• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Synthesis of LiNbO3-type compounds with polar structure and their functional properties

Research Project

Project/Area Number 24360275
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionGakushuin University

Principal Investigator

INAGUMA Yoshiyuki  学習院大学, 理学部, 教授 (00240755)

Co-Investigator(Kenkyū-buntansha) KATSUMATA Tetsuhiro  東海大学, 理学部, 准教授 (90333020)
Co-Investigator(Renkei-kenkyūsha) MORI Daisuke  学習院大学, 理学部, 助教 (00432021)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2013: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2012: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Keywordsリチウムナイオベート / 極性 / 高圧合成 / 強誘電性 / 二次ヤーン - テラー効果 / ぺロブスカイト / 光第二高調波発生 / 相転移 / 二次ヤーンテラー効果 / リチウムニオベート / ペロブスカイト / 酸化物 / 酸フッ化物 / 酸窒化物
Outline of Final Research Achievements

Polar materials exhibit properties attributable to their non-centrosymmetric structures such as ferroelectricity, piezoelectricity, non-linear optical properties, and are applicable to ferroelectric memory devices, piezoelectric devices through which electricity transforms into mechanical energy and vice versa, non-linear optical devices with wavelength conversion function, and so on. In this study, to establish the foundation of polar materials, we focused our attention to lithium niobate compounds with a polar structure and worked on the search of novel compounds and development of their functional properties. As the results, we successfully synthesized lithium niobate type compounds such as zinc titanate, ZnTiO3, investigated their crystal structure and properties such as polarity, and elucidated the relationship between constituent ions, structure, and functional properties. Furthermore, a novel polar material with a perovskite structure was found in the course of material search.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (36 results)

All 2015 2014 2013 2012 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (25 results) (of which Invited: 3 results) Remarks (5 results)

  • [Journal Article] High-pressure phase behaviors of ZnTiO3:ilmenite-perovskite transition, decomposition of perovskite into constituent oxides, and perovskite-lithium niobate transition2015

    • Author(s)
      M. Akaogi, K. Abe, H. Yusa, H. Kojitani, D. Mori, Y. Inaguma
    • Journal Title

      Phys. Chem. Minerals

      Volume: in press Issue: 6 Pages: 421-429

    • DOI

      10.1007/s00269-015-0733-1

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-Pressure Synthesis of Perovskite Related Compounds with Polar Structure and Their Functional Properties2014

    • Author(s)
      稲熊 宜之, 相見 晃久, 勝又 哲裕, 森 大輔
    • Journal Title

      The Review of High Pressure Science and Technology

      Volume: 24 Issue: 3 Pages: 212-222

    • DOI

      10.4131/jshpreview.24.212

    • NAID

      130004690976

    • ISSN
      0917-639X, 1348-1940
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 1.Synthesis, Crystal Structure, and Electronic Properties of High-Pressure PdF2-Type Oxides MO2 (M = Ru, Rh, Os, Ir, Pt)2014

    • Author(s)
      Yuichi Shirako, Xia Wang, Yoshihiro Tsujimoto, Kie Tanaka, Yanfeng Guo, Yoshitaka Matsushita, Yoshihiro Nemoto, Yoshio Katsuya, Youguo Shi, Daisuke Mori, Hiroshi Kojitani, Kazunari Yamaura, Yoshiyuki Inaguma, and Masaki Akaogi
    • Journal Title

      Inorganic Chemistry

      Volume: 53 Issue: 21 Pages: 11616-11625

    • DOI

      10.1021/ic501770g

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] High-Pressure Synthesis, Crystal Structure, and Phase Stability Relations of a LiNbO3-Type Polar Titanate ZnTiO3 and Its Reinforced Polarity by the Second-Order Jahn-Teller Effect2014

    • Author(s)
      Yoshiyuki Inaguma, Akihisa Aimi, Yuichi Shirako, Daichi Sakurai, Daisuke Mori, Hiroshi Kojitani, Masaki Akaogi, and Masanobu Nakayama
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136(7) Issue: 7 Pages: 2748-2756

    • DOI

      10.1021/ja408931v

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-Pressure Synthesis of A-Site Ordered Double Perovskite CaMnTi2O6 and Ferroelectricity Driven by Coupling of A-Site Ordering and the Second-Order Jahn–Teller Effect2014

    • Author(s)
      Akihisa Aimi, Daisuke Mori, Ko-ichi Hiraki, Toshihiro Takahashi, Yue Jin Shan, Yuichi Shirako, Jianshi Zhou and Yoshiyuki Inaguma
    • Journal Title

      Chem. Mater.

