロース微結晶キラルネマチック相に及ぼす界面活性剤の効果 (2014)
  • Author(s): 祖父江尚也, 木村史子, 木村恒久
  • Organizer: セルロース学会第21回年次大会
  • Place of Presentation: 鹿児島
  • Year and Date: 2014-07-17 – 2014-07-18
• [Presentation] In-situ X-ray Diffraction Measurements Using Magnetically Oriented Microcrystal Suspension of L-Alanine (2013)
  • Author(s): F. Kimura, K. Matsumoto, C. Tsuboi, S. Tsukui, and T. Kimura
  • Organizer: International Conference on Magneto-Science 2013
  • Place of Presentation: Bordeaux, France
  • Invited
• [Presentation] Magnetically Oriented Microcrystal Array: Complete Characterization of Chemical Shift Anisotropy from Microcrystalline Powder (2013)
  • Author(s): R. Kusumi, F. Kimura, and T. Kimura
  • Organizer: International Conference on Magneto-Science 2013
  • Place of Presentation: Bordeaux, France
• [Presentation] Anisotropic Fluctuation of Crystallographic Axes under Three-Dimensionally Constraining Dynamic Magnetic Field (2013)
  • Author(s): T. Tanaka and T. Kimura
  • Organizer: International Conference on Magneto-Science 2013
  • Place of Presentation: Bordeaux, France
• [Presentation] Solid-state NMR Study on 13C Chemical Shift Tensor of Magnetically Oriented Microcrystal Array of Cellobiose (2013)
  • Author(s): G. Song, R. Kusumi, F. Kimura, and T. Kimura
  • Organizer: International Conference on Magneto-Science 2013
  • Place of Presentation: Bordeaux, France
• [Presentation] In-situ X-ray Diffraction Measurements of Three Dimensional Magnetically Oriented Microcrystal Suspension (2013)
  • Author(s): C. Tsuboi, F. Kimura, and T. Kimura
  • Organizer: International Conference on Magneto-Science 2013
  • Place of Presentation: Bordeaux, France
• [Presentation] X-ray Diffraction Analysis of Magnetically Oriented Microcrystal Array of Lysozyme (2013)
  • Author(s): S. Tsukui, F. Kimura, K. Mizutani, B. Mikami, and T. Kimura
  • Organizer: International Conference on Magneto-Science 2013
  • Place of Presentation: Bordeaux, France
• [Presentation] Crystal Structure Analysis by In-situ X-ray Diffraction Measurement of Magnetically Oriented Microcrystal Suspension (2013)
  • Author(s): K. Matsumoto, F. Kimura, and T. Kimura
  • Organizer: International Conference on Magneto-Science 2013
  • Place of Presentation: Bordeaux, France
• [Presentation] Orientation Fluctuation of Microcrystals Under Frequency-Modulated Magnetic Fields (2013)
  • Author(s): K. Fujita, F. Kimura, and T. Kimura
  • Organizer: International Conference on Magneto-Science 2013
  • Place of Presentation: Bordeaux, France
• [Presentation] Preparation of Magnetically Oriented Green Compact of Amino Acid (2013)
  • Author(s): M. Ishibashi, F. Kimura, and T. Kimura
  • Organizer: International Conference on Magneto-Science 2013
  • Place of Presentation: Bordeaux, France
• [Presentation] Determination of Chemical Shift Tensor of L-Threonine Using Magnetically Oriented Microcrystal Array (2013)
  • Author(s): M. Kimata, R. Kusumi, F. Kimura, and T. Kimura
  • Organizer: International Conference on Magneto-Science 2013
  • Place of Presentation: Bordeaux, France
• [Presentation] Magnetic-field Responsive Material That Exhibits Twist Deformation (2013)
  • Author(s): Y. Yamamoto, F. Kimura, and T. Kimura
  • Organizer: International Conference on Magneto-Science 2013
  • Place of Presentation: Bordeaux, France
