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Molecular mechanisms of wood pyrolysis as composite material

Research Project

Project/Area Number 24380095
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Wood science
Research InstitutionKyoto University

Principal Investigator

Kawamoto Haruo  京都大学, エネルギー科学研究科, 准教授 (80224864)

Co-Investigator(Kenkyū-buntansha) Saka Shiro  京都大学, 大学院エネルギー科学研究科, 教授 (50205697)
Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥12,610,000 (Direct Cost: ¥9,700,000、Indirect Cost: ¥2,910,000)
Keywords木材 / 木質バイオマス / 熱分解 / 分子機構 / 相互作用 / バイオリファイナリー / バイオケミカルス / バイオ燃料 / バイオマス / 木質科学 / セルロース / ヘミセルロース / リグニン
Outline of Final Research Achievements

Better understanding of the molecular mechanisms involved in wood pyrolysis would provide insights into the upgrading of various pyrolysis-based technologies, which include carbonization, gasification and fast pyrolysis. In this project, we studied the molecular mechanisms of wood pyrolysis under the focus of heterogeneity of cellulose and cell wall, which consists of cellulose crystallites surrounded by lignin-hemicellulose matrix. As a result, we clarified the roles of reducing ends in cellulose pyrolysis, radical chain mechanisms in lignin pyrolysis, interactions between lignin and hemicellulose/cellulose, gas-forming mechanisms from cellulose and so on.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (59 results)

All 2016 2015 2014 2013 2012 Other

All Journal Article (17 results) (of which Peer Reviewed: 17 results,  Acknowledgement Compliant: 9 results) Presentation (41 results) (of which Int'l Joint Research: 2 results,  Invited: 5 results) Book (1 results)

  • [Journal Article] Gas-phase reactions of glyceraldehyde and 1,3-dihydroxyacetone as a model for levoglucosan conversion during biomass gasification2016

    • Author(s)
      Asuka Fukutome, Haruo Kawamoto, Shiro Saka
    • Journal Title

      ChemSusChem

      Volume: 9 Issue: 7 Pages: 703-712

    • DOI

      10.1002/cssc.201501612

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Reactivity of cellulose reducing end in pyrolysis as studied by methyl glucoside-impregnation2016

    • Author(s)
      Seiji Matsuoka, Haruo Kawamoto, Shiro Saka
    • Journal Title

      Carbohydate Research

      Volume: 420 Pages: 46-50

    • DOI

      10.1016/j.carres.2015.11.010

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Processes forming gas, tar and coke in cellulose gasification from gas-phase reactions of levoglucosan as intermediate2015

    • Author(s)
      Asuka Fukutome, Haruo Kawamoto, Shiro Saka
    • Journal Title

      ChemSusChem

      Volume: 8 Issue: 13 Pages: 2240-2249

    • DOI

      10.1002/cssc.201500275

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Strong interactions during lignin pyrolysis in wood; A study by in situ probing of the radical chain reactions using model dimers2015

    • Author(s)
      Haruo Kawamoto, Toshihiro Watanabe, Shiro Saka
    • Journal Title

      Journal of Analytical and Applied Pyrolysis

      Volume: 113 Pages: 630-637

    • DOI

      10.1016/j.jaap.2015.04.009

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Pyrolytic reactivities of deuterated beta-ether-type lignin model dimers2015

    • Author(s)
      Toshihiro Watanabe, Haruo Kawamoto, Shiro Saka
    • Journal Title

      Journal of Analytical and Applied Pyrolysis

      Volume: 112 Pages: 23-38

    • DOI

      10.1016/j.jaap.2015.02.028

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Pyrolytic formation of monomers from hardwood lignin as studied from the reactivities of the primary products2015

    • Author(s)
      Takeo Kotake, Haruo Kawamoto, Shiro Saka
    • Journal Title

      Journal of Analytical and Applied Pyrolysis

      Volume: 113 Pages: 57-64

    • DOI

      10.1016/j.jaap.2014.09.029

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] セルロースの熱分解反応と分子機構2015

    • Author(s)
      河本晴雄
    • Journal Title

      木材学会誌

      Volume: 61 Pages: 1-24

    • NAID

      130004775942

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal stabilization and decomposition of simple glycosides in the presence of aromatic substances in closed ampoules: Role of OH・・・π hydrogen bonding2014

