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Development and Morphology Controlling of a Solid Acid for the Fast and Selective Separation of Cesium

Research Project

Project/Area Number 24360324
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Reaction engineering/Process system
Research InstitutionHokkaido University

Principal Investigator

MUKAI Shin  北海道大学, 工学(系)研究科(研究院), 教授 (70243045)

Co-Investigator(Kenkyū-buntansha) OGINO Isao  北海道大学, 大学院工学研究院, 准教授 (60625581)
IWAMURA Shinichiro  北海道大学, 大学院工学研究院, 助教 (10706873)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000)
Fiscal Year 2014: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2013: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2012: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Keywords化学工学 / 反応・分離工学 / 環境技術 / 環境材料 / セラミックス / ゾル-ゲル / セシウム / ヘテロポリ酸
Outline of Final Research Achievements

In this work, heteropoly acids which form insoluble salts with Cs+ and Prussian blue analogues which selectively adsorb Cs+ were respectively dispersed and immobilized in silica gels and silica-alumina gels using freezing in order to obtain materials which allow the selective recovery of Cs+ existing in an extremely dilute state. Such materials were also molded into the form of microhoneycombs by controlling the direction of freezing in order to reduce the resistance they cause against fluid flows, and to significantly enhance their response speed towards Cs+ recovery.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (32 results)

All 2015 2014 2013 2012 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (25 results) (of which Invited: 1 results) Remarks (1 results)

  • [Journal Article] Development of a Novel Cesium Adsorbent Which Causes Minimal Hydraulic Resistance through the Immobilization of Prussian Blue Analogues in a Monolithic Silica-alumina Microhoneycomb2014

    • Author(s)
      向井紳、木村佳直、吉田誠一郎、荻野勲
    • Journal Title

      Chemical Engineering Transactions

      Volume: 42 Pages: 181-186

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optimizing the Dimensions of Magnesium Ammonium Phosphate to Maximize its Ammonia Uptake Ability2013

    • Author(s)
      増田孝信、荻野勲、向井紳
    • Journal Title

      Advanced Powder Technology

      Volume: 24 Issue: 2 Pages: 520-524

    • DOI

      10.1016/j.apt.2012.10.001

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Sulfonic Acid Functionalized Silica Honeycombs2013

    • Author(s)
      佐藤慶孝、横山裕也、荻野勲、向井紳
    • Journal Title

      Ind. Eng. Chem. Res.

      Volume: 52 Issue: 44 Pages: 15293-15297

    • DOI

      10.1021/ie400541d

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of a Monolithic Carbon-Based Acid Catalyst with a Honeycomb Structure for Flow Reaction Systems2013

    • Author(s)
      村上一博、佐藤慶孝、荻野勲、向井紳
    • Journal Title

      Ind. Eng. Chem. Res.

      Volume: 52 Issue: 44 Pages: 15372-15376

    • DOI

      10.1021/ie400656x

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of a Microhoneycomb-Type Silica-Supported Ammonium Molybdophosphate for Cesium Separation2013

    • Author(s)
      吉田誠一郎、木村佳直、荻野勲、向井紳
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 46 Issue: 9 Pages: 616-619

    • DOI

      10.1252/jcej.13we064

    • NAID

      130003361297

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Immobilization of Magnesium Ammonium Phosphate Crystals within Microchannels for Efficient Ammonia Removal2013

    • Author(s)
      増田隆信、荻野勲、向井紳
    • Journal Title

      Water Science and Technology

      Volume: 67 Issue: 2 Pages: 359-365

    • DOI

      10.2166/wst.2012.525

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] ヘテロポリ酸塩を固定化したマイクロハニカム状シリカによるセシウムの高速処理とその性能評価2015

    • Author(s)
      吉田誠一郎、岩村振一郎、荻野勲、向井紳
    • Organizer
      第24回化学工学・粉体工学研究発表会
    • Place of Presentation
      北見工業大学、北見市
    • Year and Date
      2015-01-31 – 2015-02-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] Ammonium Molybdophosphate を固定化したマイクロハニカム状シリカを用いた連続的なセシウム処理とその性能評価2015

    • Author(s)
      吉田誠一郎、岩村振一郎、荻野勲、向井紳
    • Organizer
      化学系学協会北海道支部 2015年冬季研究発表会
    • Place of Presentation
      北海道大学、札幌市
    • Year and Date
      2015-01-27 – 2015-01-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Continuous Cesium Separation Using a Silica Microhoneycomb Supporting Ammonium Molybdophosphate2014

    • Author(s)
      吉田誠一郎、木村佳直、荻野勲、向井紳
    • Organizer
      2014 AIChE Annual Meeting
    • Place of Presentation
      Atlanta Marriott Marquis & Hilton Atlanta, Atlanta, U.S.A
    • Year and Date
      2014-11-16 – 2014-11-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] Analysis of the Residence Time Distribution of Substrate in Monolithic Carbons Having Honeycomb Structure Synthesized Using Ice Templating Method2014