• [Presentation] 13C Chemical shift tensor analysis of cellobiose pseudo single crystal by solid-state NMR (2013)
  • Author(s): 宋广杰, 久住亮介, 木村史子, 木村恒久
  • Organizer: セルロース学会第20回年次大会
  • Place of Presentation: 京都大学
• [Presentation] 磁化率異方性から見たセルロースウィスカー中の微結晶の配向分布 (2013)
  • Author(s): 宋广杰, 木村恒久, 木村史子, 朴光哲
  • Organizer: セルロース学会第20回年次大会
  • Place of Presentation: 京都大学
• [Presentation] 非MAS下での固体NMRによるセルロース繊維の構造解析 (2013)
  • Author(s): 久住亮介, 宋广杰, 木村史子, 木村恒久
  • Organizer: セルロース学会第20回年次大会
  • Place of Presentation: 京都大学
• [Presentation] 磁場配向を用いたセルロース系複合材料の光学特性 (2013)
  • Author(s): 徳永志帆, 木村史子, 久住亮介, 木村恒久
  • Organizer: セルロース学会第20回年次大会
  • Place of Presentation: 京都大学
• [Presentation] In-situ X線回折測定を用いた二軸性微結晶の磁化率異方性測定 (2012)
  • Author(s): 松本賢司,木村史子,木村恒久
  • Organizer: 第7回日本磁気科学会年会
  • Place of Presentation: 京都大学(京都府)
  • Year and Date: 2012-11-22
• [Presentation] 3次元配向微結晶懸濁液のin-situ X線回折測定 (2012)
  • Author(s): 坪井千明, 樋口慎悟, 木村史子, 木村恒久
  • Organizer: 第7回日本磁気科学会年会
  • Place of Presentation: 京都大学(京都府)
  • Year and Date: 2012-11-22
• [Presentation] 3次元磁気配向の挙動 (2012)
  • Author(s): 山口益弘, 山本勲, 木村恒久
  • Organizer: 第7回日本磁気科学会年会
  • Place of Presentation: 京都大学(京都府)
  • Year and Date: 2012-11-22
• [Presentation] X線回折測定を用いた二軸性結晶の異方性磁化率比の導出 (2012)
  • Author(s): 藤田敬士, 木村史子, 木村恒久
  • Organizer: 第7回日本磁気科学会年会
  • Place of Presentation: 京都大学(京都府)
  • Year and Date: 2012-11-22
• [Presentation] L-トレオニン擬単結晶の化学シフトテンソルの決定 (2012)
  • Author(s): 木全美香子, 久住亮介, 木村史子, 木村恒久
  • Organizer: 第7回日本磁気科学会年会
  • Place of Presentation: 京都大学(京都府)
  • Year and Date: 2012-11-22
• [Presentation] 3次元拘束磁場下ての二軸性徴結晶の配向ゆらきに関する研究 (2012)
  • Author(s): 田中達也, 木村恒久
  • Organizer: 第7回日本磁気科学会年会
  • Place of Presentation: 京都大学(京都府)
  • Year and Date: 2012-11-22
• [Presentation] 構造解析を目的とした微結晶懸濁液のin-situ X線回折測定 (2012)
  • Author(s): 樋口慎悟, 坪井千明, 木村史子, 木村恒久
  • Organizer: 第7回日本磁気科学会年会
  • Place of Presentation: 京都大学(京都府)
  • Year and Date: 2012-11-22
• [Presentation] 静磁場下吸引ろ過による一軸配向L-トリプトファンクリーンコンパクトの作製 (2012)
  • Author(s): 石橋美晴, 木村史子, 木村恒久
  • Organizer: 第7回日本磁気科学会年会
  • Place of Presentation: 京都大学(京都府)
  • Year and Date: 2012-11-22
• [Presentation] Correlation Length of Orientation of Microcrystals in a Cellulose Microfiber Investigated by Means of Anisotropic Magnetic Susceptibility (2012)
  • Author(s): 宋广杰, 木村史子, 木村恒久
  • Organizer: 第7回日本磁気科学会年会
  • Place of Presentation: 京都大学(京都府)
  • Year and Date: 2012-11-22
• [Presentation] 31P固体CP NMR 法によるフェニルホスホン酸擬単結晶の化学シフトテンソル解析 (2012)
  • Author(s): 久住亮介, 木村史子, 木村恒久
  • Organizer: 第7回日本磁気科学会年会
  • Place of Presentation: 京都大学(京都府)
  • Year and Date: 2012-11-22
• [Presentation] In-situ X線回折測定を利用した微結晶の磁化率異方性測定 (2012)
  • Author(s): 松本賢司, 木村恒久
  • Organizer: 平成24年度日本結晶学会年会
  • Place of Presentation: 東北大学(仙台)
  • Year and Date: 2012-10-25
• [Presentation] X線回折測定による二軸性結晶の異方性磁化率比の導出 (2012)
  • Author(s): 藤田敬士, 木村史子, 木村恒久
  • Organizer: 平成24年度日本結晶学会年会
  • Place of Presentation: 東北大学(仙台)
  • Year and Date: 2012-10-25
• [Book] Chapter 9 in Advances in Organic Chemistry: Comprihensive Review 2015 (2015)
  • Author(s): T. Kimura
  • Total Pages: 300
  • Publisher: Springer
• [Remarks] 配向が制御されたセルロース系材料の創成
  • URL: http://www.fiber.kais.kyoto-u.ac.jp/html/Research2.html#Theme1
• [Remarks] 粉末微結晶の単結晶構造解析
  • URL: http://www.fiber.kais.kyoto-u.ac.jp/html/Research2.html#Theme3
• [Remarks] 京都大学大学院農学研究科 森林科学専攻 生物繊維学分野
  • URL: http://www.fiber.kais.kyoto-u.ac.jp/html/Research2.html