Development of environmentally-benign solid catalysts for ubiquitous green organic synthesis
| Project/Area Number |
24360333
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Kagawa University (2013-2014)
Kyoto University (2012) |
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Principal Investigator |
WADA Kenji 香川大学, 医学部, 教授 (10243049)
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| Co-Investigator(Renkei-kenkyūsha) |
HOSOKAWA Saburo 京都大学実験と理論計算科学のインタープレイによる触媒, 電池の元素戦略研究拠点ユニット, 特定講師 (90456806)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Fiscal Year 2014: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2013: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2012: ¥12,350,000 (Direct Cost: ¥9,500,000、Indirect Cost: ¥2,850,000)
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| Keywords | グリーンケミストリー / 固体触媒 / ルテニウム / イリジウム / ロジウム / 鉄 / 酸化セリウム / C-H結合活性化 / シリル化 |
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| Outline of Final Research Achievements |
In the present study, environmentally-benign solid catalysts that enable a wide range of green organic transformation with high atom efficiency have developed. Ceria-supported ruthenium (Ru/CeO2) was found to be an effective catalyst for linear-selective dimerization of styrenes. The catalytic intermolecular hydroacylation of alkynes has been achieved in the presence of Ru catalysts. Phospine-modified ceria-supported rhodium catalysts with excellent activity in silylative coupling reactions have been also developed. On the other hand, HCHO-treated Ru/CeO2 also showed excellent activity towards the silylative coupling reaction. Towards the dehydrogenative silylation of alkenes by a hydrosilane, the combination of a small amount of Ir complexes and ceria was found to show excellent activity. In addition, metastable hexagnal iron-based mixed oxides, REFeO3, has been successfully prepared .
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Report
(4 results)
Research Products
(25 results)
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[Journal Article] Highly Selective Linear Dimerization of Styrenes by Ceria-Supported Ruthenium Catalysts2012
Author(s)
Shimura, S., Miura, H., Tsukada, S., Wada, K; Hosokawa, S., Inoue, M.
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Journal Title
ChemCatChem
Volume: 4
Issue: 12
Pages: 2062-2067
DOI
Related Report
Peer Reviewed
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[Journal Article] Dehydrogenative jV-Heterocyclization of 2- (2-Aminoaryl)ethyl Alcohols to Indole Deriatives Catalyzed by (μ-Oxo)teteraruthenium Cluster /l,2-bis(diphenylphosphino)benzene2012
Author(s)
Kondo, T., Kanda, T., Takagi, D., Wada, K.; Kimura, Y., Tbshimitsu, A.
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Journal Title
Heterocycles
Volume: 86
Issue: 2
Pages: 1015-1022
DOI
Related Report
Peer Reviewed
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