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Fabrication of High-Entropy Bulk Metallic Glasses based on Confusion Principle, Clarification of their Properties and their Application

Research Project

Project/Area Number 24360284
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

Takeuchi Akira  東北大学, 金属材料研究所, 特任教授 (40250815)

Co-Investigator(Kenkyū-buntansha) 網谷 健児  東北大学, 金属材料研究所, 特任准教授 (30463798)
湯葢 邦夫  東北大学, 金属材料研究所, 准教授 (00302208)
和田 武  東北大学, 金属材料研究所, 助教 (10431602)
横山 嘉彦  東北大学, 金属材料研究所, 准教授 (00261511)
陳 娜  東北大学, 原子分子材料科学高等研究機構, 助教 (30532171)
王 軍強  東北大学, 原子分子材料科学高等研究機構, 助手 (80601385)
Project Period (FY) 2012-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2014: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2013: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2012: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Keywordsバルク金属ガラス / アモルファス材料 / 高エントロピー合金 / 等原子分率 / 固溶体 / 合金設計 / 強磁性 / 面心立方構造 / 計算機科学 / 定比化合物 / 金属物性 / 構造・機能材料 / 物性基礎論 / シミュレーション工学 / 計算物理 / 六方稠密充填構造 / 結晶構造 / 稠密六方晶構造 / アーク溶解法 / ランタノイド金属 / 混合エンタルピー / 原子寸法差 / 周期律表 / 体心立方構造 / 金属間化合物
Outline of Final Research Achievements

The present study has succeeded in fabricating high-entropy bulk metallic glasses (HE-BMGs) as represented by Fe25Co25Ni25(B, Si)25 alloy with a critical diameter of 1.5 mm for forming glassy phase. The alloys were developed by applying a concept of confusion principle that has effectively been utilized for the alloy development of high-entropy (H-E) alloys of multicomponent equi-atomic compositions. Furthermore, a first success in fabricating H-E alloys with hexagonal dense-packed structure was reported by fabricating YGdTbDyLu and GdTbDyTmLu alloys. In the 5-year project, alloy designs of the H-E and relevant alloys have been established based on statistic analysis.

Report

(6 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (30 results)

All 2017 2016 2015 2014 2013 2012 Other

All Journal Article (14 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 14 results,  Acknowledgement Compliant: 9 results) Presentation (15 results) (of which Int'l Joint Research: 3 results,  Invited: 7 results) Book (1 results)

  • [Journal Article] MnFeNiCuPt and MnFeNiCuCo high-entropy alloys designed based on L10 structure in Pettifor map for binary compounds2017

    • Author(s)
      A. Takeuchi, T. Wada and Y. Zhang
    • Journal Title

      Intermetallics

      Volume: 82 Pages: 107-115

    • DOI

      10.1016/j.intermet.2016.12.002

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Stress-Enhanced Transformations from Hypothetical B2 to Stable L1<sub>0</sub> and Amorphous to fcc Phases in Fe<sub>50</sub>Ni<sub>50</sub> Binary Alloy by Molecular Dynamic Simulations2017

    • Author(s)
      A. Takeuchi, K. Takenaka, Y. Zhang, Y.C. Wang and A. Makino
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 58 Issue: 4 Pages: 646-654

    • DOI

      10.2320/matertrans.M2016162

    • NAID

      130006777332

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Recent Progress in Alloy Designs for High-Entropy Crystalline and Glassy Alloys2016

    • Author(s)
      A. Takeuchi
    • Journal Title

      Journal of the Japan Society of Powder and Powder Metallurgy

      Volume: 63 Issue: 4 Pages: 209-216

    • DOI

      10.2497/jjspm.63.209

    • NAID

      130005150369

    • ISSN
      0532-8799, 1880-9014
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] High-Entropy Alloys Including 3d, 4d and 5d Transition Metals from the Same Group in the Periodic Table2016

    • Author(s)
      A. Takeuchi, K. Amiya, T. Wada and K. Yubuta
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 57 Issue: 7 Pages: 1197-1201

    • DOI

      10.2320/matertrans.M2016121

    • NAID

      130005158397

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Dual HCP structures formed in senary ScYLaTiZrHf multi-principal-element alloy2016

    • Author(s)
      A. Takeuchi, K. Amiya, T. Wada and K. Yubuta
    • Journal Title

      Intermetallics

      Volume: 69 Pages: 103-109

    • DOI

      10.1016/j.intermet.2015.10.022

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Alloy Designs for High-Entropy Alloys, Bulk Metallic Glasses and High-Entropy Bulk Metallic Glasses2015

