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Chemical and mechanical modification of nano/micro-structures at surfaces of ionic crystals

Research Project

Project/Area Number 24510144
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanostructural science
Research InstitutionChuo University

Principal Investigator

Shindo Hitoshi  中央大学, 理工学部, 教授 (90245986)

Co-Investigator(Kenkyū-buntansha) NIKI KAORI  千葉大学, 大学院融合科学研究科, 助教 (10548100)
IMURA KURARA  中央大学, 理工学部, 助教 (60707107)
Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2015: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords摩擦・磨耗 / 結晶力学 / 結晶表面 / 結晶形態 / 原子間力顕微鏡 / 界面活性剤 / 塑性変形 / 分子集合体 / ナノトライボロジー / 結晶形態形成 / ナノ粒子の分散・捕集 / 摩擦・摩耗 / MgO / 結晶のモルフォロジー / TiO2 / キラルな結晶面 / 岩塩型結晶 / カルサイト
Outline of Final Research Achievements

In order to understand the mechanism of friction through atomic to micrometer scales, various single crystal surfaces were scrathced with a saphire stylus in different directions. Observation of wear patterns formed using optical and atomic force microscopies revealed the mechanisms of activation of plastic deformation modes including slip, cleavage and twinning, depending upon the direction and the strength of applied load, and the location relative to the position of the stylus.
To understand why crystals grow in different polyhedral forms depending upon environments, stabilities of crystal faces were compared by observing micro-sized etch pits formed in dissolution experiments. Crystal shapes of nano- and micro-crystals were controlled by the addition of functional molecules which adsorb selectively upon specific crystal faces.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (36 results)

All 2016 2015 2014 2013 Other

All Journal Article (5 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 2 results) Presentation (27 results) (of which Int'l Joint Research: 2 results,  Invited: 3 results) Book (2 results) Remarks (2 results)

  • [Journal Article] pH-Induced recovery and re-dispersion of shape-controlled gold nanorods for nanocatalysis2015

    • Author(s)
      Clara Morita-Imura, Yoshiro Imura, Takeshi Kawai, Hitoshi Shindo
    • Journal Title

      RSC Advances

      Volume: 5 Issue: 93 Pages: 75889-75894

    • DOI

      10.1039/c5ra17369h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 結晶・高分子表面の構造・物性を原子・分子レベルで調べる2015

    • Author(s)
      新藤 斎
    • Journal Title

      分離技術

      Volume: 45 Pages: 56-61

    • Related Report
      2014 Research-status Report
    • Acknowledgement Compliant
  • [Journal Article] Recovery and redispersion of gold nanopartieles using the self-assembly of a pH sensitive zwitterionic amphiphile2014

    • Author(s)
      Clara Morita-Imura, Yoshiro Imura, Takeshi Kawai, Hitoshi Shindo
    • Journal Title

      Chemical Communications

      Volume: 50 Issue: 85 Pages: 12933-12936

    • DOI

      10.1039/c4cc04935g

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Asymmetric Autocatalysis Induced by Cinnabar: Observation of the Enantioselective Adsorption of a 5-Pyrimidyl Alkanol on the Crystal Surface2013

    • Author(s)
      Hitoshi Shindo, Yusuke Shirota, Kaori Niki, Tsuneomi Kawasaki, Kenta Suzuki, Yuko Araki, Arimasa Matsumoto, Kenso Soai
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 52 Issue: 35 Pages: 9135-9138

    • DOI

      10.1002/anie.201304284

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 硬石膏(CaSO4)結晶の形態形成について2013

    • Author(s)
      新藤 斎
    • Journal Title

      硫酸と工業

      Volume: 66 Pages: 127-134

    • Related Report
      2013 Research-status Report
  • [Presentation] 界面活性剤存在下でのマイクロ金結晶の溶解と再成長による異方形態制御2016

    • Author(s)
      秋元良裕、伊村くらら、新藤 斎
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      京田辺
    • Year and Date
      2016-03-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ca2+,Mg2+への配位がもたらすpH応答性界面活性剤の高次分子集合形態の制御2016

    • Author(s)
      村山千明、座間克也、伊村くらら、新藤 斎
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      京田辺
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 刺激応答性長鎖アミン誘導体のラメラ構造を用いた金ナノロッドの回収と再分散2016

