Development of Catalytic Hydrogen Transfer Process for Chemical Recycling of Waste Plastics
Project/Area Number |
24510090
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Environmental technology/Environmental materials
|
Research Institution | Muroran Institute of Technology |
Principal Investigator |
UEMICHI Yoshio 室蘭工業大学, 工学(系)研究科(研究院), 教授 (90168659)
|
Co-Investigator(Kenkyū-buntansha) |
KANDA Yasuharu 室蘭工業大学, 工学研究科, 助教 (70447085)
|
Project Period (FY) |
2012-04-01 – 2015-03-31
|
Project Status |
Completed (Fiscal Year 2014)
|
Budget Amount *help |
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
|
Keywords | 廃プラスチック / ケミカルリサイクル / ポリプロピレン / ポリスチレン / 水素移行 / 芳香族炭化水素 / ガリウムゼオライト / 亜鉛ゼオライト / プラスチック / リサイクル / 接触分解 / コーキング / 触媒 / 化学原料 |
Outline of Final Research Achievements |
Catalytic degradation of polystyrene/polypropylene mixtures has been carried out using gallium supported H-ZSM-5 zeolite catalyst. It has been found that the gallium catalyst is highly active for producing aromatic hydrocarbons in the degradation of the mixtures and the hydrogen atoms generated from the aromatization of polypropylene-decomposed fragments suppress the coking of polystyrene. The hydrogen transfer degradation thus developed is effective to establish a chemical recycling process in which waste hydrocarbon plastics are selectively converted into useful aromatic hydrocarbons. Furthermore, Zn/H-ZSM-5 also shows a high catalytic activity for the degradation of the plastics.
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Report
(4 results)
Research Products
(17 results)