    • Author(s)
      竹内 章
    • Journal Title

      Journal of the Japan Institute of Metals and Materials

      Volume: 79 Issue: 4 Pages: 157-168

    • DOI

      10.2320/jinstmet.J2014046

    • NAID

      130005061072

    • ISSN
      0021-4876, 1880-6880, 2433-7501
    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Alloy design for high-entropy alloys based on Pettifor map for binary compounds with 1:1 stoichiometry2015

    • Author(s)
      A. Takeuchi, K. Amiya, T. Wada and K. Yubuta
    • Journal Title

      Intermetallics

      Volume: 66 Pages: 56-66

    • DOI

      10.1016/j.intermet.2015.06.014

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Soft magnetic Fe25Co25Ni25(B,Si)25 high entropy bulk metallic glasses2015

    • Author(s)
      T.L. Qi, Y.H. Li, A. Takeuchi, G.Q. Xie, H.T. Miao and W. Zhang
    • Journal Title

      Intermetallics

      Volume: 66 Pages: 8-12

    • DOI

      10.1016/j.intermet.2015.06.015

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] High-Entropy Alloys with a Hexagonal Close-Packed Structure Designed by Equi-Atomic Alloy Strategy and Binary Phase Diagrams2014

    • Author(s)
      A. Takeuchi, K. Amiya, T. Wada, K. Yubuta and W. Zhang
    • Journal Title

      JOM

      Volume: 66 Issue: 10 Pages: 1984-1992

    • DOI

      10.1007/s11837-014-1085-x

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Alloy Designs of High-Entropy Crystalline and Bulk Glassy Alloys by Evaluating Mixing Enthalpy and Delta Parameter for Quinary to Decimal Equi-Atomic Alloys2014

    • Author(s)
      A. Takeuchi, K. Amiya, T. Wada, K. Yubuta, W. Zhang and A. Makino
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 55 Issue: 1 Pages: 165-170

    • DOI

      10.2320/matertrans.M2013352

    • NAID

      130004825127

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Al<sub>0.5</sub>TiZrPdCuNi High-Entropy (H-E) Alloy Developed through Ti<sub>20</sub>Zr<sub>20</sub>Pd<sub>20</sub>Cu<sub>20</sub>Ni<sub>20</sub> H-E Glassy Alloy Comprising Inter-Transition Metals2013

    • Author(s)
      A. Takeuchi, J.Q. Wang, N. Chen, W. Zhang, Y. Yokoyama, K. Yubuta and S.L. Zhu
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 54 Issue: 5 Pages: 776-782

    • DOI

      10.2320/matertrans.M2012370

    • NAID

      10031168425

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Entropies in Alloy Design for High-Entropy and Bulk Glassy Alloys2013

    • Author(s)
      A. Takeuchi, K. Amiya, T. Wada, K. Yubuta, W. Zhang and A. Makino
    • Journal Title

      Entropy

      Volume: 15 Issue: 9 Pages: 3810-3821

    • DOI

      10.3390/e15093810

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Alloy Design for High-Entropy Bulk Glassy Alloy2012

    • Author(s)
      A. Takeuchi
    • Journal Title

      Procedia Engineering

      Volume: 36 Pages: 226-234

    • DOI

      10.1016/j.proeng.2012.03.035

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Compositional Features of Bulk Metallic Glasses Analyzed with a Tetrahedral Composition Diagram from s-, p-, d- and f-Blocks2012

    • Author(s)
      A. Takeuchi
    • Journal Title

      International Journal of Materials Research

      Volume: 103 Issue: 9 Pages: 1102-1107

    • DOI

      10.3139/146.110801

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Future Prospects of High-Entropy Alloys (HEAs) with Hexagonal Close-Packed, Glassy and Quasicrystalline Structures and Alloy Designs of HEAs Based on Empirical and Statistical Scheme2016

    • Author(s)
      A. Takeuchi
    • Organizer
      International Conference on High-Entropy Materials (ICHEM2016)
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2016-11-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] High-Entropy Alloys Including 3D, 4D and 5D Transition Metals from the Same Group in the Periodic Table2016

    • Author(s)
      A. Takeuchi, K. Amiya, T. Wada and K. Yubuta
    • Organizer
      TMS 2016: 145th Annual Meeting & Exhibition
    • Place of Presentation
      Nashville, TN, U.S.A.
    • Year and Date
      2016-02-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Alloy Design of Metallic Glasses and Relevant Alloys Based on Digitalized Empirical Criteria and Pettifor Map2015

