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Separation and recovery of rare metals from secondary buttery using mineral processing and refining technologies

Research Project

Project/Area Number 24360376
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Recycling engineering
Research InstitutionKansai University

Principal Investigator

SHIBATA Junji  関西大学, 環境都市工学部, 教授 (70067742)

Co-Investigator(Kenkyū-buntansha) MURAYAMA Norihiro  関西大学, 環境都市工学部, 准教授 (90340635)
KOYANAKA Shigeki  独立行政法人産業技術総合研究所, 環境管理技術研究部門, 主任研究員 (60357035)
村山 憲弘  関西大学, 環境都市工学部, 准教授 (90340653)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥13,650,000 (Direct Cost: ¥10,500,000、Indirect Cost: ¥3,150,000)
Fiscal Year 2014: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2013: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Keywords二次電池 / レアメタル / リサイクル / 乾式処理 / 湿式処理 / 粉砕 / 分級 / 溶媒抽出 / リチウムイオン電池 / ニッケル水素電池 / 2次電池 / 粉砕・選別 / 溶媒抽出法 / マスキング効果 / 技術のブレークスルー
Outline of Final Research Achievements

Lithium ion battery (LIB) is composed of valuable metals such as Li, Co, Ni. The toxic and flammable electrolyte, LiPF6, and organic solvents, ethylene carbonate and dimethyl carbonate are used for an electrolytic solution. By this reason, the treatment process should have crushing, classifying and hydrometallurgical treatments after burning LIB at about 500℃.
The recycling technology of used LIB has been investigated in order to recover rare metals such as Li, Co and Ni with the combination process of crushing, classifying and hydrometallurgical treatments. The burnt LIB used for PC was employed in this research. Then, the physical treatments consisting of crushing, classifying and magnetic separation, and the chemical treatments containing acid leaching, hydroxide precipitation, solvent extraction and carbonate precipitation methods were applied. The treatment process for LIB was established according to our results.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (20 results)

All 2014 2013 2012 Other

All Journal Article (9 results) (of which Peer Reviewed: 7 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (9 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Recycling Technology for Lithium Ion Battery by Crushing and Classification, and Hydrometallurgical Process2014

    • Author(s)
      蓬莱賢一,芝田隼次,村山憲弘,古屋仲茂樹,新苗正和
    • Journal Title

      Journal of the Japan Institute of Metals and Materials

      Volume: 78 Issue: 7 Pages: 250-257

    • DOI

      10.2320/jinstmet.JA201402

    • NAID

      130004786468

    • ISSN
      0021-4876, 1880-6880, 2433-7501
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Study of Crushing and Physical Separation Properties of Nickel-Hydrogen Battery2014

    • Author(s)
      蓬莱賢一,芝田隼次,村山憲弘,古屋仲茂樹
    • Journal Title

      Resources Processing

      Volume: 61 Issue: 3 Pages: 177-184

    • DOI

      10.4144/rpsj.61.177

    • NAID

      130004713112

    • ISSN
      1348-6012, 1349-9262
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] リチウムイオン電池のリサイクル2014

    • Author(s)
      芝田隼次,村山憲弘
    • Journal Title

      ケミカルエンジニアリング

      Volume: 59 Pages: 17-23

    • Related Report
      2013 Annual Research Report
  • [Journal Article] 粉砕・分級と湿式処理によるリチウムイオン電池のリサイクル2014

    • Author(s)
      蓬莱賢一,芝田隼次,村山憲弘,古屋仲茂樹,新苗正和
    • Journal Title

      日本金属学会誌

      Volume: 78

    • NAID

      130004786468

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solvent Extraction of Li and Co by using the Masking Effect of Chelating Agents2013

    • Author(s)
      田中智史,椋田裕行,蓬莱賢一,村山憲弘,芝田隼次,佐伯智則
    • Journal Title

      KAGAKU KOGAKU RONBUNSHU

      Volume: 39 Issue: 4 Pages: 294-300

    • DOI

      10.1252/kakoronbunshu.39.294

    • NAID

      10031188065

    • ISSN
      0386-216X, 1349-9203
    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Leaching and Separation of Li and Co from Under Size Product of Roasted and Crushed Lithium Ion Battery2013

