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Fabrication of intermediate temperature fuel cells using proton conducting anodic oxide film as a novel solud electrolyte

Research Project

Project/Area Number 24360298
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Material processing/treatments
Research InstitutionHokkaido University

Principal Investigator

HABAZAKI HIROKI  北海道大学, 工学(系)研究科(研究院), 教授 (50208568)

Co-Investigator(Kenkyū-buntansha) AOKI Yoshitaka  北海道大学, 大学院工学研究院, 准教授 (50360475)
TSUJI Etsushi  北海道大学, 大学院工学研究院, 助教 (80610443)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2013: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2012: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Keywords燃料電池 / プロトン伝導体 / アノード酸化 / 水素透過膜 / プロトン伝導 / イオニクス / ナノ薄膜 / 中温燃料電池 / 水素透過 / プロトン伝導膜 / 固体電解質 / 水素膜燃料電池
Outline of Final Research Achievements

IIn this study, we investigated the fabrication of membrane-electrode assembly using proton conductive anodic ZrO2-WO3 or ZrO2-WO3-SiO2 nanofilms, which were developed by us, for intermediate temperature fuel cells operating below ~300 degre C. Hydrogen permeable anode foils have been utilized as a support of the proton conducting nanofilms and several fabrication processes have been proposed and examined. We succeeded to generate power. Further, by modifying the anodizing process to form the proton conducting anodic films, we have increased the proton conductivity by nearly one order of magnitude.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (13 results)

All 2015 2014 2013 2012 Other

All Journal Article (4 results) (of which Peer Reviewed: 3 results) Presentation (8 results) (of which Invited: 1 results) Remarks (1 results)

  • [Journal Article] Gas sensing properties of the nanostructured anodic Zr-W oxide film2014

    • Author(s)
      R. M. Vazquez, A. Mozalev, R. Calavia, F. Gispert-Guirado, X. Vilanova, H. Habazaki and E. Llobet
    • Journal Title

      Sensors and Actuators B

      Volume: 204 Pages: 588-595

    • DOI

      10.1016/j.snb.2014.08.014

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Compositional dependence of the proton conductivity of anodic ZrO2-WO3-SiO2 nanofilms at intermediate temperatures2013

    • Author(s)
      K. Ye, Y. Aoki, E. Tsuji, S. Nagata, H. Habazaki
    • Journal Title

      Journal of the Electrochemical Society

      Volume: 160 Issue: 9 Pages: F1096-F1102

    • DOI

      10.1149/2.120309jes

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High proton conductivity in anodic ZrO2-WO3 nanofilms2013

    • Author(s)
      K. Ye, Y. Aoki, E. Tsuji, S. Nagata, H. Habazaki
    • Journal Title

      ECS Transactions

      Volume: 50 Issue: 27 Pages: 193-201

    • DOI

      10.1149/05027.0193ecst

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High Proton Conductivity in Anodic ZrO_2-WO_3-SiO_2 Nanofilms2013

    • Author(s)
      Ke Ye
    • Journal Title

      ECS Transactions

      Volume: (印刷中)

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] アノード酸化ZrO2-WO3-SiO2膜のプロトン伝導性に及ぼす アノード酸化条件の影響2015

    • Author(s)
      514.坂下良介,辻悦司,青木芳尚,幅崎浩樹
    • Organizer
      化学系学協会北海道支部2015年冬季研究発表会
    • Place of Presentation
      北海道大学,札幌
    • Year and Date
      2015-01-27 – 2015-01-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] 燃料電池用水素透過膜アノード/プロトン伝導性ZrO2-WO3電解質膜接合体の作製2014

    • Author(s)
      大庭博司,青木芳尚,辻悦司,幅崎浩樹
    • Organizer
      化学系学協会北海道支部2014年冬季研究発表会
    • Place of Presentation
      北海道大学 (札幌市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 機能性非平衡物質の創製と界面電気化学プロセスの解析2013

    • Author(s)
      幅崎浩樹
    • Organizer
      第80回電気化学会講演大会
    • Place of Presentation
      東北大学(宮城県)(招待講演)
    • Year and Date
      2013-03-31
    • Related Report
      2012 Annual Research Report
  • [Presentation] プロトン伝導性ZrO_2-WO_3アノード酸化ナノ薄膜を電解質とする薄膜燃料電池作製の試み2013

    • Author(s)
      大庭博司
    • Organizer
      化学系学協会北海道支部2013年冬季研究発表
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2013-01-30
    • Related Report
      2012 Annual Research Report
  • [Presentation] High proton conductivity of amorphous ZrO2-WO3-SiO2 nanofilms at intermediate temperatures2013

    • Author(s)
      H. Habazaki, K. Ye, Y. Aoki, E. Tsuji, S. Nagata
    • Organizer
      19th International Conference on Solid State Ionics
    • Place of Presentation
      Kyoto International Conference Center(京都市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 金属のアノード酸化皮膜: その生成プロセスと機能2013

    • Author(s)
      幅崎浩樹
    • Organizer
      資源・素材2013
    • Place of Presentation
      北海道大学 (札幌市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Enhanced Proton Conductivity by Hydrogenation in Anodic ZrO2-WG3-SiO2 Nanofilms2012

    • Author(s)
      Ke Ye
    • Organizer
      PRiME2012
    • Place of Presentation
      ハワイ・コンベンションセンタ(ホノルル・米国)
    • Year and Date
      2012-10-11
    • Related Report
      2012 Annual Research Report
  • [Presentation] Proton conductivity of anodic ZrO2-WO3-SiO2 nanofilms2012

    • Author(s)
      Ke Ye
    • Organizer
      nth Asian Conference on Solid State Ionics
    • Place of Presentation
      東北大学(宮城県)
    • Year and Date
      2012-07-18
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://labs._eng._hokudai._ac._jp/labo/elechem/

    • Related Report
      2012 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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