    • Author(s)
      A. Takeuchi, K. Amiya, T. Wada and K. Yubuta
    • Organizer
      Europian Congress and Exhibition on Advanced Materials and Processing (EUROMAT2015)
    • Place of Presentation
      Warsaw, Poland
    • Year and Date
      2015-09-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 2相分離HCP構造を有するScYLaTiZrHf六元系等原子分率合金2015

    • Author(s)
      竹内 章、網谷 健児、和田 武、湯葢 邦夫
    • Organizer
      公益社団法人 日本金属学会 2015年秋期講演大会(第157回)
    • Place of Presentation
      九州大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] ガラス合金および高エントロピー合金の計算機支援による設計と開発2015

    • Author(s)
      竹内 章、網谷 健児、和田 武、湯葢 邦夫、張 偉
    • Organizer
      一般社団法人 粉体粉末冶金協会 平成27年度春季大会(第115回講演大会)
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-05-26
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 二元系1:1化合物のPettifor Mapを利用した高エントロピー合金の開発2015

    • Author(s)
      竹内 章、網谷健児、和田 武、湯葢 邦夫
    • Organizer
      日本金属学会 2015年春期(第156回)大会
    • Place of Presentation
      東京大学
    • Year and Date
      2015-03-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 計算機支援、データベース利用等による金属ガラスおよび関連合金の設計および開発2015

    • Author(s)
      竹内 章、網谷健児、和田 武、湯葢 邦夫、張 偉
    • Organizer
      金属ガラス・ナノ金属結晶材料合同講演会
    • Place of Presentation
      兵庫県立工業技術センター
    • Year and Date
      2015-01-30
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 稠密六方晶系の高エントロピー合金の作製2014

    • Author(s)
      竹内 章、網谷健児、和田 武、湯葢 邦夫
    • Organizer
      日本金属学会 2014年秋期(第155回)大会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] High-Entropy Glassy Alloys Designed from Ti_2Ni and C_6Cr_23 Structures Using Digitalized Crystallographic Database2013

    • Author(s)
      A. Takeuchi
    • Organizer
      TMS 2013 : 142nd Annual Meeting & Exhibition
    • Place of Presentation
      San Antonio, PA, U. S. A.(招待講演)
    • Year and Date
      2013-03-06
    • Related Report
      2012 Annual Research Report
  • [Presentation] Inter-Transition High-Entropy Glassy Alloys2012

    • Author(s)
      A. Takeuchi
    • Organizer
      Materials Science & Technology 2012 Conference & Exhibition(MS&T2012)
    • Place of Presentation
      Pittsburgh, TX, U. S. A.(招待講演)
    • Year and Date
      2012-10-09
    • Related Report
      2012 Annual Research Report
  • [Presentation] 金属-金属系高エントロピーガラス合金の作製とガラス形成能2012

    • Author(s)
      竹内章
    • Organizer
      日本金属学会2012年秋期講演(第151回)大会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2012-09-18
    • Related Report
      2012 Annual Research Report
  • [Presentation] Statistical Analysis of Equi-Atomic Quinary Alloys for Mixing Enthalpy and Delta Parameter

    • Author(s)
      A. Takeuchi, J.Q. Wang, N. Chen,K. Yubuta and W. Zhang
    • Organizer
      8th Pacific Rim International Congress on Advanced Materials and Processing (PRICM-8)
    • Place of Presentation
      Waikoloa, HI, U.S.A.
    • Related Report
      2013 Annual Research Report
  • [Presentation] 金属ガラスおよび高エントロピー合金の原子寸法差因子の相関の統計解析

    • Author(s)
      竹内 章、網谷健児、和田 武、湯葢邦夫、張 偉
    • Organizer
      日本金属学会2013年秋期(第153回)大会
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Mixing Enthalpy for Alloys Including Al and Structural Enthalpy for High-Entropy Alloys

    • Author(s)
      A. Takeuchi, K. Amiya, T. Wada, K. Yubuta, W. Zhang, A. Makino
    • Organizer
      TMS 2014: 143rd Annual Meeting & Exhibition
    • Place of Presentation
      San Diego, CA, U.S.A.
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 高エントロピー合金、バルク金属ガラスおよび高エントロピーバルク金属ガラス

    • Author(s)
      竹内 章、網谷健児、和田 武、湯葢邦夫、張 偉
    • Organizer
      日本材料学会・金属ガラス部門委員会・第26回研究会
    • Place of Presentation
      兵庫県立大学・神戸ポートアイランドキャンパス
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] Chapter 13, High-Entropy Metallic Glasses, in High-Entropy Alloys: Fundamentals and Applications2016

    • Author(s)
      A. Takeuchi, M.C. Gao, J.W. Qiao and M. Widom
    • Publisher
      Springer International Publishing, Switzerland
    • Related Report
      2016 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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