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Development of advanced mineral processing technology for treatment of impurity ore by flotation and leaching combination process

Research Project

Project/Area Number 24360370
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Earth system and resources enginnering
Research InstitutionAkita University

Principal Investigator

SHIBAYAMA ATSUSHI  秋田大学, その他部局等, 教授 (30323132)

Co-Investigator(Kenkyū-buntansha) HAGA Kazutoshi  秋田大学, 大学院工学資源学研究科, 助教 (10588461)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2013: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2012: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Keywords浮選 / アルカリ浸出 / ミネラルプロセシング / 硫砒銅鉱 / 四面銅鉱 / 不純物 / ヒ素 / アンチモン / 浸出 / 銅鉱石
Outline of Final Research Achievements

This study investigated the development of advanced mineral processing such as flotation - leaching - precipitation for removing impurities such as arsenic (As) and antimony (Sb) from copper ore with tennantite, tetrahedratite and enargite. In flotation, 95 % of enargite (Cu3AsS4) was recovered from the ore at pH4. On the other hand, recovery of chalcopyrite reached 20%. It is possible to separate enargite and chalcopyrite by controlling hydrophobicity of mineral surface and stability of froth that forms in the flotation cell by the addition of flotation reagents. In alkaline leaching, 90% of As and Sb were dissolved from the ore in NaOH - NaHS media under the optimum leaching conditions. In precipitation, more than 90 % of As and Sb were removed as a precipitate from the solution by adding sulphur, cooling and conditioning. Accordingly, valuable treatment conditions for removing impurities such as arsenic (As) and antimony (Sb) from dirty copper ore were developed.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (16 results)

All 2015 2014 2013 2012

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (14 results)

  • [Journal Article] アルカリ浸出と沈殿処理による四面銅鉱からのヒ素およびアンチモン除去プロセスの開発2015

    • Author(s)
      芳賀一寿、バトナサン アルタンスック、柴山敦
    • Journal Title

      Journal of MMIJ

      Volume: 131 Pages: 27-32

    • NAID

      130005117318

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Floatability of Bubble behavior in Seawater Flotation for the Recovering Copper Mineral2014

    • Author(s)
      Haga, K., Nishioka, K., Altansukh, B. and Shibayama, A.
    • Journal Title

      International Journal of Materials Engineering and Resource Science

      Volume: Vol.20, No.1 Pages: 82-86

    • NAID

      130005095367

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Investigation of copper recovery from low-grade silicate-copper ore by flotation and leaching2014

    • Author(s)
      Shibayama, A., Altansukh, B. and Haga, K.
    • Organizer
      International Mineral Processing Congress 2014 (IMPC2014)
    • Place of Presentation
      Sheraton Hotel(チリ・サンチアゴ市)
    • Year and Date
      2014-10-20 – 2014-10-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] The investigation of copper recovery process from nine tailing by flotation and high pressure leaching2014

    • Author(s)
      Han, B., Altansukh, B., Haga, K., Stevanovic, Z., Radojka, J., Marcovic, R., Avramovic, L., Obradovic, L., Takasaki, T., Masuda, N., Ishiyama, D., and Shibayama, A.
    • Organizer
      International Mineral Processing Congress 2014 (IMPC2014)
    • Place of Presentation
      Sheraton Hotel(チリ・サンチアゴ市)
    • Year and Date
      2014-10-20 – 2014-10-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fundamental study of the effect of flotation reagents on copper flotation with seawater2014

    • Author(s)
      Haga, K., Nishioka, K., Altansukh, B., and Shibayama, A.
    • Organizer
      International Mineral Processing Congress 2014 (IMPC2014)
    • Place of Presentation
      Sheraton Hotel(チリ・サンチアゴ市)
    • Year and Date
      2014-10-20 – 2014-10-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 浮選による低品位銅鉱石からの銅回収条件の検討2014

    • Author(s)
      韓百歳,バトナサン アルタンスック,芳賀一寿,柴山敦
    • Organizer
      資源・素材秋季大会 資源・素材2014(熊本)
    • Place of Presentation
      熊本大学(熊本市)
    • Year and Date
      2014-09-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] 浮遊選鉱法を用いた黄銅鉱と砒四面銅鉱の分離条件の検討2014

    • Author(s)
      早川亮史,芳賀一寿,柴山敦
    • Organizer
      日本素材物性学会平成26年度(第24回)年会
    • Place of Presentation
      秋田ビューホテル(秋田市)
    • Year and Date
      2014-06-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 浮遊選鉱法を用いた低品位銅鉱石からの銅回収における起泡剤の影響2014

    • Author(s)
      中川正大,中本裕香,芳賀一寿,柴山敦
    • Organizer
      資源・素材学会東北支部平成26年度春季大会
    • Place of Presentation
      東北大学(仙台市)
    • Year and Date
      2014-06-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Floatability and bubble behavior in seawater flotation for the recovering copper mineral2013

    • Author(s)
      Nishioka, K., Haga, K., Altansukh, B. and Shibayama, A.
    • Organizer
      International Conference on Materials Engineering for Resources
    • Place of Presentation
      Akita, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Investigation of tennantite/tetratedrite treatment process by alkaline leaching and precipitation2013

    • Author(s)
      Shibayama, A., Altansukh, B., Haga, K.
    • Organizer
      Copper 2013
    • Place of Presentation
      Santiago, Chile
    • Related Report
      2013 Annual Research Report
  • [Presentation] 銅鉱物の浮選分離に及ぼす海水成分の影響2013

    • Author(s)
      西岡 昂祐,芳賀 一寿,柴山 敦
    • Organizer
      資源・素材学会東北支部平成25年度春季大会
    • Place of Presentation
      東北大学、仙台、日本
    • Related Report
      2013 Annual Research Report
  • [Presentation] 選鉱・湿式分離技術を用いたヒ素含有銅鉱石処理に関する研究と現状2013

    • Author(s)
      芳賀 一寿,柴山 敦
    • Organizer
      資源・素材平成25年度秋季大会 資源・素材2013(札幌)
    • Place of Presentation
      北海道大学、札幌、日本
    • Related Report
      2013 Annual Research Report
  • [Presentation] アルカリ浸出-沈殿処理による四面銅鉱処理プロセスの検討2013

    • Author(s)
      芳賀 一寿,柴山 敦
    • Organizer
      資源・素材平成25年度秋季大会 資源・素材2013(札幌)
    • Place of Presentation
      北海道大学、札幌、日本
    • Related Report
      2013 Annual Research Report
  • [Presentation] 海水を用いた銅鉱物の浮選分離に関する基礎的研究2013

    • Author(s)
      西岡 昂祐,芳賀 一寿,柴山 敦
    • Organizer
      資源・素材平成25年度秋季大会 資源・素材2013(札幌)
    • Place of Presentation
      北海道大学、札幌、日本
    • Related Report
      2013 Annual Research Report
  • [Presentation] EnargiteとChalcopyriteの浮遊挙動と分離条件の最適化2013

    • Author(s)
      芳賀一寿, 池田春美, 柴山敦
    • Organizer
      資源・素材学会春季大会
    • Place of Presentation
      千葉工業大学(習志野市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] コレクターレス浮選におけるEnargiteの浮遊挙動2012

    • Author(s)
      芳賀一寿,池田春美, William Tongamp, 柴山敦
    • Organizer
      資源・素材2012 (秋田)
    • Place of Presentation
      秋田大学(秋田市)
    • Related Report
      2012 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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