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Study on initial growth mechanism of vertically-grown nanographene observed by in-situ TEM

Research Project

Project/Area Number 24360015
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionNagoya University

Principal Investigator

KONDO HIROKI  名古屋大学, 工学(系)研究科(研究院), 准教授 (50345930)

Co-Investigator(Kenkyū-buntansha) TAKEDA Keigo  名古屋大学, 大学院工学研究科, 助教 (00377863)
Co-Investigator(Renkei-kenkyūsha) HORI Masaru  名古屋大学, 大学院工学研究科, 教授 (80242824)
HIRAMATSU Mineo  名城大学, 理工学部, 教授 (50199098)
ISHIKAWA Kenji  名古屋大学, 大学院工学研究科, 特任教授 (60417384)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Fiscal Year 2014: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2012: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
Keywordsプラズマ / 透過型電子顕微鏡 / グラフェン / その場観察 / X線光電子分光法 / ナノグラフェン / 透過電子顕微鏡 / in-situ観察 / エッチング
Outline of Final Research Achievements

Growth processes and mechanisms of carbon nanowalls (CNW) were investigated. Employing plasma diagnostic techniques and surface composition and structure analyses methods, we developed compact radical source, which can be installed to “Reaction science high-voltage scanning transmission electron microscope” (Nagoya University). And, in-situ observation technique of nanographene nucleation and growth processes at the CNW growth by plasma-enhanced chemical vapor deposition method. Surface composition change and biding structure change were also investigated using X-ray photoelectron spectroscopy. Effects of fluorine and hydroxide radicals exposed to CNW surfaces were clarified. Selective growth of CNW of patterned metal electrodes were also studied.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (36 results)

All 2015 2014 2013 2012 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (27 results) (of which Invited: 10 results) Remarks (3 results)

  • [Journal Article] Nanostructure modification to carbon nanowall surface employing hydrogen peroxide solution2014

    • Author(s)
      Hironao Shimoeda, Hiroki Kondo, Kenji Ishikawa, Mineo Hiramatsu, Makoto Sekine, and Masaru Hori
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 4 Pages: 040305-040305

    • DOI

      10.7567/jjap.53.040305

    • NAID

      210000143507

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of nitrogen plasma post-treatment on electrical conduction of carbon nanowalls2014

    • Author(s)
      Hyung Jun Cho, Hiroki Kondo, Kenji Ishikawa, Makoto Sekine, Mineo Hiramatsu, and Masaru Hori
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 4 Pages: 040307-040307

    • DOI

      10.7567/jjap.53.040307

    • NAID

      210000143509

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hierarchical regrowth of flowerlike nanographene sheets on oxygen-plasma-treated carbon nanowalls2014

    • Author(s)
      Hironao Shimoeda, Hiroki Kondo, Kenji Ishikawa, Mineo Hiramatsu, Makoto Sekine, and Masaru Hori
    • Journal Title

      Appl. Phys. Express

      Volume: 7 Issue: 4 Pages: 046201-046201

    • DOI

      10.7567/apex.7.046201

    • NAID

      210000137068

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Density Control of Carbon Nanowalls Grown by CH4/H2 plasma and Their Electrical Properties2013

    • Author(s)
      Hyung Jun Cho, Hiroki Kondo, Kenji Ishikawa, Makoto Sekine, Mineo Hiramatsu, and Masaru Hori
    • Journal Title

      Carbon

      Volume: 68 Pages: 380-388

    • DOI

      10.1016/j.carbon.2013.11.014

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic Oxygen Etching from the Top Edges of Carbon Nanowalls2013

    • Author(s)
      Hironao Shimoeda, Hiroki Kondo, Kenji Ishikawa, Mineo Hiramatsu, Makoto Sekine, and Masaru Hori
    • Journal Title

      Appl. Phys. Express

      Volume: 6 Issue: 9 Pages: 095201-095201

    • DOI

      10.7567/apex.6.095201

    • NAID

      10031199873

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface Chemical Modification of Carbon Nanowalls for Wide-Range Control of Surface Wettability2013

    • Author(s)
      H. Watanabe, H. Kondo, M. Hiramatsu, M. Sekine, S. Kumar, K. Ostrikov, M. Hori
    • Journal Title

      Plasma Process. Polym.

      Volume: 10 Issue: 7 Pages: 582-592

    • DOI

      10.1002/ppap.201200141

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Fabrication of Polymer Electrolyte Fuel Cell Using Carbon Nanowalls2015

    • Author(s)
      Ryosuke Okei, Takayuki Ohta, Masafumi Ito, Mineo Hiramatsu, Hiroki Kondo, Masaru Hori
    • Organizer
      7th International Symposium on Advanced Plasma Science and Its Applications for Nitrides and Nanomaterials / 8th International Conference on Plasma Nanotechnology and Science
    • Place of Presentation
      Nagoya University
    • Year and Date
      2015-03-26 – 2015-03-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] Electrochemical Characteristics and Durability of Pt Nanoparticles Supported Carbon Nanowalls2015

