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Novel Development of Solid-Liquid Interfacial Reaction - from Adsorption to Sorption -

Research Project

Project/Area Number 24510019
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental dynamic analysis
Research InstitutionJapan Women's University

Principal Investigator

MIYAZAKI Akane  日本女子大学, 理学部, 教授 (80293067)

Co-Investigator(Renkei-kenkyūsha) YOKOYAMA Takushi  九州大学, 大学院理学研究院, 教授 (20136419)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Keywords吸着 / 収着 / 27Al MAS NMR / 113Cd MAS NMR / アルミナ / 表面錯形成 / フェリハイドライト / モリブデン酸イオン / 脱着 / 固液界面反応
Outline of Final Research Achievements

Adsorption of heavy metals onto oxide solids is a crucial process in many fields, such as water treatment, preparation of catalysts. The solid-liquid interfacial phenomena have been explained as surface complex formation between heavy metal ions and surface –OH groups on the solids. However, we found that adsorption can be transformed to sorption, which is assimilating heavy metal ions into the solid’s structure. In this study, we characterized sorption products and revealed the transformation process from adsorption to sorption.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (19 results)

All 2015 2014 2013 2012

All Journal Article (11 results) (of which Peer Reviewed: 9 results) Presentation (7 results) Book (1 results)

  • [Journal Article] Impact of particle size and metal-support interaction on denitration behavior of well-defined Pt-Cu nanoparticles2015

    • Author(s)
      Akane MIYAZAKI, Kaori MATSUDA, Florica Papa, Mariana scurtu, Catalin Negrila, Gianina Dobrescu, Ioan Balint
    • Journal Title

      Catalysis Science & Technology

      Volume: 5 Pages: 492-503

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 都市近郊の小規模森林樹冠に対する微量金属元素の沈着挙動2014

    • Author(s)
      吉田円香、宮崎あかね、緒方裕子
    • Journal Title

      大気環境学会誌

      Volume: 49 Pages: 53-58

    • NAID

      130004554466

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Concentration and particle size distribution of polycyclic aromatic hydrocarbons formed by thermal cooking2014

    • Author(s)
      Erina SAITO, Nobuyuki TANAKA, Akane MIYAZAKI, Masaharu TSUZAKI
    • Journal Title

      Food Chemistry

      Volume: 153 Pages: 285-291

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Impact of particle size and metal-support interaction on denitration behavior of well-defined Pt-Cu nanoparticles2014

    • Author(s)
      Florica Papa, Akane MIYAZAKI, Mariana Scurtu, Adelina C. Ianculescu, Ioan Balint
    • Journal Title

      Catalysis Science & Technology

      Volume: 16

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A study on the interaction between ferric ion and silicic acid in hydrosphere: Ferruginous deposits containing Si formed in natural hot spring waters2013

    • Author(s)
      Gaowa NAREN, Akane MIYAZAKI, Motoyuki MATSUO, Shiqin BAI, Kotaro YONESU, Yoshihiro OKAUE, Takushi YOKOYAMA
    • Journal Title

      Chinese Journal of Geochemistry,

      Volume: 32 Pages: 27-34

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Evidence for the AlO4 tetrahedral structure formation induced by Zn2+ adsorption onto Al(OH)3 gel2013

    • Author(s)
      Akane MIYAZAKI, Mayumi NUMATA, Mayumi Etou, Kotaro YONEZU, Ioan BALINT, Takushi YOKOYAMA
    • Journal Title

      Colloids and Surfaces A: Physicochemical and Engineering Aspects

      Volume: 420 Pages: 115-121

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Relevance of MO-Sm2O3 (M=Zn, Mg, Ca, Sr) mixed oxides basicity on the efficiency of methane conversion to C2+ hydrocarbons2012

    • Author(s)
      Ioan Balint, Akane Miyazaki, Dana Gingasu, Florica Papa
    • Journal Title

