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Creation of growth technique for high-quality zinc oxide thin films using catalytically generated high-energy H2O beam

Research Project

Project/Area Number 24360014
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionNagaoka University of Technology

Principal Investigator

YASUI Kanji  長岡技術科学大学, 工学(系)研究科(研究院), 教授 (70126481)

Co-Investigator(Kenkyū-buntansha) UMEMOTO Hironobu  静岡大学, 工学部, 教授 (80167288)
SHIMIZU Hidehiko  新潟大学, 自然科学系, 准教授 (00313502)
Co-Investigator(Renkei-kenkyūsha) KATO Takahiro  長岡技術科学大学, 工学部, 助教
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥19,370,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥4,470,000)
Fiscal Year 2014: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2012: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
Keywords化学気相堆積法 / 触媒反応 / 酸化亜鉛薄膜 / 酸化亜鉛 / 薄膜
Outline of Final Research Achievements

Aiming at the fabrication of next-generation ultraviolet laser diodes and light-emitting diodes, creation of growth technique for high-quality zinc oxide thin films using catalytically generated high-energy H2O beam was conducted. As a result, zinc oxide thin films with the high electron mobility greater than 200 cm2/Vs were obtained. By the oxynitrogen gas addition during the ZnO film growth, the decrease in the electron concentration and an observation of neutral acceptor bound exiton emissions. The possibility of the fabrication on p-type zinc oxide films by nitrogen doping was confirmed. By the observation of the H2O beam energy in an adiabatic expansion expansion process in the reaction space, the difference in the beam energy dependent on angular aperture of the nozzles was confirmed.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (44 results)

All 2015 2014 2013 2012 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results,  Acknowledgement Compliant: 2 results) Presentation (35 results) (of which Invited: 4 results) Remarks (1 results)

  • [Journal Article] Effects of N2O addition on the properties of ZnO thin films grown using high-temperature H2O generated by catalytic reaction2014

    • Author(s)
      N. Yamaguchi, E. Nagatomi, T. Kato, K. Ohishi, Y. Tamayama, and K. Yasui
    • Journal Title

      MRS Proceedings

      Volume: 1633 Pages: 61-67

    • DOI

      10.1557/opl.2014.20

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Influence of sputtered buffer layer on the characteristics of ZnO:Al films grown on glass substrates using high-temperature H2O generated by a catalytic reaction2014

    • Author(s)
      Tomoya Nishiyama, Kazuki Takezawa, Yuta Nakazawa, Takahiro Oyanagi, Takahiro Kato, Koichiro Oishi, Susumu Nakamura, and Kanji Yasui
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 2S Pages: 02BC02-02BC02

    • DOI

      10.7567/jjap.53.02bc02

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Influence of sputtered buffer layer on the characteristics of ZnO:Al films grown on glass substrates using high-temperature H2O generated by a catalytic reaction2014

    • Author(s)
      Tomoya Nishiyama , Kazuki Takezawa, Yuta Nakazawa, Takahiro Oyanagi, Takahiro Kato, Koichiro Oishi, Susumu Nakamura, Kanji Yasui
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Properties of zinc oxide films grown on sapphire substrates using high-temperature H2O generated by a catalytic reaction on platinum nanoparticles2014

    • Author(s)
      Kanji Yasui, Tomohiko Takeuchi, Eichi Nagatomi, Souichi Satomoto, Hitoshi Miura, Takahiro Kato
    • Journal Title

      Journal of Vacuum Science & Technology A

      Volume: 32 Issue: 2

    • DOI

      10.1116/1.4831969

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrical properties of ZnO thin films grown on a-plane sapphire substrates using catalytically generated high-energy H2O2013

    • Author(s)
      N. Yamaguchi, T. Takeuchi, E. Nagatomi, T. Kato, H. Umemoto, Kanji Yasui
    • Journal Title

      Thin Solid Films

      Volume: 549 Pages: 18-21

    • DOI

      10.1016/j.tsf.2013.06.035

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrical properties of zinc oxide thin films deposited using high-energy H2O generated from a catalytic reaction on platinum nanoparticles2013

    • Author(s)
      Kanji Yasui, Naoya Yamaguchi, Eichi Nagatomi, Souichi Satomoto, Takahiro Kato
    • Journal Title