    • Author(s)
      Kawamoto, H., Hosoya, T., Ueno, Y., Shoji, T.., Saka S.
    • Journal Title

      J. Anal. Appl. Pyrolysis

      Volume: 109 Pages: 41-46

    • DOI

      10.1016/j.jaap.2014.07.015

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Boiling point of levoglucosan and devolatilization temeratures in cellulose pyrolysis measured at different heating area temperautres2014

    • Author(s)
      Shoji, T., Kawamoto, H., Saka S.
    • Journal Title

      J. Anal. Appl. Pyrolysis

      Volume: 109 Pages: 185-195

    • DOI

      10.1016/j.jaap.2014.06.014

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Gas- and coke-forming reactivities of cellulose-derived tar components under nitrogen and oxygen/nitrogen2014

    • Author(s)
      Fukutome, A., Kawamoto, H.,, Saka S.
    • Journal Title

      J. Anal. Appl. Pyrolysis

      Volume: 108 Pages: 98-108

    • DOI

      10.1016/j.jaap.2014.05.012

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] What is Active Cellulose in Pyrolysis? An Approach based on Reactivity of Cellulose Reducing End2014

    • Author(s)
      Matsuoka, S., Kawamoto, H. and Saka S
    • Journal Title

      J. Anal. Appl. Pyrolysis

      Volume: 106 Pages: 138-146

    • DOI

      10.1016/j.jaap.2014.01.011

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanisms for the Formation of Monomers and Oliglmers During the Pyrolysis of a Softwood Lignin2014

    • Author(s)
      Kotake, T, Kawamoto, H., Saka, S.
    • Journal Title

      J. Anal. Appl. Pyrolysis

      Volume: 105 Pages: 309-316

    • DOI

      10.1016/j.jaap.2013.11.018

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pyrolysis Reactions of Coniferyl Alcohol as a Model of the Primary Structure Formed During Lignin Pyrolysis2013

    • Author(s)
      Kotake, T, Kawamoto, H., Saka, S
    • Journal Title

      J. Anal. Appl. Pyrolysis

      Volume: 104 Pages: 573-584

    • DOI

      10.1016/j.jaap.2013.05.011

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of Hydroxyl Group Configuration on Pyrolytic Formation of 1, 6-Anhydrohexopyranoses From Various Hexoses : An Experimental And Theoretical Study2013

    • Author(s)
      Matsuoka, S., Kawamoto, H., Saka S
    • Journal Title

      J. Anal. Appl. Pyrolysis

      Volume: 103 Pages: 300-306

    • DOI

      10.1016/j.jaap.2012.08.008

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal Reactivities of Non-Reducing Sugars in Polyether -Role of Intermolecular Hydrogen Bondings in Pyrolysis2013

    • Author(s)
      Kawamoto, H., Ueno, Y., Saka S
    • Journal Title

      J. Anal. Appl. Pyrolysis

      Volume: 103 Pages: 287-292

    • DOI

      10.1016/j.jaap.2012.08.009

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Retro-Adel-Type Fragmentation of Reducing Sugars Preferentially Occurring in Polyether at High Temperature : Role of the Ether Oxygen as a Base Catalyst2012

    • Author(s)
      Matsuoka, S., Kawamoto, H. and Saka S.
    • Journal Title

      J. Anal. Appl. Pyrol.

      Volume: 93 Pages: 24-32

    • DOI

      10.1016/j.jaap.2011.09.005

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Effects of Combining Guaiacol and Syringol on their Pyrolysis2012

    • Author(s)
      Asmadi, M., Kawamoto, H., Saka, S.
    • Journal Title

      Holzforschung

      Volume: 66 Pages: 323-330

    • NAID

      120006601453

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Pyrolysis behaviors of hardwood and softwood species and milled wood lignin fractions2016

    • Author(s)
      Mohd Asmadi, Haruo Kawamoto, Shiro Saka
    • Organizer
      第66回日本木材学会大会
    • Place of Presentation
      名古屋大学(愛知県・名古屋市)
    • Year and Date
      2016-03-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] リグニン熱分解における芳香核構造の変換機構 -同位体ラベルによる検討-2015

    • Author(s)
      成田和夫、河本晴雄、坂志朗
    • Organizer
      第60回リグニン討論会
    • Place of Presentation
      筑波大学(茨城県・つくば市)
    • Year and Date
      2015-11-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Radical chain and heterolysis reactions in lignin pyrolysis as studied with model dimers2015

