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Middle-temperature waste heat utilization by thermochemical energy storage material accompanied with high-thermal conductivity

Research Project

Project/Area Number 24360404
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Energy engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

Kato Yukitaka  東京工業大学, 原子炉工学研究所, 教授 (20233827)

Co-Investigator(Kenkyū-buntansha) RYU JUNICHI  千葉大学, 工学研究科, 准教授 (70376937)
Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,590,000 (Direct Cost: ¥14,300,000、Indirect Cost: ¥4,290,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2013: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2012: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Keywords化学蓄熱 / 中温 / 酸化マグネシウム / 伝熱促進 / 反応促進 / 充填層反応 / 中温排熱 / 膨張化グラファイト / 蓄熱 / 排熱利用
Outline of Final Research Achievements

Composite thermochemical energy storage material (EM) mixed with magnesium hydroxide (Mg(OH)2) and expanded graphite (EG) is developed. It was demonstrated by kinetic analysis by using a thermo-balance that EG has higher thermal conductivity, vapor diffusivity and reactivity than one of conventional Mg(OH)2. Tablet figure of EM was discussed as a suitable figure for practical packed bed reactor having heat-exchanging function. It was shown that mixing mass ratio of Mg(OH)2 : EG = 8 : 1 was the optimum mixing ratio in the stand point of reactivity per unit mass of material. The tablet EM was used for a packed bed experiment for demonstration of practical thermochemical energy storage performance of EM. The EM packed bed had higher heat storage amount and heat storage rate than one of conventional Mg(OH)2. Then, it was demonstrated from this study that thermochemical energy storage system using the EM material would have new possibility for middle-temperature heat utilization.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (29 results)

All 2016 2015 2014 2013 2012

All Journal Article (12 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 12 results,  Acknowledgement Compliant: 6 results,  Open Access: 4 results) Presentation (14 results) (of which Int'l Joint Research: 4 results,  Invited: 2 results) Book (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Thermal Conductivity Measurements of Expanded Graphite-Magnesium Hydroxide Composites for Packed Bed Reactors of Chemical Heat Storage/Pump Systems2016

    • Author(s)
      1.Massimiliano Zamengo, Juraj Tomaskovic, Junichi Ryu, Yukitaka Kato
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 49 Issue: 3 Pages: 261-267

    • DOI

      10.1252/jcej.14we292

    • NAID

      130005137814

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Kinetic Characterization of Expanded Graphite, Calcium Chloride, and Magnesium Hydroxide Composite for the Chemical Heat Pump2015

    • Author(s)
      S. T. Kim, M. Zamengo, J. Ryu, Y. Kato
    • Journal Title

      Heat Transfer Research

      Volume: 46 Issue: 2 Pages: 91-107

    • DOI

      10.1615/heattransres.2014006874

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Reaction Performance of Calcium Hydroxide and Expanded Graphite Composites for Chemical Heat Storage Applications2015

    • Author(s)
      Jun Kariya, Junicihi Ryu, Yukitaka Kato
    • Journal Title

      ISIJ International

      Volume: 55 Issue: 2 Pages: 457-463

    • DOI

      10.2355/isijinternational.55.457

    • NAID

      130004734553

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Waste Heat Recovery from Iron Production by Using Magnesium Oxide/Water Chemical Heat Pump as Thermal Energy Storage2015

    • Author(s)
      Odtsetseg MYAGMARJAV, Junichi RYU, Yukitaka KATO
    • Journal Title

      ISIJ International

      Volume: 55 Issue: 2 Pages: 464-472

    • DOI

      10.2355/isijinternational.55.464

    • NAID

      130004734556

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Numerical Analysis of Chemical Heat Storage Units for Waste Heat Recovery in Steel Making Processes2015

    • Author(s)
      M. Zamengo, J. Ryu, Y. Kato
    • Journal Title

      ISIJ International

      Volume: 55 Issue: 2 Pages: 473-482

    • DOI

      10.2355/isijinternational.55.473

    • NAID

      130004734555

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Dehydration Kinetic Study of a Chemical Heat Storage Material with Lithium Bromide for a Magnesium Oxide/Water Chemical Heat Pump2015

    • Author(s)
      O. MYAGMARJAV, J. RYU, Y. KATO
    • Journal Title

      Prog. Nuc. Eng.