      MRS Symposium Proceedings

      Volume: 1494 Pages: 127-132

    • DOI

      10.1557/opl.2013.240

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrical properties of zinc oxide thin films deposited using high-energy H_2O generated from a catalytic reaction on platinum nanoparticles2013

    • Author(s)
      Kanji Yasui, Naoya Yamaguchi, Eichi Nagatomi, Soichi Satomoto, Takahiro Kato
    • Journal Title

      MRS Symposium Proceedings

      Volume: (in press)

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optical properties of ZnO thin films grown on glass substrates using catalytically generated high-temperature H_2O2012

    • Author(s)
      Eichi Nagatomi, Soichi Satomoto, Masami Tahara, Takahiro Kato, Kanji Yasui
    • Journal Title

      Surface & Coatings Technology

      Volume: 215 Pages: 148-151

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Influence of oxynitrogen gas addition on the properties of ZnO thin films on a-Al2O3 grown by catalytic reaction assisted chemical vapor deposition2015

    • Author(s)
      Y. Ishidzuka, Y. Ohashi, N. Yamaguchi, Y. Tamayama, T. Kato, K. Yasui
    • Organizer
      2015 MRS Spring Meeting
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2015-04-06 – 2015-04-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] ZnO film growth using catalytic reaction assisted chemical vapor deposition2014

    • Author(s)
      Kanji Yasui
    • Organizer
      1st European MRS-MRS Japan Joint Symposium
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2014-12-10 – 2014-12-12
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Distribution of dislocations in ZnO thin films grown on a-plane sapphire substrates using high-temperature H2O produced by a Pt-catalyzed H2-O2 reaction2014

    • Author(s)
      Tomoki Nakaura, Masataka Tomita, Yasuhiro Tamayama, Kanji Yasui
    • Organizer
      1st European MRS-MRS Japan Joint Symposium 2014
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2014-12-10 – 2014-12-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] Influence of N2O addition on the properties of ZnO thin films grown on a-Al2O3 using high-temperature H2O generated by a catalytic reaction2014

    • Author(s)
      Yuki Ohashi, Shingo Kanouchi, Naoya Yamaguchi, Yasuhiro Tamayama, Takahiro Kato, and Kanji Yasui
    • Organizer
      21st Int. Display Workshop
    • Place of Presentation
      Toki Messe, Niigata, Japan
    • Year and Date
      2014-12-03 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Properties of ZnO thin films grown with N2O gas using high-temperature H2O generated by a catalytic reaction2014

    • Author(s)
      Yuki Ohashi, Naoya Yamaguchi, Eichi Nagatoomi, Koichi Ohishi, Hironobu Katagiri, Yasuhiro Tamayama, Kanji Yasui
    • Organizer
      MJIIT-JUC Joint International Symposium (MJJIS 2014)
    • Place of Presentation
      Kuala Lumpur, Malaysia
    • Year and Date
      2014-11-12 – 2014-11-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] High-quality ZnO Thin Films Grown by a New CVD Method using Catalytically- generated High-energy Precursors2014

    • Author(s)
      K. Yasui
    • Organizer
      American Vacuum Society (AVS) 61st International Symposium and Exhibition
    • Place of Presentation
      Baltimore, USA
    • Year and Date
      2014-11-09 – 2014-11-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Influence of N2O addition on the properties of ZnO films grown using high-temperature H2O generated by a catalytic reaction on Pt nanoparticles2014

    • Author(s)
      Yuki Ohashi, Naoya Yamaguchi, Eichi Nagatomi, Yasuhiro Tamayama, and Kanji Yasui
    • Organizer
      The 15th IUMRS-Int. Conf. in Asia (IUMRS-ICA 2014)
    • Place of Presentation
      Fukuoka, Japan
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effect of low-temperature buffer layer inserted in ZnO films grown on glass substrates using high-temperature H2O generated by a catalytic reaction2014

    • Author(s)
      Tomoki Nakamura, Kazuki Takezawa, Koichirou Ohishi, Takahiro Kato, Kanji Yasui
    • Organizer
      The 15th IUMRS-Int. Conf. in Asia (IUMRS-ICA 2014)
    • Place of Presentation
      Fukuoka, Japan
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Dependence on the film thickness of the properties of ZnO thin films grown on a-plane sapphire substrates using high-temperature H2O generated from a catalytic reaction2014