    • Author(s)
      田中智史,椋田裕行,村山憲弘,芝田隼次,佐伯智則
    • Journal Title

      KAGAKU KOGAKU RONBUNSHU

      Volume: 39 Issue: 5 Pages: 466-471

    • DOI

      10.1252/kakoronbunshu.39.466

    • NAID

      130004463933

    • ISSN
      0386-216X, 1349-9203
    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] キレート化剤のマスキング効果を用いた溶媒抽出によるLi^+およびCo^<2+>の抽出分離2013

    • Author(s)
      田中智史, ら
    • Journal Title

      化学工学論文集

      Volume: (掲載決定)

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 使用済みリチウムイオン電池焼成物の選択破砕・物理選別特性に関する実験的2012

    • Author(s)
      古屋仲茂樹, ら
    • Journal Title

      J.MMIJ

      Volume: Vol.128 Pages: 232-240

    • Related Report
      2012 Annual Research Report
  • [Journal Article] 廃リチウムイオン二次電池塩酸浸出液からの金属の溶媒抽出分離プロセス2012

    • Author(s)
      新苗正和, ら
    • Journal Title

      環境資源工学

      Volume: 59,(3) Pages: 131-136

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] 使用済みリチウムイオン電池の湿式処理2013

    • Author(s)
      蓬莱賢一, ら
    • Organizer
      化学工学第78年会
    • Place of Presentation
      大阪大学
    • Year and Date
      2013-03-19
    • Related Report
      2012 Annual Research Report
  • [Presentation] レアメタルの利用とリサイクル技術 -技術のブレークスルー-2013

    • Author(s)
      芝田隼次
    • Organizer
      大阪商工会議所、金属部会第4会講演会
    • Place of Presentation
      大阪商工会議所(招待講演)
    • Year and Date
      2013-02-18
    • Related Report
      2012 Annual Research Report
  • [Presentation] レアメタルの回収技術とBreakthroughの重要性2012

    • Author(s)
      芝田隼次
    • Organizer
      福岡県リサイクル総合研究センター講演会
    • Place of Presentation
      小倉会議場(招待講演)
    • Year and Date
      2012-10-13
    • Related Report
      2012 Annual Research Report
  • [Presentation] キレート化剤のマスキング効果を利用したLiの抽出分離2012

    • Author(s)
      田中智史, ら
    • Organizer
      資源素材学会平成24年秋期大会
    • Place of Presentation
      秋田大学
    • Year and Date
      2012-09-12
    • Related Report
      2012 Annual Research Report
  • [Presentation] リチウムイオン電池のリサイクルプロセスへの晶析剥離法の適用

    • Author(s)
      椋田裕行,蓬莱賢一,村山憲弘,芝田隼次
    • Organizer
      資源・素材学会,資源・素材2013
    • Place of Presentation
      北海道大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] キレート化剤のマスキング効果を用いたLi+とCo2+の選択的抽出

    • Author(s)
      椋田裕行,田中智史,村山憲弘,芝田隼次
    • Organizer
      日本溶媒抽出学会,第32回溶媒抽出討論会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] リチウムイオン電池のリサイクル技術

    • Author(s)
      芝田隼次,村山憲弘
    • Organizer
      第18回関西大学先端科学技術シンポジウム
    • Place of Presentation
      関西大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 晶析剥離法によるリチウムイオン電池浸出液からのLiの回収プロセス

    • Author(s)
      椋田裕行,保田恵太,村山憲弘,芝田隼次
    • Organizer
      資源・素材学会,平成26年度春季大会
    • Place of Presentation
      東京大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] リチウムイオン電池の処理技術、どうする価値のない電池の処理?

    • Author(s)
      蓬莱賢一,芝田隼次,村山憲弘
    • Organizer
      資源・素材学会,平成26年度春季大会
    • Place of Presentation
      東京大学
    • Related Report
      2013 Annual Research Report
  • [Book] 粉体精製と湿式処理 -基礎と応用-2012

    • Author(s)
      芝田隼次, ら
    • Total Pages
      200
    • Publisher
      環境資源工学会発行(会長 芝田隼次)
    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] リチウムイオン電池の再資源化方法およびその装置2012

    • Inventor(s)
      芝田隼次, ら
    • Industrial Property Rights Holder
      関西大学
    • Industrial Property Number
      2012-199564
    • Filing Date
      2012-09-11
    • Related Report
      2012 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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