    • Author(s)
      Haruo Kawamoto, Keiko Matsuda, Shiro Saka
    • Organizer
      18th International Symposium on Wood, Fiber and pulping Chemistry 2015 (ISWFPC 2015)
    • Place of Presentation
      ウィーン(オーストリア)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Molecular mechanisms of gaseous levoglucosan as a cellulose gasification intermediate2015

    • Author(s)
      Asuka Fukutome, Haruo Kawamoto, Shiro Saka
    • Organizer
      18th International Symposium on Wood, Fiber and pulping Chemistry 2015 (ISWFPC 2015)
    • Place of Presentation
      ウィーン(オーストリア)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 木質バイオマスの炭素化-熱分解分子機構からの考察-2015

    • Author(s)
      河本晴雄
    • Organizer
      第53回炭素材料夏季セミナー
    • Place of Presentation
      東京ソラマチ(東京都・江東区)
    • Year and Date
      2015-08-10
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] リグニン熱分解におけるラジカル連鎖とヘテロリシス反応機構2015

    • Author(s)
      松田佳子、河本晴雄、坂志朗
    • Organizer
      第24回日本エネルギー学会
    • Place of Presentation
      札幌コンベンションセンター(北海道・札幌市)
    • Year and Date
      2015-08-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] レボグルコサンの気相での熱分解反応機構 -グリセロールとグリセルアルデヒドの反応性の相違からの検討-2015

    • Author(s)
      福留明日香、河本晴雄、坂志朗
    • Organizer
      第24回日本エネルギー学会
    • Place of Presentation
      札幌コンベンションセンター(北海道・札幌市)
    • Year and Date
      2015-08-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] 気相でのレボグルコサンの特異的な熱安定性とその分子機構 -メチルグルコシド類との比較-2015

    • Author(s)
      福留明日香、河本晴雄、坂志朗
    • Organizer
      セルロース学会第22回年次大会
    • Place of Presentation
      北海道大学(北海道・札幌市)
    • Year and Date
      2015-07-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] リグニンモデル化合物の熱分解における側鎖でのヘテロリシス機構2015

    • Author(s)
      松田佳子、河本晴雄、坂 志朗
    • Organizer
      第65回日本木材学会大会
    • Place of Presentation
      東京
    • Year and Date
      2015-03-16 – 2015-03-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] メトキシル基に起因するリグニン熱分解の同位体ラベルによる反応機構の解明2015

    • Author(s)
      成田和央、河本晴雄、坂 志朗
    • Organizer
      第65回日本木材学会大会
    • Place of Presentation
      東京
    • Year and Date
      2015-03-16 – 2015-03-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Primary and secondary reactions of lignin pyrolysis2015

    • Author(s)
      Kawamoto, H., Saka, S.
    • Organizer
      International Symposium on Wood Science and Technology 2015 (IAWPS 2015)
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Gas- and liquid-phase reactions of levoglucosan as a key intermediate of cellulose gasification2015

    • Author(s)
      Fukutome, A., Kawamoto, H., Saka, S.
    • Organizer
      International Symposium on Wood Science and Technology 2015 (IAWPS 2015)
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 熱分解によるリグニンからのケミカルス生産の可能性2014

    • Author(s)
      河本晴雄
    • Organizer
      第53回関西バイオポリマー研究会「バイオマス材料と医療材料(4)」
    • Place of Presentation
      大阪
    • Year and Date
      2014-12-04
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Secondary reactions of volatile intermediates during cellulose and lignin pyrolysis/gasification2014

    • Author(s)
      Kawamoto, H.
    • Organizer
      AIChE Annual Meeting
    • Place of Presentation
      Atlanta, USA
    • Year and Date
      2014-11-16 – 2014-11-21
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 非フェノール性-エーテル型リグニン二量体モデル化合物の熱分解反応機構-側鎖水酸基に起因するレトロアルドール反応-2014

    • Author(s)
      松田佳子、福留 明日香、河本晴雄、坂 志朗
    • Organizer
      第59回リグニン討論会
    • Place of Presentation
      福井
    • Year and Date
      2014-09-11 – 2014-09-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] Mechanisms of monomer and oligomer formation in lignin pyrolysis2014