      Volume: 82 Pages: 153-158

    • DOI

      10.1016/j.pnucene.2014.07.026

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Kinetic Analysis of the Effects of Mixing Mole Ratios of LiBr-to-Mg(OH)<sub>2</sub> on Dehydration and Hydration2014

    • Author(s)
      Odtsetseg Myagmarjav, Junichi Ryu, Yukitaka Kato
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 47 Issue: 7 Pages: 595-601

    • DOI

      10.1252/jcej.13we301

    • NAID

      130004056949

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] The optimization of mixing ratio of expanded graphite mixed chemical heat storage material for magnesium oxide/water chemical heat pump2014

    • Author(s)
      Seon Tae Kim, Junichi Ryu, Yukitaka Kato
    • Journal Title

      Applied Therm. Eng.

      Volume: 66 Issue: 1 Pages: 274-281

    • DOI

      10.1016/j.applthermaleng.2012.07.005

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermochemical performance of magnesium hydroxide - expanded graphite pellets for a packed bed reactor chemical heat pump2014

    • Author(s)
      Zamengo M.,Ryu J., Kato Y.
    • Journal Title

      Applied Thermal Engineering

      Volume: 64 Issue: 1-2 Pages: 339-347

    • DOI

      10.1016/j.applthermaleng.2013.12.036

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnesium hydroxide - expanded graphite composite pellets for a packed bed reactor chemical heat pump2013

    • Author(s)
      Zamengo M.,Ryu J., Kato Y.
    • Journal Title

      Applied Thermal Engineering

      Volume: 61 Issue: 2 Pages: 853-858

    • DOI

      10.1016/j.applthermaleng.2013.04.045

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The optimized mixing ratio of expanded graphite mixture for packed bed reactor of chemical heat pump2013

    • Author(s)
      Seon Tae KIM, Junichi RYU, Yukitaka KATO
    • Journal Title

      Applied Thermal Engineering

      Volume: 50 Pages: 485-490

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evaluation of Heat Output Densities of Lithium Chloride-Modified Magnesium Hydroxide for Thermochemical Energy Storage2013

    • Author(s)
      Hirokazu Ishitobi, Naoya Hirao, Junichi Ryu, Yukitaka Kato
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: (掲載確定)(印刷中) Issue: 15 Pages: 1639-1644

    • DOI

      10.1021/ie302841y

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Development of Chemical Heat Storage Material for a Combined System with Load-following Nuclear Power Plant2015

    • Author(s)
      Odtsetseg Myagmarjav and Yukitaka Kato
    • Organizer
      THE 3rd JAPAN-CHINA ACADEMIC SYMPOSIUM ON NUCLEAR FUEL CYCLE (ASNFC 2015)
    • Place of Presentation
      Tokyo
    • Year and Date
      2015-12-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermochemical energy storage for waste heat recoveries and utilizations2015

    • Author(s)
      Y. Kato
    • Organizer
      World Engineering Conference and Convention (WECC2015)
    • Place of Presentation
      Kyoto
    • Year and Date
      2015-12-01
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Compacted block of magnesium hydroxide; expanded graphite for heat storage/output enhancement in thermochemical energy storage systems2015

    • Author(s)
      Massimiliano ZAMENGO, Junichi RYU, Keiko FUJIOKA, Junko MORIKAWA, Yukitaka KATO
    • Organizer
      Sorption Friends’ Meeting
    • Place of Presentation
      Sicily, Italy
    • Year and Date
      2015-09-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reaction Performance of Calcium Hydroxide and Vermiculite Composite for Chemical Heat Storage Application2015

    • Author(s)
      Jun Kariya, Junichi Ryu, Yukitaka Kato
    • Organizer
      Proc. of The 13th International Conference on Energy Storage (GREENSTOCK 2015)
    • Place of Presentation
      Beijin, China
    • Year and Date
      2015-05-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reaction Performance Enhancement of Chemical Heat Storage Material Mixed with Expanded Graphite for CaO/H2O Chemical Heat Pump2014

    • Author(s)
      J. Kariya, Y. Kato
    • Organizer
      Eurotherm Seminar 99
    • Place of Presentation
      Lleida, Spain
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Investigations on a composite block for a magnesium oxide / water chemical heat pump2013

