Controlling of electric properties of carbon nanosystems by adsorption of organic molecules

• Project/Area Number: 24510150
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Nanomaterials/Nanobioscience
• Research Institution: Kyushu Institute of Technology (2014); Osaka University (2012-2013)
• Principal Investigator: TANAKA Hirofumi 九州工業大学, 生命体工学研究科, 教授 (90373191)
• Co-Investigator(Renkei-kenkyūsha): TANAKA Daisuke 大阪大学, 大学院理学研究科, 助教 (60589399)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000); Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000); Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
• Keywords: グラフェンナノリボン / カーボンナノチューブ / アンジップ / 平面分子 / 吸着 / 半導体化 / 走査トンネル分光 / トランジスタ / ニューロン発火素子 / HAT / 絶縁破壊 / ポリ酸 / POM / ノイズ源 / カーボンナノチューブネットワーク / 負性抵抗

Outline of Final Research Achievements

Planaer molecular nanoparticles are adsorbed to single layer graphene nanoribbon (GNR) obtained by unzipped carbon nanotube. Plateau was obsereved in I-V curve of GNR after adsroption of for example, hat-(CM)6. While particle larger than width of GNR adsorption did not make any change to I-V curves. Electric property of cross structure of semimetallic GNR was investigated and only cross point changed to the semiconduction property.