    • Author(s)
      小林孝博、伊村くらら、新藤 斎
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      京田辺
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] マイクロ金プレート結晶の溶解と再成長による金ロッド結晶の形成2015

    • Author(s)
      秋元良裕、伊村くらら、新藤 斎
    • Organizer
      2015年真空・表面科学合同講演会
    • Place of Presentation
      つくば
    • Year and Date
      2015-12-02
    • Related Report
      2015 Annual Research Report
  • [Presentation] Recovery and redispersion of noble-metal nanomaterials using stimuli-responsive supramolecules of zwitterionic amphiphiles2015

    • Author(s)
      Clara Imura, Katsuya Zama, Takahiro Kobayashi, Yoshiro Imura, Takeshi Kawai, Hitoshi Shindo
    • Organizer
      6th Asian Conference on Colloid and Interface Science
    • Place of Presentation
      長崎
    • Year and Date
      2015-11-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] プレート状構造からロッド状構造へのマイクロ金結晶の形態変化2015

    • Author(s)
      秋元良裕、伊村くらら、新藤 斎
    • Organizer
      2015年度色材研究発表会
    • Place of Presentation
      習志野
    • Year and Date
      2015-10-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] Micro-scale friction and wear at orthorhombic single crystal surfaces of sulfate minerals2015

    • Author(s)
      H. Shindo, T. Sasaki, T. Hosono, M. Moriya, C. Morita-Imura, K. Niki
    • Organizer
      International Tribology Conference, Tokyo 2015
    • Place of Presentation
      東京
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 刺激応答性界面活性剤との複合化による貴金属ナノ結晶の分離回収制御2015

    • Author(s)
      伊村くらら、波多野萌、座間克也、小林孝博、新藤 斎
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島
    • Year and Date
      2015-09-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] pH変化による分子集合体転移を用いた有機色素の可溶化と分離回収機能の発現2015

    • Author(s)
      座間克也、伊村くらら、新藤 斎
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島
    • Year and Date
      2015-09-10
    • Related Report
      2015 Annual Research Report
  • [Presentation] 刺激応答性を有する長鎖アミン誘導体を用いた金ナノ結晶の回収と再分散2014

    • Author(s)
      小林孝博、伊村くらら、新藤 斎
    • Organizer
      2014年度色材研究発表会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-10-23
    • Related Report
      2014 Research-status Report
  • [Presentation] pHによる長鎖アミン誘導体を用いた有機-無機色材物質の可溶化と分離回収2014

    • Author(s)
      座間克也、伊村くらら、新藤 斎
    • Organizer
      2014年度色材研究発表会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-10-23
    • Related Report
      2014 Research-status Report
  • [Presentation] pH-responsive transition of self-assembled structure for single surfactant system of zwitterionic amphiphile2014

    • Author(s)
      Clara Imura, Moe Hatano, Yoshiro Imura, Takeshi Kawai, Hitoshi Shindo
    • Organizer
      1st Asian Conference on Oleo Science
    • Place of Presentation
      札幌
    • Year and Date
      2014-09-08 – 2014-09-09
    • Related Report
      2014 Research-status Report
  • [Presentation] 長鎖アミン誘導体による多重刺激応答性材料の創製2014

    • Author(s)
      伊村くらら
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2014-09-05
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 長鎖アミン誘導体による銀ナノ粒子の回収と再分散2014

    • Author(s)
      座間克也、伊村くらら、新藤 斎
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2014-09-03
    • Related Report
      2014 Research-status Report
  • [Presentation] 刺激応答性の長鎖アミン誘導体を用いた金ナノロッドの回収と再分散2014

    • Author(s)
      小林孝博、伊村くらら、新藤 斎
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2014-09-03
    • Related Report
      2014 Research-status Report
  • [Presentation] BaSO4(001)表面での摩擦と摩耗に関する研究2013

    • Author(s)
      佐々木達也、森谷大樹、新藤 斎
    • Organizer
      トライボロジー会議2013春 東京シンポジウム
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
  • [Presentation] Stabilities of crystal faces of calcite compared by AFM observation of facet formation processes during dissolution in dilute aqueous acetic acid2013

