Construction of a multimetallic complex within a cyclic porphyrin nanoring
| Project/Area Number |
24510140
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Nanostructural science
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| Research Institution | Tokyo University of Science |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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| Keywords | 多核錯体 / ポルフィリン / マクロサイクル / 大環状化合物 / ビピリジン / ナノポア / ホストゲスト化学 / ナノリング / ホストゲスト / ホモカップリング / 触媒 / 錯体 |
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| Outline of Final Research Achievements |
One-step synthesis of a macrocyclic porphyrin trimer having three metal liands was achieved by coupling reaction of bis(chloropyridyl)porphyrinatozinc compounds. A target trimer was efficiently isolated by modified silica-gel column chromatography from a mixture including acyclic and cyclic porphyrin oligomers. Introduction of palladium complexes into a macrocyclic porphyrin trimer gave a trispalladium complex of the macrocyclic porphyrin trimer. Replacement of zinc ions on the porphyrin parts into ferric ions was also succeeded. Such multimetallic complex is expected as one of unique catalysts.
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Report
(4 results)
Research Products
(30 results)
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[Journal Article] 1) Self-assembled dimerization of bis(crown ether)-2,2’-bibenzimidazoles2014
Author(s)
Akiharu Satake, Kazuo Tanaka, Hiroki Asakura, Masahiro Okano, Tsutsumu Hashimoto, You Matsuura, Yusuke Inaba, Tetsuhisa Oda, Shun Hirota, Hiroyuki Koshino
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Journal Title
Bull. Chem. Soc. Jpn.
Volume: 87
Issue: 1
Pages: 88-97
DOI
NAID
Related Report
Peer Reviewed
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