      Volume: 26(8) Issue: 8 Pages: 2601-2608

    • DOI

      10.1021/cm500016z

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dielectric properties of a polar ZnSnO_3 with LiNbO_3-type structure2012

    • Author(s)
      Y. Inaguma, et al.
    • Journal Title

      Journal of Solid State Chemistry

      Volume: 195 Pages: 115-119

    • DOI

      10.1016/j.jssc.2012.07.036

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] リチウムナイオベート型酸窒化物,MnTaO2N の合成条件の検討討2015

    • Author(s)
      勝又哲裕、戸部綾菜、大場ちづる、竹田充志、相見晃久、森大輔、稲熊宜之
    • Organizer
      日本セラミックス協会2015年年会
    • Place of Presentation
      岡山大学 (津島キャンパス)
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] LiNbO3型酸化物固溶体(1-x)LiTaO3-xCaBO3(B=Ti, Zr)の合成、構造及び強誘電性2015

    • Author(s)
      佐山暁久、森大輔、稲熊宜之
    • Organizer
      日本セラミックス協会第53回セラミックス基礎科学討論会
    • Place of Presentation
      京都テルサ(京都勤労者総合福祉センター)
    • Year and Date
      2015-01-08 – 2015-01-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] リチウムナイオベート型酸窒化物固溶体、(1-x)Mn4Ta2O9-xMnTaO2Nの合成2014

    • Author(s)
      大場ちづる、竹田充志、勝又哲裕、相見晃久、森大輔、稲熊宜之
    • Organizer
      日本セラミックス協会第27回秋季シンポジウム
    • Place of Presentation
      鹿児島大学(郡元キャンパス)
    • Year and Date
      2014-09-09 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Aサイト秩序型二重ペロブスカサイトCaA'Ti 2O6(A': 2価イオン)の高圧合成と極性の検討2014

    • Author(s)
      赤間洋平、相見晃久、 森大輔、 稲熊宜之
    • Organizer
      第30回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      栃木県芳賀青年の家
    • Year and Date
      2014-09-02 – 2014-09-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] リチウムナイオベート型酸窒化物、MnTaO2Nの合成2014

    • Author(s)
      戸部綾菜、大場ちづる、竹田 充志、勝又哲裕、森大 輔、稲熊宜之
    • Organizer
      第30回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      栃木県芳賀青年の家
    • Year and Date
      2014-09-02 – 2014-09-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] LiTaO3-CaTiO3固溶体の構造と強誘電性2014

    • Author(s)
      佐山暁久 、森大輔、 稲熊宜之
    • Organizer
      第30回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      栃木県芳賀青年の家
    • Year and Date
      2014-09-02 – 2014-09-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] High-pressure synthesis, structure, phase relation of polar LiNbO3-type ZnTiO32014

    • Author(s)
      Yoshiyuki Inaguma, Akihisa Aimi, Yuichi Shirako, Daichi Sakurai, Daisuke Mori, Hiroshi Kojitani, Masaki Akaogi, Tetsuhiro Katsumata and Masanobu Nakayama
    • Organizer
      23rd Congress and General Assembly of the International Union of Crystallography(IUCr2014)
    • Place of Presentation
      Montreal, Canada
    • Year and Date
      2014-08-05 – 2014-08-12
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ペロフスカイト型酸フッ化固溶体、(1-x)KNbO3-xKMgF3の誘電性2014

    • Author(s)
      勝又哲裕、蔵谷亮祐、澤田信宏、森大輔、稲熊宜之
    • Organizer
      日本セラミックス協会2014年年会
    • Place of Presentation
      慶応義塾大学(横浜)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Aサイト秩序型二重ペロブスカイトMnCaTi2O6における強誘電相転移2013

    • Author(s)
      相見晃久、森大輔、稲熊宜之、単躍進
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学(長野)
    • Related Report
      2013 Annual Research Report
  • [Presentation] LiNbO3型化合物における極性と構成元素との関係2013

    • Author(s)
      稲熊宜之、相見晃久、森大輔、勝又哲裕、中山将伸
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学(長野)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ペロフスカイト型酸フッ化固溶体,(1-x)KNbO3-xKMgF3の構造相転移と誘電性2013

    • Author(s)
      勝又哲裕、蔵谷亮祐、澤田信宏、森大輔、稲熊宜之
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学(長野)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 新規LiNbO_3型酸化物ZnSn_<1-x>Ti_xO_3の合成および結晶構造と誘電性2013

    • Author(s)
      櫻井, ら
    • Organizer
      第51回セラミックス基礎討論会
    • Place of Presentation
      仙台国際センター、仙台
    • Related Report
      2012 Annual Research Report
  • [Presentation] ペロフスカイト型酸化物Bi_<0.5>(Na_<1-x>Ag_x)_<0.5-y>TiO_3の強誘電性および圧電性2013

