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Synthesis and structure control of yolk-shell inorganic nanoparticles by templating polymeric micelles

Research Project

Project/Area Number 24510139
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanostructural science
Research InstitutionSaga University

Principal Investigator

NAKASHIMA KENICHI  佐賀大学, 工学(系)研究科(研究院), 教授 (10104720)

Co-Investigator(Kenkyū-buntansha) WATARI TAKANORI  佐賀大学, 大学院工学系研究科, 教授 (10136541)
Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords卵黄-卵殻型ナノ粒子 / 高分子ミセル / 鋳型合成 / ゾル-ゲル反応 / 金ナノ粒子 / 銀ナノ粒子 / シリカ / コア-シェル-コロナ構造 / 金 / 銀
Outline of Final Research Achievements

We have synthesized gold-silica (and silver-silica) yolk-shell nanoparticles. The synthesis is based on a novel technique which is developed from our earlier method for silica hollow nanoparticles (J. Am. Chem. Soc. 2007, 129, 1534). We have succeeded in obtaining gold-silica (and silver-silica) yolk-shell nanoparticles. However, the yields of the yolk-shell nanoparticles are low for both gold-silica and silver-silica cases. We have tried to increase the yields by several modifications such as changing a template polymer. However, the yields have not been improved significantly. It seems necessary to increase the amount of the adsorbed template polymers on the core (yolk) nanoparticles to increase the yields of the yolk-shell nanoparticles.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (26 results)

All 2016 2015 2014 2013 2012 Other

All Int'l Joint Research (2 results) Journal Article (11 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 11 results,  Acknowledgement Compliant: 7 results) Presentation (9 results) (of which Int'l Joint Research: 3 results,  Invited: 5 results) Remarks (4 results)

  • [Int'l Joint Research] ガジャマダ大学(インドネシア)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] ダゴン大学(ミャンマー)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Fluorescence ON-OFF switching using micelle of stimuli-responsive double hydrophilic block copolymers: NileRed fluorescence in micelles of poly(acrylicacid-b-N-isopropylacrylamide)2016

    • Author(s)
      Min Min Yee, Miyabi Tsubone, Takuya Morita, Shin-ichi Yusa and Kenichi Nakashima
    • Journal Title

      Journal of Luminescence

      Volume: 76 Pages: 318-323

    • DOI

      10.1016/j.jlumin.2016.02.043

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Synthesis of zinc borate hollow nanosphere using polymeric micelles with core-corona architecture as a template2015

    • Author(s)
      Mohammad Mydul Alam, Kimiko Hashimoto, Chihiro Yamaguchi, Shin-ichi Yusa, Kenichi Nakashima
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 88 Issue: 1 Pages: 124-126

    • DOI

      10.1246/bcsj.20140238

    • NAID

      130004690775

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Cobalt oxide hollow nanoparticles as synthesized by templating tri-block copolymer micelle with core-shell-corona structure: a promising anode material for lithium ion batteries2015

    • Author(s)
      Nhut Minh Dang, Wen-Wen Zhao, Shinichi Yusa, Hideyuki Noguchi, Kenichi Nakashima
    • Journal Title

      New Journal of Chemistry

      Volume: 39 Issue: 6 Pages: 4726-4730

    • DOI

      10.1039/c5nj00058k

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Sol-gel preparation of photoactive srilankite-type zirconium titanate hollow spheres by templating sulfonated polystyrene latex particles2015

    • Author(s)
      Akhmad Syoufian, Yukitaka Manako, and Kenichi Nakashima
    • Journal Title

      Powder Technology

      Volume: 280 Pages: 207-210

    • DOI

      10.1016/j.powtec.2015.04.059

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of Hollow Silica Nanosphere with High Accessible Surface Area and Their Hybridization with Carbon Matrix for Drastic Enhancement of Electrochemical Property2014

    • Author(s)
      Mohammad Mydul Alam, Haruki Yamahana, Bishnu Prasad Bastakoti, Hom Nath Luitel, Wenwen Zhao,Yusuke Yamauchi, Takanori Watari, Hideyuki Noguchi, Kenichi Nakashima
    • Journal Title

      Applied Surface Science

      Volume: 314 Pages: 552-557

    • DOI

      10.1016/j.apsusc.2014.07.030

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fabrication of copper oxide hollow nanosphere using ABC block copolymer templates and its application as anode materials in lithium ion batteries2014

    • Author(s)
      Mohammad Alam, Wenwen Zhao, Shin-ichi Yusa, Kenichi Nakashima, Shuo Zhai,and Noguchi, Hideyuki
    • Journal Title

      Chemistry Letters

      Volume: 43 Issue: 9 Pages: 1426-1428

    • DOI

      10.1246/cl.140418

    • NAID

      130004427165

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Template free synthesis of dendritic silver nanostrustures and their supplication in surface-enhanced Raman scattering2014

    • Author(s)
      Mohammad MydulAlam, Wei Ji, HomNathLuitel, Yukihiro Ozaki, TakanoriWatari and Kenichi Nakashima
    • Journal Title

      RSC Advances

      Volume: 4 Issue: 95 Pages: 52686-52689

    • DOI

      10.1039/c4ra10113h

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] CoreShellCorona Polymeric Micelles as a Versatile Template for Synthesis of Inorganic Hollow Nanospheres2014

    • Author(s)
      Manickam Sasidharan and Kenichi Nakashima
    • Journal Title

      Acc. Che. Res.