    • Author(s)
      Yuki Ohashi, Tomoki Nakamura, Naoya Yamaguchi, Yasuhiro Tamayama, Kanji Yasui
    • Organizer
      IUMRS-ICEM 2014
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2014-06-10 – 2014-06-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Epitaxial growth of ZnO films on a-plane sapphire substrates using high-temperature H2O generated from a catalytic reaction2014

    • Author(s)
      Kanji Yasui
    • Organizer
      IUMRS-ICEM 2014
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2014-06-10 – 2014-06-14
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Effects of N2O addition during the growth of ZnO films using high-temperature H2O generated by a catalytic reaction2014

    • Author(s)
      Tomoki Nakamura, Naoya Yamaguchi, Eichi Nagatomi, Takahiro Kato, Yasuhiro Tamayama, Kanji Yasui
    • Organizer
      41th Int. Conf. on Metallurgical Coatings & Thin Films
    • Place of Presentation
      San Diego, USA
    • Year and Date
      2014-04-30 – 2014-05-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] Epitaxial Growth of Zinc Oxide Thin Films Using High-Energy H2O Generated by a Catalytic Reaction on Pt Nanoparticles2013

    • Author(s)
      K. Yasui, H. Miura, S. Satomoto, H. Nishiyama
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      Kyotanabe, Japan
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Influence of nitrogen doping on the properties of ZnO thin films grown using high-energy H2O generated by a catalytic reaction2013

    • Author(s)
      T. Takeuchi, N. Yamaguchi, E. Nagatomi, Y. Tamayama, K. Yasui
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      Kyotanabe, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] ZnO film growth on glass substrates using high-energy H2O generated by a catalytic reaction -Effect of low-temperature buffer layer-2013

    • Author(s)
      K. Takezawa, T. Oyanagi, T. Kato, H. Katagiri, K. Oishi, K. Jinbo, K. Yasui
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      Kyotanabe, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] ZnO films grown on glass substrates using high-temperature H2O generated by a catalytic reaction between H2 and O2 -Effect of low-temperature CVD buffer layer-2013

    • Author(s)
      Kazuki Takezawa, Takahiro Oyanagi, Takahiro Kato, Hironori Katagiri, Koichiro Oishi, Kazuo Jinbo, Kanji Yasui
    • Organizer
      8th Int. Symp. on Transparent Oxide and Related Mater. for Electronics and Optics
    • Place of Presentation
      Waseda Univ., Tokyo, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] 触媒反応生成高エネルギーH2Oを用いてa面サファイア基板上に成長したZnOエピタキシャル膜の結晶構造2013

    • Author(s)
      山口直也, 竹内智彦, 中村友紀, 大橋優樹, 永冨瑛智, 玉山泰宏, 安井寛治
    • Organizer
      電子情報通信学会電子部品材料研究会
    • Place of Presentation
      釧路
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effect of N2O addition on the properties of ZnO thin films grown using high-temperature H2O generated by a catalytic reaction2013

    • Author(s)
      N. Yamaguchi, K. Yasui, Y. Ohhashi, E. Nagatomi, Y. Tamayama
    • Organizer
      MRS Fall Meeting 2013
    • Place of Presentation
      Boston, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Observation of crystalline structure of ZnO thin films on a-Al2O3 using a catalytically generated H2O2013

    • Author(s)
      N. Yamaguchi, T. Takeuchi. E. Nagatomi, S. Satomoto, Y. Tamayama, K. Yasui
    • Organizer
      MRS-Japan Annual Meeting, International section
    • Place of Presentation
      Yokohama Media & Communications Center
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Electrical properties of the ZnO thin films grown on a-plane sapphire substrates using catalytically generated high-energy H2O2013

    • Author(s)
      N. Yamaguchi, T. Takeuchi, E. Nagatomi, T. Kato, H. Umemoto, K. Yasui
    • Organizer
      40th Int. Conf. on Metallurgical Coatings & Thin Films
    • Place of Presentation
      San Diego, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Influence of a sputtered buffer layer on the characteristics of ZnO thin films grown on glass substrates using catalytically generated high-energy H2O2013