    • Author(s)
      高野, ら
    • Organizer
      第51回セラミックス基礎討論会
    • Place of Presentation
      仙台国際センター、仙台
    • Related Report
      2012 Annual Research Report
  • [Presentation] Joint International Workshop of WFF&WFSO2013

    • Author(s)
      Y. Inaguma, et al.
    • Organizer
      High-pressure synthesis and dielectric properties of polar LiNbO_3-type oxides
    • Place of Presentation
      札幌(北海道大学)および日高(招待講演)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 新規極性酸化物Aサイト秩序二重ペロプスガイドMnCaTi_O_6の高圧合成と構造および物性2013

    • Author(s)
      相見, ら
    • Organizer
      セラミックス協会2013年年会
    • Place of Presentation
      東京工業大学、東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] High-pressure synthesis and dielectric properties of polar LiNbO_3-type oxides2012

    • Author(s)
      Y. Inaguma, et al.
    • Organizer
      China-Japan-Korea Forum on Electric and Optical oxide materials and Applications-2012 (CJK-FEOMA 2012)
    • Place of Presentation
      Shanghai, China(招待講演)
    • Related Report
      2012 Annual Research Report
  • [Presentation] High-pressure synthesis, structure and dielectric properties for A-site oredered perovskite-type titanium oxides2012

    • Author(s)
      D. Mori, et al.
    • Organizer
      Joint International Symposium ISFD-11th-RCBJSF
    • Place of Presentation
      Ekaterinburg, Russia
    • Related Report
      2012 Annual Research Report
  • [Presentation] High-pressure synthesis and dielectric properties of polar LiNbO_3-type oxides2012

    • Author(s)
      Y. Inaguma, et al.
    • Organizer
      Joint International Symposium ISFD-11th-RCBJSF
    • Place of Presentation
      Ekaterinburg, Russia
    • Related Report
      2012 Annual Research Report
  • [Presentation] LiNbO_3型MnTiO_3の高圧下における単結晶の育成2012

    • Author(s)
      相見, ら
    • Organizer
      セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学、名古屋
    • Related Report
      2012 Annual Research Report
  • [Presentation] Aサイト秩序型ペロプスガイドCa_<1-x>Sr_xCu_3TiO_<12>の高圧合成、構造および物性2012

    • Author(s)
      森, ら
    • Organizer
      セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学、名古屋
    • Related Report
      2012 Annual Research Report
  • [Presentation] LiNbO_3型極性酸化物の高圧合成および結晶構造と誘電性との関係2012

    • Author(s)
      稲熊, ら
    • Organizer
      セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学、名古屋
    • Related Report
      2012 Annual Research Report
  • [Presentation] ペロフスカイト型酸フッ化物固溶体(l-x)KNbo_3-xKMgF_3の合成と結晶構造2012

    • Author(s)
      勝又, ら
    • Organizer
      セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学、名古屋
    • Related Report
      2012 Annual Research Report
  • [Presentation] Structure and Dielectric Properties of Perovskite-type Oxyfluorides, AScO_2F (A=Pb and Ba)2012

    • Author(s)
      Katsumata, et al.
    • Organizer
      International symposium on Rare Earths in 2012
    • Place of Presentation
      那覇(沖縄ハーバービューホテル)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 極性構造をもつ新規LiNbO3型化合物の高圧合成と機能開拓

    • Author(s)
      稲熊宜之
    • Organizer
      第3回新機能無機物質探索研究センターシンポジウム
    • Place of Presentation
      東北大学(仙台)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 極性構造をもつぺロブスカイト関連化合物の高圧合成と機能開拓

    • Author(s)
      稲熊宜之
    • Organizer
      RIKEN-CEMSワークショップ
    • Place of Presentation
      理化学研究所(埼玉)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Remarks]

    • URL

      http://www-cc.gakushuin.ac.jp/~19990787/group/index.htm

    • Related Report
      2014 Annual Research Report
  • [Remarks] About the Cover

    • URL

      http://pubs.acs.org/toc/jacsat/136/7

    • Related Report
      2013 Annual Research Report
  • [Remarks] JACS Spotlights

    • URL

      http://pubs.acs.org/doi/abs/10.1021/ja501425f

    • Related Report
      2013 Annual Research Report
  • [Remarks] 学習院大学稲熊研究室ホームページ Our Studies

    • URL

      http://www-cc.gakushuin.ac.jp/~19990787/group/studies.html

    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www-cc.gakusyuini.ac.jp/~19990787/group/index.htm

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2012-04-24   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi