Development of experiments in chemical education from the view point of human life : Detection and recognition of esters in various products
| Project/Area Number |
24501109
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Science education
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| Research Institution | Tokyo University of Science |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
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| Keywords | エステル / ヒドロキサム酸法 / 陽イオン界面活性剤 / プラスチック / 繊維 / 構造異性体 / エステルの検出 / ヒドロキサム酸鉄（III）法 |
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| Outline of Final Research Achievements |
Esters of carboxylic acids are widely used compounds around our life. In our laboratory, the experiment detecting esters in various products around us has been developed as teaching materials. To detect esters utilizing coloring reaction, we used the hydroxamic acid method. In the conventional method, high concentration of sodium hydroxide solution and organic solvent like ethanol must be used to detect hydrophobic esters. We have investigated the improved safe method of hydroxamic acid method to perform all reactions in aqueous media. We found that certain cationic surfactants are able to promote the reaction between esters and hydroxyl amine, in basic aqueous solution. Utilizing this system, we’ve developed the experiments to detect esters in perfumes, plastics and fibers. Furthermore we have developed the experiment identifying plant oils with different average molecular weight, and structural isomers of esters.
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Report
(4 results)
Research Products
(10 results)