    • Author(s)
      T. Nishiyama, Y. Nakazawa, K. Takezawa, T. Oyanagi, T. Kato, K. Oishi, S. Nakamura, K. Yasui
    • Organizer
      The 4th Int. Sympo. on Organic and Inorganic Electronic Materials and Related Nanotechnol.
    • Place of Presentation
      Ishikawa Ongakudo, Kanazawa, JAPAN
    • Related Report
      2013 Annual Research Report
  • [Presentation] Characteristics of ZnO Films Grown by a Newly Developed CVD Method Using High-Temperature H2O Generated from a Catalytic Reaction2013

    • Author(s)
      N. Yamaguchi, T. Takeuchi, E. Nagatomi, S. Satomoto, T. Kato, K. Yasui
    • Organizer
      Int. Conf. on II-VI Compounds and Related Materials 2013
    • Place of Presentation
      Nagahama, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Cryatalline Structure of ZnO Thin Films Grown on A- snd C-plane Sapphires Using High-Energy H2O Generated by a Catalytic Reaction2013

    • Author(s)
      T. Takeuchi, E. Nagatomi, S. Satomoto, H. Miura, K. Yasui
    • Organizer
      MJIIT-JUC Joint Int. Sympo. 2013
    • Place of Presentation
      Hiratsuka, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Zinc Oxide Film Growth Using High-Energy H_2O Generated by a Catalytic Reaction on Pt Nanoparticles2012

    • Author(s)
      Kanji Yasui, Hitoshi Miura, Hiroshi Nishiyama
    • Organizer
      The 19th International Display Workshops in conjunction with Asia Display 2012 (IDW/AD '12)
    • Place of Presentation
      京都コンベンションセンター(招待講演)
    • Year and Date
      2012-12-04
    • Related Report
      2012 Annual Research Report
  • [Presentation] Electrical properties of zinc oxide thin films deposited using high-energy H_2O generated from a catalytic reaction on platinum nanoparticles2012

    • Author(s)
      Kanji Yasui, Naoya Yamaguchi, Eichi Nagatomi, Souichi Satomoto, Takahiro Kato
    • Organizer
      MRS Fall Meeting 2012
    • Place of Presentation
      Boston Convention Center, USA
    • Year and Date
      2012-11-29
    • Related Report
      2012 Annual Research Report
  • [Presentation] 触媒反応生成H_2Oを用いてガラス基板上に堆積したZnO膜へのCVD低温バッファ層による効果2012

    • Author(s)
      小柳貴寛,竹澤和樹,里本宗一,片桐裕則,神保和夫,加藤孝弘,安井寛治
    • Organizer
      第32回表面科学学術講演会
    • Place of Presentation
      東北大学片平キャンパス, 仙台
    • Year and Date
      2012-11-20
    • Related Report
      2012 Annual Research Report
  • [Presentation] 触媒反応生成高エネルギーH_2Oを用いてガラス基板上に成長したZnO膜へのCVD低温バッファ層挿入効果2012

    • Author(s)
      小柳貴寛,竹澤和樹,加藤孝弘,片桐裕則,神保和夫,安井寛治
    • Organizer
      電子情報通信学会電子部品材料研究会
    • Place of Presentation
      まちなかキャンパス、長岡市
    • Year and Date
      2012-10-26
    • Related Report
      2012 Annual Research Report
  • [Presentation] 触媒反応生成高エネルギーH_2Oを用いたCVD法によるZnO薄膜の堆積特性2012

    • Author(s)
      安井寛治, 三浦仁嗣, 田原将巳, 里本宗一
    • Organizer
      電子情報通信学会電子部品材料研究会
    • Place of Presentation
      まちなかキャンパス、長岡市
    • Year and Date
      2012-10-26
    • Related Report
      2012 Annual Research Report
  • [Presentation] Characteristics o talytic reaction on platinum nanoparticles2012

