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Fundamental Research Using Materials Engineering Methods on Removal of Cesium in Clay (Layered Silicates) Soil by Microwave Heating

Research Project

Project/Area Number 24360285
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

Yoshikawa Noboru  東北大学, 環境科学研究科, 准教授 (70166924)

Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2013: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2012: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Keywordsマイクロ波 / 層状珪酸塩 / セシウム / バーミキュライト / イオン置換 / 誘電率 / 導電率 / 加熱 / 粘度土土壌 / 物質工学 / 浸透深さ / ナノ構造 / 微量分析 / 誘電加熱 / 除去 / 粘土土壌
Outline of Final Research Achievements

In this research, vermiculite was selected for a specimen as one of layered silicate salts. Vermiculite was suspended in water and Cs was doped. Various salts were mixed with the Cs-doped vermiculite in solid (powder) state and microwave was irradiated, which was found effective for Cs removal.
Addition of KCl and CaCl2 was effective for the ion exchange of Cs. And it was found that microwave heating has better removal effect than by an electric furnace below 700oC. It was also found that addition of these salts increases the permittivity and electric conductivity, which is related with the better microwave heating characteristics. Further addition of CaCO3 improves the removal effect, however, microwave heating became less easy.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (9 results)

All 2016 2015 2014 2013 2012

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 2 results) Presentation (5 results) Funded Workshop (1 results)

  • [Journal Article] Exchange and removal of Cs ion in clay minerals by microwave application.2015

    • Author(s)
      N.Yoshikawa, T.Sumi, S.Mikoshiba, Y.Itagaki and S.Taniguchi
    • Journal Title

      Proc. 8th Int. Conf. on Electromagnetic Processing of Materials (EPM2015)

      Volume: 8 Pages: 481-484

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Exchange of Cs Ion in Clay Minerals by Microwave Application2014

    • Author(s)
      N.Yoshikawa, T.Sumi, S.Mikoshiba and S.Taniguchi
    • Journal Title

      Ceramics Transactions

      Volume: 249 Pages: 347-335

    • DOI

      10.4028/www.scientific.net/ast.88.21

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Exchange of Cs Ion in Clay Minerals by Microwave Application2014

    • Author(s)
      Noboru Yoshikawa, Takeshi Sumi, Shun Mikoshiba and Shoji Taniguchi
    • Journal Title

      Ceramic Transactions

      Volume: 掲載確定

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 層状珪酸塩(粘土)鉱物中Csのマイクロ波印加イオン置換反応に及ぼす添加物の影響2016

    • Author(s)
      吉川昇、角剛、御子柴駿、板垣勇司、谷口尚司, コマロフセルゲイ
    • Organizer
      日本鉄鋼協会、日本金属学会共同セッション
    • Place of Presentation
      東京理科大葛飾キャンパス(東京都)
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 層状珪酸塩(粘土)鉱物中の Cs イオン置換に及ぼすマイクロ波印加効果2015

    • Author(s)
      吉川昇 、角剛 、御子柴駿 、谷口尚司
    • Organizer
      日本鉄鋼協会
    • Place of Presentation
      東京大学 (東京都目黒区)
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] マイクロ波プロセッシングのための誘電率測定研究会活動と 誘電率測定に関する研究紹介2013

    • Author(s)
      吉川昇、李長全、川平啓太、鈴木宏規、谷口尚司
    • Organizer
      日本鉄鋼協会
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Exchange of Cs Ion in Clay Minerals by Microwave Application2013

    • Author(s)
      Noboru Yoshikawa, Takeshi Sumi, Shun Mikoshiba and Shoji Taniguchi
    • Organizer
      2013 Conference on Materials Science and Technology (MS&T'13)
    • Place of Presentation
      カナダ、モントリオール
    • Related Report
      2013 Annual Research Report
  • [Presentation] Containment of Fukushima Radio Active Pollutions in Microwave Sintered Clay and Glasses2012

    • Author(s)
      吉川昇
    • Organizer
      マイクロ波エネルギー応用に関する国際会議(GCMEA2)
    • Place of Presentation
      米国ロングビーチ
    • Year and Date
      2012-07-26
    • Related Report
      2012 Annual Research Report
  • [Funded Workshop] 8th International Conference on Electromagnetic Processing of Materials (EPM)2015

    • Place of Presentation
      Cannes, France
    • Year and Date
      2015-10-12
    • Related Report
      2015 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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