    • Author(s)
      Zamengo Massimiliano, Ryu Junichi, Kato Yukitaka
    • Organizer
      化学工学会第78年会
    • Place of Presentation
      大阪
    • Year and Date
      2013-03-19
    • Related Report
      2012 Annual Research Report
  • [Presentation] Chemical heat storage of thermal energy from a nuclear reactor by using a magnesium hydroxide/expanded graphite composite material2013

    • Author(s)
      M Zamengo, J Ryu, Y Kato
    • Organizer
      The Fourth International Symposium on Innovative Nuclear Energy Systems (INES-4)
    • Place of Presentation
      Tokyo
    • Related Report
      2013 Annual Research Report
  • [Presentation] Volumetric Heat Storage Capacity in a Packed Bed Reactor of a Magnesium Oxide / Water Chemical Heat Pump2013

    • Author(s)
      M Zamengo, J Ryu, Y Kato
    • Organizer
      International Symposium on Innovative Materials for Processes in Energy Systems 2013 (IMPRES2013)
    • Place of Presentation
      Fukuoka
    • Related Report
      2013 Annual Research Report
  • [Presentation] Magnesium hydroxide pellets for the storage of industrial waste heat2013

    • Author(s)
      M Zamengo, J Ryu, Y Kato
    • Organizer
      Massive Energy Storage for the Broader Use of Renewable Energy Sources
    • Place of Presentation
      Califronia, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Contribution of thermal energy storage technologies on vehicle’s thermal energy storage (VTES)2013

    • Author(s)
      Y Kato
    • Organizer
      Massive Energy Storage for the Broader Use of Renewable Energy Sources
    • Place of Presentation
      Califronia, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] The effects of density Oil Mg(0H)2 - expanded graphite pellets for a chemical heat pump2012

    • Author(s)
      Zamengo Massimiliano, Kim Seon Tae, Ryu Junichi, Kato Yukitaka
    • Organizer
      化学工学会第44回秋季大会
    • Place of Presentation
      仙台
    • Year and Date
      2012-09-19
    • Related Report
      2012 Annual Research Report
  • [Presentation] Magnesium Hydroxide - Expanded Graphite Composite Pellets for a Packed Bed Reactor Chemical Heat Pump2012

    • Author(s)
      Massimiliano Zamengo, Junichi Ryu, Yukitaka Kato,
    • Organizer
      Heat Powered Cycles Conference 2012 (HPC2012)
    • Place of Presentation
      Alkmaar, The Netherlands
    • Year and Date
      2012-09-09
    • Related Report
      2012 Annual Research Report
  • [Presentation] Thermal conductivity enhancement of a packed bed reactor in a magnesium oxide/water chemical heat pump2012

    • Author(s)
      Zamengo Massimiliano.Ryu Junichi, Kato Yukitaka
    • Organizer
      第49回伝熱シンポジウム
    • Place of Presentation
      富山
    • Year and Date
      2012-06-01
    • Related Report
      2012 Annual Research Report
  • [Presentation] Reactivity Enhance of Packed Bed Chemical Material Using Expanded Graphite for Chemical Heat Pump2012

    • Author(s)
      Seon Tae KIM, Junichi RYU, Yukitaka KATO
    • Organizer
      12th International Conference on Energy Storage(Innostock 2012)
    • Place of Presentation
      Lieida, Spain
    • Year and Date
      2012-05-16
    • Related Report
      2012 Annual Research Report
  • [Book] エネルギー科学と地球温暖化2015

    • Author(s)
      加藤之貴 分担
    • Total Pages
      244
    • Publisher
      共立出版
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 熱出力方法および熱出力システム2012

    • Inventor(s)
      加藤之貴、渡邉寛子、山岸哲
    • Industrial Property Rights Holder
      東京ガス(株)、東京工業大学
    • Industrial Property Number
      2012-259171
    • Filing Date
      2012-11-27
    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] 蓄熱方法、蓄熱装置および蓄熱システム2012

    • Inventor(s)
      加藤之貴、渡邉寛子、山岸哲
    • Industrial Property Rights Holder
      東京ガス(株)、東京工業大学
    • Industrial Property Number
      2012-259170
    • Filing Date
      2012-11-27
    • Related Report
      2012 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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