    • Author(s)
      Kanji Yasui, Hitoshi Miura, Souichi Satomoto, Takahiro Kato
    • Organizer
      2012 Pacific Rim Meeting on Elcctrochemical and Solid-State Science (PRiME 2012)
    • Place of Presentation
      Hawaii Convention Center, Honolulu, USA
    • Year and Date
      2012-10-10
    • Related Report
      2012 Annual Research Report
  • [Presentation] Optical Properties of ZnO epitaxial film on a-plane sapphire using high-energy H_2O generated on Pt-nanoparticles2012

    • Author(s)
      Eichi Nagatomi, Naoya Yamaguchi, Hitoshi Miura, Takahiro Kato, Kanji Yasui
    • Organizer
      IUMRS-International Conference on Electronic Material(IUMRS-lCEM 2012)
    • Place of Presentation
      パシフィコ横浜(招待講演)
    • Year and Date
      2012-09-25
    • Related Report
      2012 Annual Research Report
  • [Presentation] 触媒反応生成H_2Oを用いて堆積したガラス基板上ZnO膜へのCVD低温バッファ層による効果2012

    • Author(s)
      小柳貴寛,竹沢和樹,片桐裕則,神保和夫,加藤孝弘,安井寛治
    • Organizer
      2012年秋季 第73回 応用物理学会学術講演会
    • Place of Presentation
      愛媛大学、松山大学
    • Year and Date
      2012-09-14
    • Related Report
      2012 Annual Research Report
  • [Presentation] H_2-O_2触媒反応生成高エネルギーH_2Oを用いて堆積したZnO/a-Al_2O_3の電気伝導特性の解析2012

    • Author(s)
      永冨瑛智,山口直也,清水英彦,梅本宏信,加藤孝弘,安井寛治
    • Organizer
      2012年秋季 第73回 応用物理学会学術講演会
    • Place of Presentation
      愛媛大学、松山大学
    • Year and Date
      2012-09-14
    • Related Report
      2012 Annual Research Report
  • [Presentation] 触媒反応生成高エネルギーH_2Oを用いた高品位ZnO結晶膜のエピタキシャル成長技術2012

    • Author(s)
      永富瑛智,山口直也,里本宗一,三浦仁嗣,加藤孝弘,安井寛治
    • Organizer
      平成24年電気学会電子・情報・システム部門大会
    • Place of Presentation
      弘前大学文京町キャンパス
    • Year and Date
      2012-09-07
    • Related Report
      2012 Annual Research Report
  • [Presentation] 触媒反応生成高エネルギーH_2Oを用いて成長したZnO/a-Al_2O_3膜の電気伝導特性(二層モデルによる解析)2012

    • Author(s)
      永冨瑛智, 山口直也, 加藤孝弘, 梅本宏信, 安井寛治
    • Organizer
      電子情報通信学会エレクトロニクスソサイエティ材料デバイスサマーミーティング
    • Place of Presentation
      機械振興会館、東京
    • Year and Date
      2012-06-22
    • Related Report
      2012 Annual Research Report
  • [Presentation] 触媒反応生成高エネルギーH_2Oを用いてガラス基板上に成長したZnO膜の特性(スパッタ法によるバッファー層挿入効果)2012

    • Author(s)
      小柳貴寛, 里本宗一, 佐藤 魁, 加藤孝弘, 片桐裕則, 神保和夫, 安井寛治
    • Organizer
      電子情報通信学会エレクトロニクスソサイエティ材料デバイスサマーミーティング
    • Place of Presentation
      機械振興会館、東京
    • Year and Date
      2012-06-22
    • Related Report
      2012 Annual Research Report
  • [Presentation] Optical properties of ZnO thin films grown on glass substrates using catalytically generated high-energy H_2O2012

    • Author(s)
      Eichi Nagatomi, Souichi Satomoto, Masami Tahara, Takahiro Kato, Kanji Yasui
    • Organizer
      39_<th> International Conference on Metallurgical Coatings and Thin Films (ICMCTF 2012)
    • Place of Presentation
      Town & Country Hotel, Convention Center, San Diego, USA
    • Year and Date
      2012-04-26
    • Related Report
      2012 Annual Research Report
  • [Remarks] 半導体工学研究室

    • URL

      http://kyasuiweb.nagaoksaut.ac.jp/second/index-2.htm

    • Related Report
      2014 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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