    • Author(s)
      Shun Imai, Hiroki Kondo, Hiroyuki Kano, Kenji Ishikawa, Makoto Sekine, Mineo Hiramatsu, Masaru Hori
    • Organizer
      7th International Symposium on Advanced Plasma Science and Its Applications for Nitrides and Nanomaterials / 8th International Conference on Plasma Nanotechnology and Science
    • Place of Presentation
      Nagoya University
    • Year and Date
      2015-03-26 – 2015-03-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] Plasma-Enhanced Synthesis and Esge-Modification of Carbon Nanowalls for Nano-Bio Applications2014

    • Author(s)
      H. Kondo, M. Hiramatsu, M. Sekine, M. Hori
    • Organizer
      2014 Materials Research Society Fall Meeting and Exhibit
    • Place of Presentation
      Boston
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] アルゴン/ フッ素ガスを用いたグラフェンエッジ終端のカーボンナノウォールの化学構造および電気的特性に対する効果2014

    • Author(s)
      趙亨峻、田嶋聡美、近藤博基、石川健治、関根誠、平松美根男、堀勝
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学札幌キャンパス
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Anisotropic etching and structural modification of carbon nanowalls by oxygen-related radicals2014

    • Author(s)
      HIROKI KONDO, Hironao Shimoeda, Kenji Ishikawa, Mineo Hiramatsu, Makoto Sekine, Masaru Hori
    • Organizer
      14th International Conference on Plasma Surface Engineering (PSE2014)
    • Place of Presentation
      Garmisch-Partenkirchen, Germany
    • Year and Date
      2014-09-15 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] Surface modification of carbon nanowalls for their nano-bio applications2014

    • Author(s)
      Masaru Hori, HIROKI KONDO, Mineo Hiramatsu
    • Organizer
      14th International Conference on Plasma Surface Engineering (PSE2014)
    • Place of Presentation
      Garmisch-Partenkirchen, Germany
    • Year and Date
      2014-09-15 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] Controlled Synthesis of Carbon Nanomaterials Employing Plasma-Enhanced Chemical Vapor Deposition for Future Green Energy Applications2014

    • Author(s)
      Hiroki KONDO, Mineo HIRAMATSU, Masaru HORI
    • Organizer
      International Union of Materials Research Societies - The 15th International Conference in Asia (IUMRS-ICA2014)
    • Place of Presentation
      Fukuoka Univerrsity, Fukuoka
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Nano-Bio applications of carbon-nano materials synthesized and modified by plasma2014

    • Author(s)
      Hiroki Kondo, Mineo Hiramatsu, and Masaru Hori
    • Organizer
      19th Korea-Japan Workshop on Advanced Plasma Processes and Diagnostics & 6th Workshop for NU-SKKU Joint Institute for Plasma-Nano Materials
    • Place of Presentation
      Gunsan, Korea
    • Year and Date
      2014-07-06 – 2014-07-07
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Advanced plasma-nano processes for controls of crystallographic and electrical properties of carbon nanomaterials2014

    • Author(s)
      Hiroki Kondo, Masaru Hori
    • Organizer
      The International Symposium on Plasma-Nano Materials and Processes
    • Place of Presentation
      The Riverside Hotel, Seoul, South Korea, April 1 - 5, 2014
    • Year and Date
      2014-04-01 – 2014-04-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Control of Edge and Surface Oxidation of Carbon Nanowalls by Argon Ion Irradiation2014

    • Author(s)
      H. Shimoeda, H. Kondo, K. Takeda, K. Ishikawa, M. Hiramatsu, M. Sekine, M. Hori
    • Organizer
      6th International Symposium on Advanced Plasma Science and its Applications for Nitrides and Nanomaterials
    • Place of Presentation
      Meijo Univ.
    • Related Report
      2013 Annual Research Report
  • [Presentation] Plasma nano-interface with organic materials for surface-roughness formation2014

    • Author(s)
      M. Sekine, Y. Zhang, K. Ishikawa, K. Takeda, H. Kondo, M. Hori
    • Organizer
      The 9th EU-Japan Joint Symposium on Plasma Processing, Bohinj Park ECO Hotel
    • Place of Presentation
      Bohinjska Bistrica, Slovenia
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Plasma Induced Surface Roughness of Polymeric Materials2014

    • Author(s)
      K. Ishikawa, T. Takeuchi, Y. Zhang, Y. Setsuhara, K. Takeda, H. Kondo, M. Sekine, M. Hori
    • Organizer
      18th Korea - Japan Workshop on Advanced Plasma Processes and Diagnostics
    • Place of Presentation
      Fukuoka
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Behaviors of activated species in SiH4/H2 plasma for µc-Si:H thin film deposition2014

    • Author(s)
      K. Takeda, Y. Abe, K. Ishikawa, H. Kondo, M. Sekine, M. Hori
    • Organizer
      18th Korea - Japan Workshop on Advanced Plasma Processes and Diagnostics
    • Place of Presentation
      Fukuoka
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] カーボンナノウォールの結晶構造に対するラジカル酸化効果(III)2014

    • Author(s)
      近藤博基,下枝弘尚,石川健治,平松美根男,関根誠,堀勝
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] Chemical modification and nano-bio applications of carbon nanowalls2013