      Volume: 47 Issue: 1 Pages: 157-167

    • DOI

      10.1021/ar4001026

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Multifunctional Core-Shell-Corona-Type Polymeric Micelles for Anticancer Drug-Delivery and Imaging2013

    • Author(s)
      Bishnu Prasad Bastakoti. Kevin C-W. Wu, Masamichi Inoue, Shin-ichi Yusa, Kenichi Nakashima, and Yusuke Yamauchi
    • Journal Title

      Chemistry-A European Journal

      Volume: 19 Issue: 15 Pages: 4812-4817

    • DOI

      10.1002/chem.201203958

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Nanometer-sized Hollow Calcium Tungstate Particles by Using Micelles of Poly(styrene-b-acrylic acid-b-ethylene oxide) as a Soft Template2013

    • Author(s)
      Shuo Zhai, Yukitaka Manako, Shin-ichi Yusa, and Kenichi Nakashima
    • Journal Title

      Chemistry Letters

      Volume: 42

    • NAID

      10031183277

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Hollow Zinc Oxide Nanoparticles by Templating Micelles of Poly(styrene-b-acrylic acid-b-ethylene oxide) in Aqueous Solutions2013

    • Author(s)
      Shuo Zhai, Shin-ichi Yusa, and Kenichi Nakashima
    • Journal Title

      Bulletin of The Chemical Society of Japan

      Volume: 86

    • NAID

      10031183254

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Luminescent Hollow Nanoparticles: Synthesis and Properties2016

    • Author(s)
      Kenichi Nakashima, Yukitaka Manako, and Taufik A. Natsir
    • Organizer
      RACI Physical Chemistry 2016 Meeting
    • Place of Presentation
      Christchurch, New Zealand
    • Year and Date
      2016-02-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Novel Approach to Synthesize Hollow and Yolk-Shell Nanoparticles – Use of Polymeric Micelle Templates2015

    • Author(s)
      Kenichi Nakashima
    • Organizer
      6th Asian Conference on Colloid and Interface Science
    • Place of Presentation
      Sasebo, Japan
    • Year and Date
      2015-11-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fluorescence ON-OFF Switching of Nile Red by Using Stimuli-Responsive Polymeric Micelle of Poly(Acrylic Acid-b-N-Isopropyl Acryl Amide)2015

    • Author(s)
      Kenichi Nakashima, Min Min Yee, Miyabi Tsubone, Takuya Morita, and Shin-ichi Yusa
    • Organizer
      14th Conference on Methods and Applications of Fluorescence
    • Place of Presentation
      Wurzburg, Germany
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Inorganic hollow nanoparticles: Synthesis and their applications2014

    • Author(s)
      Kenichi Nakashima
    • Organizer
      International Conference ICAMN-2014
    • Place of Presentation
      Kathmandu, Nepal
    • Year and Date
      2014-11-04 – 2014-11-06
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] A Novel Technique to Synthesize Hollow Inorganic Nanoparticles - Use of Polymeric Micelle Template with Core-Shell-Corona Architecture2014

    • Author(s)
      Kenichi Nakashima
    • Organizer
      The 15th IUMRS-International Conference in Asia
    • Place of Presentation
      Fukuoka, Japan
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Synthesis of Hollow Magnetite Nanosparticles Directed by a Smart Temple of Polymeric Micelle with Core-Shell-Corona Structure2014

    • Author(s)
      Kenichi Nakashima, Manickam Sasidharan, Masamichi Inoue, Shin-Ichi Yusa
    • Organizer
      Japan-Taiwan Joint Workshop on Nanospace Materials
    • Place of Presentation
      Fukuoka, Japan
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Core-Shell-Corona Polymeric Micelles as a Smart Template for the Synthesis of Inorganic Hollow Nanoparticles2013

    • Author(s)
      Kenichi Nakashima
    • Organizer
      21st Joint Seminar of KB-CSJ and BB-KCS
    • Place of Presentation
      Busan, Korea
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Core-Shell-Corona Polymeric Micelles as a Versatile Template for the Synthesis of Inorganic Hollow Nanoparticles: Application to Mesoporous Hollow Silica Nanospheres2012

    • Author(s)
      Kenichi Nakashima, Manickam Sasidharan, Haruna Zenibana, Mahasweta Nandi, Asim Bhaumik
    • Organizer
      World Congress on Oleo Science
    • Place of Presentation
      Sasebo, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Quadruple Stimuli-responsiveness of Aqueous Polymeric Micelles of Poly[N-isopropylacrylamide-b-sodium-2-(acrylamido)-2-methylpropanesulfonate] with Spiropyran Dimer Pendant2012

    • Author(s)
      Kenichi Nakashima, Sudhina Guragain, Bishnu P. Bastakoti, and Shin-ichi Yusa
    • Organizer
      8th International Symposium on Stimuli-Responsive Materials
    • Place of Presentation
      Sonoma, CA, USA
    • Related Report
      2012 Research-status Report
    • Invited
  • [Remarks] 中島謙一研究室

    • URL

      http://extwww.cc.saga-u.ac.jp/~nakashik/index.html

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
  • [Remarks] Professor Kenichi Nakashima’s Research Group

    • URL

      http://extwww.cc.saga-u.ac.jp/~nakashik/nakashimaHP_E.html

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
  • [Remarks] 中島謙一研究室

    • URL

      http://extwww.cc.saga-u.ac.jp/~nakashik/index.html

    • Related Report
      2013 Research-status Report
  • [Remarks] 中島謙一研究室ホームページ

    • URL

      http://extwww.cc.saga-u.ac.jp/~nakashik/index.html

    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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