    • Author(s)
      Kawamoto, H.
    • Organizer
      XXVIIth International Conference on Polyphenols & 8th Tannin Conference (ICP2014)
    • Place of Presentation
      Nagoya, Japan
    • Year and Date
      2014-09-02 – 2014-09-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Hydrogen bonding as a principle mechanism to promote carbohydrate pyrolysis reactions2014

    • Author(s)
      Kawamoto, H., Saka, S.
    • Organizer
      Grand Renewable Energy 2014
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2014-07-27 – 2014-08-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] セルロースガス化の分子機構-中間体としてのガス状レボグルコサンの役割-2014

    • Author(s)
      福留 明日香、河本晴雄、坂 志朗
    • Organizer
      第23回日本エネルギー学会大会
    • Place of Presentation
      福岡
    • Year and Date
      2014-07-19 – 2014-07-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 温度に依存したリグニンの熱分解反応機構2014

    • Author(s)
      河本晴雄、坂 志朗
    • Organizer
      第23回日本エネルギー学会大会
    • Place of Presentation
      福岡
    • Year and Date
      2014-07-19 – 2014-07-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 熱分解におけるセルロースの活性化機構-”Active cellulose”とは? 還元性末端の反応性からのアプローチ2014

    • Author(s)
      松岡聖二、河本晴雄、坂 志朗
    • Organizer
      セルロース学会第21回年次大会
    • Place of Presentation
      鹿児島
    • Year and Date
      2014-07-17 – 2014-07-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Hydrogen bonding as a principle mechanism to promote cellulose and other carbohydrate pyrolysis reactions2014

    • Author(s)
      Kawamoto, H.
    • Organizer
      20th International Symposium on Analytical and Applied Pyrolysis (Pyro 2012)
    • Place of Presentation
      Birmingham, UK
    • Year and Date
      2014-05-19 – 2014-05-23
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] What is active cellulose in pyrolysis? An approach based on reactivity of cellulose reducing end2014

    • Author(s)
      Matsuoka, S., Kawamoto, H., Saka, S.
    • Organizer
      20th International Symposium on Analytical and Applied Pyrolysis (Pyro 2012)
    • Place of Presentation
      Birmingham, UK
    • Year and Date
      2014-05-19 – 2014-05-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Pyrolytic formation of monomers from hardwood lignin as studied from the reactivity of the primary products2014

    • Author(s)
      Kotake, T., Kawamoto, H., Saka, S.
    • Organizer
      20th International Symposium on Analytical and Applied Pyrolysis (Pyro 2012)
    • Place of Presentation
      Birmingham, UK
    • Year and Date
      2014-05-19 – 2014-05-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] 熱分解におけるリグニンの低分子化とそれを阻害する分子機構2014

    • Author(s)
      河本晴雄、小竹毅郎、坂 志朗
    • Organizer
      第64回日本木材学会大会
    • Place of Presentation
      松山
    • Related Report
      2013 Annual Research Report
  • [Presentation] 気相中でのレボグルコサンの熱分解反応機構2014

    • Author(s)
      福留明日香、河本晴雄、坂 志朗
    • Organizer
      第64回日本木材学会大会
    • Place of Presentation
      松山
    • Related Report
      2013 Annual Research Report
  • [Presentation] 加熱速度がセルロース熱分解における分解物の沸騰温度に及ぼす影響2014

    • Author(s)
      庄司妙子、河本晴雄、坂 志朗
    • Organizer
      第64回日本木材学会大会
    • Place of Presentation
      松山
    • Related Report
      2013 Annual Research Report
  • [Presentation] Hydrogen bonding promotes pyrolytic reactions of carbohydrate pyrolysis2013

    • Author(s)
      Kawamoto, H.
    • Organizer
      21st European Biomass Conference & Exhibition.
    • Place of Presentation
      Copenhagen
    • Related Report
      2013 Annual Research Report
  • [Presentation] Molecular mechanisms in pyrolytic formation of monomers/oliglmers from lignin2013

    • Author(s)
      Kawamoto, H., Kotake, T., Saka, S.
    • Organizer
      21st European Biomass Conference & Exhibition.
    • Place of Presentation
      Copenhagen
    • Related Report
      2013 Annual Research Report
  • [Presentation] 側鎖からの水素引抜によるリグニンラジカル連鎖β-エーテル開裂機構の検討2013