    • Author(s)
      H. Kondo, M. Hiramatsu, M. Sekine, M. Hori
    • Organizer
      17th Korea-Japan Workshop on Advanced Plasma Processes and Diagnostics & 4th Workshop for NU-SKKU Joint Institute for Plasma-Nano Materials
    • Place of Presentation
      Sungkyunkwan University, Suwon & Hanhwa Resort Seorak, Sokcho, Republic of Korea
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Carbon nanowalls: synthesis and application2013

    • Author(s)
      M. Hiramatsu, H. Kondo, M. Hori
    • Organizer
      The 1st International Conference on Surface Engineering (ICSE2013)
    • Place of Presentation
      Busan, Korea
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Carbon Nanowalls: Growth Control and their Clean Applications2013

    • Author(s)
      M. Hiramatsu, H. Kondo, M. Hori
    • Organizer
      8th Asia-Pacfic International Symposium on the Basics and Applications of Plasma Technology
    • Place of Presentation
      Hsinchu, Taiwan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Gradual transition of chemical structures at initial growth stage of carbon nanowalls2013

    • Author(s)
      H. Kondo, K. Yasuda, K. Ishikawa, M. Sekine, M. Hiramatsu, and M. Hori
    • Organizer
      The European Materials Conference European Materials Research Society Fall Meeting Scientific/Technical Symposia & Exhibition
    • Place of Presentation
      Warsaw University of Technology, Warsaw, Poland
    • Related Report
      2013 Annual Research Report
  • [Presentation] Nucleation control of self-organized vertical nano-graphenes using inductively coupled plasma enhanced chemical vapor deposition2013

    • Author(s)
      M. Hiramatsu, Y. Nihashi, H. Kondo, M. Hori
    • Organizer
      The European Materials Conference European Materials Research Society Fall Meeting Scientific/Technical Symposia & Exhibition
    • Place of Presentation
      Warsaw University of Technology, Warsaw, Poland
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis of graphene nanowalls for clean energy application2013

    • Author(s)
      M. Hiramatsu, H. Kondo, M. Hori
    • Organizer
      International conference on processing and manufacturing of advanced materials
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Controlled synthesis and nano-bio applications of carbon nanowalls based on advanced plasma technology2013

    • Author(s)
      H. Kondo, M. Hori, M. Hiramatsu
    • Organizer
      International conference on processing and manufacturing of advanced materials
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] カーボンナノウォールの表面化学修飾とナノバイオ応用2013

    • Author(s)
      近藤博基,渡邊均,石川健治,関根誠,堀勝,平松美根男
    • Organizer
      平成25年秋季第74回応用物理学会学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] カーボンナノウォールに対する酸素原子及びアルゴンイオンの同時照射効果2013

    • Author(s)
      下枝弘尚,近藤博基,石川健治,平松美根男,関根誠,堀勝
    • Organizer
      平成25年秋季第74回応用物理学会学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] Edge and Surface Modification of Nanographenes in Carbon Nanowalls by Hydrogen Peroxide Treatments2012

    • Author(s)
      H. Shimoeda, H. Kondo, K. Ishikawa, M. Hiramatsu, M. Sekine, M. Hori
    • Organizer
      The 4th International Conference on Microelectronics and Plasma Technology
    • Place of Presentation
      Ramada Plaza Jeju Hotel, Jeju, Korea
    • Related Report
      2012 Annual Research Report
  • [Presentation] Advanced Plasma Science and Technologies for Nanostructure Control of Carbon Nanomaterials2012

    • Author(s)
      H. Kondo, M. Hiramatsu, M. Hori
    • Organizer
      International Union of Materials Research Societies - Internet Conference on Electronic Materials 2012
    • Place of Presentation
      Yokohama, Japan(招待講演)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Effects of Hydroxyl Radical on Nanographene Surfaces in Carbon Nanowalls2012

    • Author(s)
      H. Shimoeda, H. Kondo, K. Ishikawa, M. Hiramatsu, M. Sekine, and M. Hori
    • Organizer
      The 11th APCPST and 25th SPSM
    • Place of Presentation
      Kyoto University ROHM Plaza, Kyoto, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] カーボンナノウォールの結晶構造に対するラジカル酸化効果2012

    • Author(s)
      下枝弘尚, 近藤博基, 石川健治, 平松美根男, 関根誠, 堀勝
    • Organizer
      平成24年秋季第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学城北地区・松山大学文京キャンパス
    • Related Report
      2012 Annual Research Report
  • [Remarks] 名古屋大学教員データベース

    • URL

      http://profs.provost.nagoya-u.ac.jp/view/html/100002054_ja.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 名古屋大学大学院工学研究科電子情報システム専攻 堀・関根研究室

    • URL

      http://horilab.nuee.nagoya-u.ac.jp/index.php

    • Related Report
      2014 Annual Research Report
  • [Remarks] 近藤博基・名古屋大学教員データベース

    • URL

      http://profs.provost.nagoya-u.ac.jp/view/html/100002054_ja.html?k=%E5%8D%9A%E5%9F%BA

    • Related Report
      2013 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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