    • Author(s)
      高橋峻平、佐藤慶孝、荻野勲、向井紳
    • Organizer
      The 23rd International Symposium on Chemical Reaction Engineering
    • Place of Presentation
      Centara Grand & Bangkok Convention Centre (BCC) at Central World, Bangkok, Thailand
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Silica Microhoneycomb Supporting Heteropoly Salts for Continuous Cesium Separation2014

    • Author(s)
      吉田誠一郎、木村佳直、荻野勲、向井紳
    • Organizer
      The 3rd Frontier Chemistry Center International Symposium
    • Place of Presentation
      北海道大学、札幌市
    • Year and Date
      2014-06-13 – 2014-06-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Development of a Cesium Adsorbent for High Throughput Processing through the Immobilization of Prussian Blue Type Nanoparticles in a Silica-Alumina Microhoneycomb2014

    • Author(s)
      向井紳、木村佳直、吉田誠一郎、荻野勲
    • Organizer
      ACS 247th National Meeting & Exposition
    • Place of Presentation
      Dallas Convention Center、ダラス市、米国
    • Related Report
      2013 Annual Research Report
  • [Presentation] 12-モリブドリン酸三アンモニウム固定化シリカマイクロハニカムによるセシウムの連続処理2014

    • Author(s)
      吉田誠一郎、木村佳直、荻野勲、向井紳
    • Organizer
      化学系学協会北海道支部 2014年冬季研究発表会
    • Place of Presentation
      北海道大学、札幌市
    • Related Report
      2013 Annual Research Report
  • [Presentation] セシウムの連続分離に適したマイクロハニカム状へテロポリ酸塩・シリカ複合体の開発2014

    • Author(s)
      木村佳直、吉田誠一郎、荻野勲、向井紳
    • Organizer
      第23回化学工学・粉体工学研究発表会
    • Place of Presentation
      北海道大学、札幌市
    • Related Report
      2013 Annual Research Report
  • [Presentation] 12-モリブドリン酸三アンモニウムを固定化したシリカマイクロハニカムによるセシウムの連続分離2013

    • Author(s)
      吉田誠一郎、木村佳直、荻野勲、向井紳
    • Organizer
      第22回化学工学・粉体工学研究発表会
    • Place of Presentation
      北海道大学、函館市
    • Year and Date
      2013-02-02
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis of a Honeycomb-Type Carbon-Based Acid Catalyst for Flow Reaction Systems2013

    • Author(s)
      荻野勲、村上一博、佐藤慶孝、向井紳
    • Organizer
      23rd North American Catalysis Society Meeting
    • Place of Presentation
      Galt House Hotel、ルイビル市、米国
    • Related Report
      2013 Annual Research Report
  • [Presentation] Fluid Property of a Monolith Having Honeycomb Structure Synthesized Using Ice Templating Method2013

    • Author(s)
      佐藤慶孝、高橋峻平、村上一博、荻野勲、向井紳
    • Organizer
      The 16th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis
    • Place of Presentation
      北海道大学、札幌市
    • Related Report
      2013 Annual Research Report
  • [Presentation] Development of a Novel Cesium Adsorbent Which Causes Minimal Hydraulic Resistance through the Immobilization of Prussian Blue Analogues in a Monolithic Silica-alumina Microhoneycomb2013

    • Author(s)
      向井紳、木村佳直、吉田誠一郎、荻野勲
    • Organizer
      8th Conference on Sustainable Development of Energy, Water and Environment Systems
    • Place of Presentation
      ドブロフニク大学、ドブロフニク市、クロアチア
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 12-モリブドリン酸三アンモニウムを固定化したマイクロハニカム状シリカによるセシウムの高速分2013

    • Author(s)
      吉田誠一郎、木村佳直、荻野勲、向井紳
    • Organizer
      第27回日本吸着学会研究発表会
    • Place of Presentation
      千葉大学、千葉市
    • Related Report
      2013 Annual Research Report
  • [Presentation] Strengthening of Monolithic Silica with Microhoneycombs Synthesized Using Ice Templating Method2012

    • Author(s)
      荻野勲、三好悠基、佐藤慶孝、向井紳
    • Organizer
      The 6th International Conference on Multi-Functional Materials and Applications
    • Place of Presentation
      ハンバツト国立大学、大田市、韓国(招待講演)
    • Year and Date
      2012-11-23
    • Related Report
      2012 Annual Research Report
  • [Presentation] Tuning the Hierarchical Pore Structure of Monolithic Silica Having Honeycomb Structure via the Ice Templating Method2012