      Reaction Kinetics, Mechanisms and Catalysis

      Volume: 105 Pages: 5-11

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] 食品の加熱調理により排出されるオイルミスト中の多環芳香族炭化水素の分析2012

    • Author(s)
      田中伸幸、大竹加耶子、津崎昌東、宮崎あかね
    • Journal Title

      分析化学

      Volume: 61 Pages: 77-86

    • NAID

      10030134985

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] 魚の焼き調理により排出される多環芳香族炭化水素の粒径分布2012

    • Author(s)
      田中伸幸、赤井依美、津崎昌東、宮崎あかね
    • Journal Title

      分析化学

      Volume: 61 Pages: 901-910

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] 調理排気中の多環芳香族炭化水素(PAHs)の測定から-素材による汚染濃度の違い―2012

    • Author(s)
      宮崎あかね、田中伸幸
    • Journal Title

      日本調理科学会誌

      Volume: 45 Pages: 1-2

    • NAID

      110009562889

    • Related Report
      2012 Research-status Report
  • [Journal Article] 化学にもっとたくさんの女子学生を2012

    • Author(s)
      宮崎あかね
    • Journal Title

      化学と教育

      Volume: 160 Pages: 491-491

    • Related Report
      2012 Research-status Report
  • [Presentation] Observation of dry deposition of acidic substances onto the forest canopy in a small conifer/deciduous mixed forest in Greater Tokyo using foliar rising and surrogate surface method2014

    • Author(s)
      Yuya SUGIURA, Hiroshi OKOCHI, Hiroko OGATA, Kazuhide MATSUDA, Akane MIYAZAKI
    • Organizer
      International Conference of Asian Environmental Chemistry 2014
    • Place of Presentation
      Bangkok, Thailand
    • Year and Date
      2014-11-24 – 2014-11-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effect of CO2 on MoO42- adsorption on ferrihydrite.2014

    • Author(s)
      Akane MIYAZAKI, Hiroshi OHMOTO
    • Organizer
      Goldshmidt2014
    • Place of Presentation
      Sacramento, USA
    • Year and Date
      2014-06-08 – 2014-06-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effect of CO2 on MoO42- adsorption on ferrihydrite2014

    • Author(s)
      Akane MIYAZAKI, Hiroshi OHMOTO
    • Organizer
      Goldschmidt Conference
    • Place of Presentation
      Sacramento, USA
    • Related Report
      2013 Research-status Report
  • [Presentation] アーバスキュラー菌根菌とミミズの共存による牧草の生育への共同効果2012

    • Author(s)
      小島知子、宮崎あかね
    • Organizer
      日本土壌微生物学会2012年度大会
    • Place of Presentation
      神戸、神戸大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 里山の生態系サービスと窒素飽和現象(2)2012

    • Author(s)
      江口裕之、大河内博、緒方祐子、宮崎あかね
    • Organizer
      第53回大気環境学会
    • Place of Presentation
      横浜、神奈川大学
    • Related Report
      2012 Research-status Report
  • [Presentation] ケイ酸および亜鉛イオンの水酸化アルミニウムに対する吸着挙動2012

    • Author(s)
      宮崎あかね、沼田麻由美、江藤真由美、横山拓史
    • Organizer
      2012年度日本地球化学会年会
    • Place of Presentation
      福岡、九州大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Local structure of Al in Al-Zn hydroxide coprecipitation2012

    • Author(s)
      Akane MIYAZAKI, Mayumi ETOU, Kotaro YONEZU, Ioan BALINT, Takushi YOKOYAMA
    • Organizer
      Goldschmidt Conference
    • Place of Presentation
      Montreal, Canada
    • Related Report
      2012 Research-status Report
  • [Book] Dekker Encyclopedia of Nanoscience and Nanotechnology (3rd Edition)2014

    • Author(s)
      Ioan BALINT, Akane MIYAZAKI
    • Publisher
      Marcel Dekker, New York
    • Related Report
      2014 Annual Research Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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