    • Author(s)
      松田佳子、河本晴雄、坂 志朗
    • Organizer
      第58回リグニン討論会
    • Place of Presentation
      高松
    • Related Report
      2013 Annual Research Report
  • [Presentation] セルロース熱分解における1,6-無水糖生成機構2013

    • Author(s)
      河本晴雄、松岡聖二、坂 志朗
    • Organizer
      セルロース学会第20回年次大会
    • Place of Presentation
      宇治
    • Related Report
      2013 Annual Research Report
  • [Presentation] セルロース系バイオマスのガス化中間体としてのレボグルコサンの気相中での熱分解反応機構2013

    • Author(s)
      福留 明日香、河本晴雄、坂 志朗
    • Organizer
      セルロース学会第20回年次大会
    • Place of Presentation
      宇治
    • Related Report
      2013 Annual Research Report
  • [Presentation] リグニンの熱分解ラジカル連鎖β-エーテル開裂機構の解明-Cβ水素引き抜きによる経路-2013

    • Author(s)
      松田佳子、河本晴雄、坂 志朗
    • Organizer
      第63回日本木材学会大会
    • Place of Presentation
      盛岡
    • Related Report
      2012 Annual Research Report
  • [Presentation] セルロース系バイオマスのガス化中間体としてのレボグルコサンの気相での熱分解反応特性2013

    • Author(s)
      福留 明日香、河本晴雄、坂 志朗
    • Organizer
      第63回日本木材学会大会
    • Place of Presentation
      盛岡
    • Related Report
      2012 Annual Research Report
  • [Presentation] Aromatic substance and polyether as media for controlled pyrolysis for chemical production from carbohydrates2012

    • Author(s)
      Kawamoto, H., Saka, S.
    • Organizer
      3rd International Cellulose Conference (ICC2012)
    • Place of Presentation
      札幌
    • Related Report
      2012 Annual Research Report
  • [Presentation] Molecular-based study of gas and coke formation in gasification of cellulosic biomass2012

    • Author(s)
      Fukutome, A., Kawamoto, H., Saka, S.
    • Organizer
      3rd International Cellulose Conference (ICC2012)
    • Place of Presentation
      札幌
    • Related Report
      2012 Annual Research Report
  • [Presentation] Thermal reactivities of reducing and non-reducing sugars in polyether : role f inter-and intra-molecular hydrogen bondings in pyrolysis2012

    • Author(s)
      Kawamoto, H., Ueno, Y., Saka, S.
    • Organizer
      19th International Symposium on Analytical and Applied Pyrolysis (Pyrolysis 2012)
    • Place of Presentation
      リンツ、オーストリア
    • Related Report
      2012 Annual Research Report
  • [Presentation] Influence of hydroxl group configuration on pyrolytic formation of 1,6-anhydrohexoses from various hexoses : and experimental and theoretical study2012

    • Author(s)
      Matsuoka, S., Kawamoto, H., Saka, S.
    • Organizer
      19th International Symposium on Analytical and Applied Pyrolysis (Pyrolysis 2012)
    • Place of Presentation
      リンツ、オーストリア
    • Related Report
      2012 Annual Research Report
  • [Presentation] 芳香族吾郷物中での非還元糖の熱安定化とその機構2012

    • Author(s)
      河本晴雄、細谷隆史、上野貴臣、坂 志朗
    • Organizer
      セルロース学会第19回年次大会
    • Place of Presentation
      名古屋
    • Related Report
      2012 Annual Research Report
  • [Presentation] 糖の熱分解機構 : 気相でなぜ安定化するのか2012

    • Author(s)
      河本晴雄、坂 志朗
    • Organizer
      第21回日本エネルギー学会大会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 広葉樹リグニン熱分解における低分子シリンゴール類/グアイアコール類の生成挙動2012

    • Author(s)
      小竹毅郎、河本晴雄、坂 志朗
    • Organizer
      第57回リグニン討論会
    • Place of Presentation
      福岡
    • Related Report
      2012 Annual Research Report
  • [Presentation] リグニン熱分解における低分子化とそれを阻害する分子機構

    • Author(s)
      河本晴雄
    • Organizer
      第254回生存圏シンポジウム(第4回生存圏熱帯林人工林フラッグシップシンポジウム)
    • Place of Presentation
      京都
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] 第4章 5リグニンの熱分解による化学物質 in 「リグニン利用の最動向」2013

    • Author(s)
      河本晴雄
    • Total Pages
      8
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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