    • Author(s)
      佐藤慶孝、荻野勲、向井紳
    • Organizer
      The 6th International Conference on Multi-Functional Materials and Applications
    • Place of Presentation
      ハンバット国立大学、大田市、韓国
    • Year and Date
      2012-11-23
    • Related Report
      2012 Annual Research Report
  • [Presentation] Utilization of Heteropoly Acid Supported by Silica Microhoneycomb in a Flow System2012

    • Author(s)
      村上一博、吉田誠一郎、橋本昌俊、荻野勲、向井紳
    • Organizer
      The 6th International Conference on Multi-Functional Materials and Applications
    • Place of Presentation
      ハンバット国立大学、大田市、韓国
    • Year and Date
      2012-11-23
    • Related Report
      2012 Annual Research Report
  • [Presentation] セシ不溶性フェロシアン化物のシリカアルミナマイクロハニカムへの包含によるセシウム吸着剤の創製2012

    • Author(s)
      木村佳直、吉田誠一郎、荻野勲、向井紳
    • Organizer
      第26回日本吸着学会研究発表会
    • Place of Presentation
      産業技術総合研究所、つくば市
    • Year and Date
      2012-11-15
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis of Silica Microhoneycomb-Immobilized Heteropoly Acid Catalystfor Liquid"Phase Esterification Reaction2012

    • Author(s)
      村上一博、吉田誠一郎、橋本昌俊、荻野勲、向井紳
    • Organizer
      10th Japan-Korea Symposium on Materials & Interfaces
    • Place of Presentation
      大学生協京都会館、京都市
    • Year and Date
      2012-11-08
    • Related Report
      2012 Annual Research Report
  • [Presentation] スルホ基導入によるシリカマイクロハニカムの高機能化2012

    • Author(s)
      横山裕也、佐藤慶孝、荻野勲、向井紳
    • Organizer
      触媒学会第110回触媒討論会
    • Place of Presentation
      九州大学、福岡市
    • Year and Date
      2012-09-25
    • Related Report
      2012 Annual Research Report
  • [Presentation] Nafion樹脂固定化シリカマイクロハニカムの細孔構造制御による触媒性能の向上2012

    • Author(s)
      佐藤慶孝、荻野勲、向井紳
    • Organizer
      触媒学会第110回触媒討論会
    • Place of Presentation
      九州大学、福岡市
    • Year and Date
      2012-09-24
    • Related Report
      2012 Annual Research Report
  • [Presentation] 氷晶テンプレート法を利用して作製したシリカマイクロハニカムのTEOS中エージングによる構造強化2012

    • Author(s)
      三好悠基、佐藤慶孝、荻野勲、向井紳
    • Organizer
      化学工学会第44回秋季大会
    • Place of Presentation
      東北大学、仙台市
    • Year and Date
      2012-09-21
    • Related Report
      2012 Annual Research Report
  • [Presentation] 氷晶テンプレート法を用いたマイクロハニカム状弱酸性イオン交換樹脂の開発とその応用2012

    • Author(s)
      妹尾元基、佐藤慶孝、村上一博、荻野勲、向井紳
    • Organizer
      化学工学会第44回秋季大会
    • Place of Presentation
      東北大学、仙台市
    • Year and Date
      2012-09-20
    • Related Report
      2012 Annual Research Report
  • [Presentation] Development of a Carbon-Based Solid-Acid Catalyst with a Low Hydraulic Resistance2012

    • Author(s)
      向井紳、村上一博、佐藤慶孝、荻野勲
    • Organizer
      22nd International Symposium on ChemicalReaction Engineering
    • Place of Presentation
      Maastricht Exhibition &Congress Centres、マーストリヒト市、オランダ
    • Year and Date
      2012-09-03
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis of Silica Microhoneycombs Including Nafion Nanoparticles via the IceTemplating Method2012

    • Author(s)
      佐藤慶孝、三浦雄一郎、荻野勲、向井紳
    • Organizer
      ZMPC 2012
    • Place of Presentation
      アステールプラザ広島、広島市
    • Year and Date
      2012-07-29
    • Related Report
      2012 Annual Research Report
  • [Presentation] Carbon Gels with Unique Morphologies2012

    • Author(s)
      向井紳
    • Organizer
      The 3rd German-Japanese on Carbon Materials
    • Place of Presentation
      Hotel Seminaris、ベルリン市、ドイツ(招待講演)
    • Year and Date
      2012-06-25
    • Related Report
      2012 Annual Research Report
  • [Remarks] 材料化学工学研究室研究室概要

    • URL

      http://mde-cp.eng.hokudai.ac.jp/outline.html

    • Related Report
      2014 Annual Research Report

URL: 

Published: 2012-04-24   Modified: 2019-07-29  

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