    • Author(s)
      Hitoshi Shindo, Yohei Ohtsu, Ryohei Yamamura, Tamon Kose, Kaori Niki
    • Organizer
      17th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      Warsaw, Poland
    • Related Report
      2013 Research-status Report
  • [Presentation] Structures of chiral crystal faces inducing autocatalytic chiral amplifying reaction of 2-substituted pyrimidyne-5-carbaldehyde2013

    • Author(s)
      Takashi Fujioka, Tsuyoshi Takeshita, Yusuke Shirota, Hitoshi Shindo, Kaori Niki
    • Organizer
      17th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      Warsaw, Poland
    • Related Report
      2013 Research-status Report
  • [Presentation] Relative stabilities of crystal faces of anatase compared by AFM observation of micro-etch pits formed in highly oxidative environment2013

    • Author(s)
      Yohei Ohkawa, Shun-ichiro saito, Hitoshi Shindo
    • Organizer
      17th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      Warsaw, Poland
    • Related Report
      2013 Research-status Report
  • [Presentation] Effects of slip and twinning deformation systems upon friction and wear at single crystal faces of calcite(CaCO3)2013

    • Author(s)
      Hitoshi Shindo, Mai Kobayashi, Kaori Niki
    • Organizer
      World Tribology Congress 2013
    • Place of Presentation
      Torino, Italy
    • Related Report
      2013 Research-status Report
  • [Presentation] Effects of slip systems upon friction and wear at (001) faces of rock salt-type single crystals2013

    • Author(s)
      Erika Kasahara, Kaori Niki, Hitoshi Shindo
    • Organizer
      World Tribology Congress 2013
    • Place of Presentation
      Torino, Italy
    • Related Report
      2013 Research-status Report
  • [Presentation] 塩粒表面の不思議な世界

    • Author(s)
      新藤 斎
    • Organizer
      ソルト・サイエンスシンポジウム2013
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Structures of chiral crystal faces inducing Soai reaction

    • Author(s)
      Takashi Fujioka, Tsuyoshi Takeshita, Yusuke Shirota, Hitoshi Shindo
    • Organizer
      12th Symposium on Chemical Approach to Chirality
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
  • [Presentation] Studying friction and wear at crystal surfaces using scanning probe microscopies

    • Author(s)
      Hitoshi Shindo, Gaku Mochimaru, Kaori Niki
    • Organizer
      2nd NCU/CHUO Chemistry Workshop
    • Place of Presentation
      Tokyo
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 岩塩型結晶(001)表面上におけるマイクロスケール摩擦・摩耗

    • Author(s)
      笠原えりか、新藤 斎、二木かおり
    • Organizer
      第32回表面科学学術講演会
    • Place of Presentation
      仙台
    • Related Report
      2012 Research-status Report
  • [Presentation] 酸化環境中で生成するエッチピットのAFM観察によるアナターゼ(TiO2)結晶表面の安定性の比較

    • Author(s)
      大川遥平、西藤俊一郎、新藤 斎、二木かおり
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津(滋賀)
    • Related Report
      2012 Research-status Report
  • [Presentation] イオン結晶表面におけるナノ・マイクロスケールの摩擦機構

    • Author(s)
      新藤 斎・二木かおり
    • Organizer
      第24回中央大学学術シンポジウム
    • Place of Presentation
      草津(滋賀)
    • Related Report
      2012 Research-status Report
  • [Book] ナノスケール・ミクロスケールから見えるビッグな世界 第3章イオン結晶表面におけるナノ・マイクロスケールの摩擦機構2013

    • Author(s)
      二木かおり、新藤 斎
    • Total Pages
      600
    • Publisher
      中央大学出版部
    • Related Report
      2012 Research-status Report
  • [Book] ナノスケール・ミクロスケールから見えるビッグな世界 第5章結晶の形と成長環境 ー表面の溶解過程でできるナノ・ミクロ構造から成長環境を推定する2013

    • Author(s)
      新藤 斎
    • Total Pages
      600
    • Publisher
      中央大学出版部
    • Related Report
      2012 Research-status Report
  • [Remarks] 表面化学研究室研究紹介

    • URL

      http://www.chem.chuo-u.ac.jp/~surface/

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
  • [Remarks] http://www.chem.chuo-u.ac.jp/~surface/

    • Related Report
      2013 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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