Research Products

• [Journal Article] Effect of Protonation on the Single-Molecule-Magnet Behavior of a Mixed (Phthalocyaninato)(porphyrinato) Terbium Double-Decker Complex (2015)
  • Author(s): D. Tanaka, N. Sumitani, T. Inose, H. Tanaka, N. Ishikawa, T. Ogawa
  • Journal Title: Chem. Lett. Volume: -
  • NAID: 130005067974
  • Peer Reviewed
• [Journal Article] Correlation of Critical Parameters on Carbon Nanotubes Crystallinity in Chemical Vapor Deposition by using Renewable Bioresource (2015)
  • Author(s): A. TermehYousefi, H. Tanaka, S. Bagheri, M. R. Mahmood, S. Ikeda
  • Journal Title: J. Nanosci. Nanotechnol. Volume: -
• [Journal Article] Thin films of spin-crossover coordination polymers with large thermal hysteresis loops prepared by nanoparticle spin coating (2014)
  • Author(s): D. Tanaka, N. Aketa, H. Tanaka, T. Tamaki, T. Inose, T. Akai, H. Toyama, O. Sakata, Hiroo Tajiri, T. Ogawa
  • Journal Title: Chemical communications Volume: 50 Issue: 70 Pages: 10074-10077
  • DOI: 10.1039/c4cc04123b
  • Peer Reviewed / Open Access
• [Journal Article] 光アシスト原子スイッチを用いたナノ光センサーの開発～人工網膜への可能性～ (2014)
  • Author(s): 田中啓文、小川琢治
  • Journal Title: マテリアルステージ６月号 Volume: - Pages: 1-4
  • NAID: 40020118857
• [Journal Article] Influence of Atmosphere on Photo-Assisted Atomic Switch Operations (2014)
  • Author(s): 日野貴美、長谷川剛、田中啓文、鶴岡徹、小川琢治、青野正和
  • Journal Title: Key Engineering Materials Volume: 596 Pages: 116-120
  • DOI: 10.4028/www.scientific.net/kem.596.116
  • Peer Reviewed
• [Journal Article] Surface self-assembly of trans-substituted porphyrin double-decker complexes exhibiting slow magnetic relaxation (2014)
  • Author(s): D. Tanaka, T. Inose, S. Shimono, H. Tanaka, T. Tamaki, A. I. A. A. El-mageed, A. K. F. Dyab, N. Ishikawa, T. Ogawa
  • Journal Title: e-J. Surf. Sci. Nanotechnol. Volume: 12 Pages: 185-188
  • NAID: 130004933809
  • Peer Reviewed
• [Journal Article] Sequential phase transition during fabricating β-Ag2S film on Agelectrode by wet chemical process (2014)
  • Author(s): H. Tanaka, T. Akai, D. Tanaka, T. Ogawa
  • Journal Title: e-J. Surf. Sci. Nanotechnol. Volume: 12 Pages: 124-128
  • NAID: 130004438879
  • Peer Reviewed
• [Journal Article] Temperature-Dependent Current-Voltage and Photoresponsive Properties for Semiconducting Nanodevices Fabricated from an Oligothiazole Dithiol and Gold Nanoparticles (2013)
  • Author(s): T. Tao, J. Geng, L. Hong, W. Huang, H. Tanaka, D. Tanaka, and T. Ogawa
  • Journal Title: J. Phys. Chem. C Volume: 117 Issue: 48 Pages: 25325-258333
  • DOI: 10.1021/jp409124u
  • Peer Reviewed / Open Access
• [Journal Article] Advanced Photoassisted Atomic Switch Produced Using ITO Nanowire Electrodes and Molten Photoconductive Organic Semiconductor (2013)
  • Author(s): A. Klamchuen, H. Tanaka, D. Tanaka, H. Toyama, G. Meng, S. Rahong, K. Nagashima, M. Kanai, T. Yanagida, T. Kawai and T. Ogawa
  • Journal Title: Advanced Materials Volume: 25 Issue: 41 Pages: 5893-5897
  • DOI: 10.1002/adma.201302552
  • Peer Reviewed / Open Access
• [Journal Article] Volatile and nonvolatile selective switching of a photo-assisted initialized atomic switch (2013)
  • Author(s): 日野貴美、長谷川剛、田中啓文、鶴岡徹、寺部一弥、小川琢治、青野正和
  • Journal Title: NANOTECHNOLOGY Volume: 24 Issue: 38 Pages: 384006-384006
  • DOI: 10.1088/0957-4484/24/38/384006
  • Peer Reviewed
• [Journal Article] Rectification direction inversion in a phosphododecamolybdic acid /single-walled carbon nanotube junction (2013)
  • Author(s): Liu Hong, Hirofumi Tanaka and Takuji Ogawa
  • Journal Title: J. Mat. Chem. C Volume: 1(6) Issue: 6 Pages: 1137-1143
  • DOI: 10.1039/c2tc00171c
  • Peer Reviewed
• [Journal Article] Influence of nanoparticle size to the electrical properties of naphthalenediimide on single-walled carbon nanotube wiring (2012)
  • Author(s): Hirofumi Tanaka, Liu Hong, Minoru Fukumori, Ryota Negishi, Yoshihiro Kobayashi, Daisuke Tanaka, and Takuji Ogawa
  • Journal Title: Nanotechnology Volume: 23 Issue: 21 Pages: 215701-215701
  • DOI: 10.1088/0957-4484/23/21/215701
  • Peer Reviewed
• [Journal Article] Large Rectification Effect Achieved bya Combination of Carbon Nanotube Junction and Molecule-Carbon Nanotube Interface (2012)
  • Author(s): Liu Hong, Hirofumi Tanaka, and Takuji Ogawa
  • Journal Title: Applied Physics Express Volume: 5 Issue: 11 Pages: 115102-115102
  • DOI: 10.1143/apex.5.115102
  • Peer Reviewed
• [Journal Article] Nanoscale diodes composed of single-walled carbon nanotube and physically adsorbed organic molecule nanoparticles (2012)
  • Author(s): Liu Hong, H. Tanaka, T. Ogawa
  • Journal Title: 12th IEEE Conference on Nanotechnology (IEEE-NANO) Volume: 1 Pages: 1-5
  • DOI: 10.1109/nano.2012.6321905
• [Presentation] スピントロニクスを志向したポルフィリンTb二核錯体の合成と物性評価 (2015)
  • Author(s): 坂田直弥・田中大輔・炭谷宣登・猪瀬朋子・田中啓文・小川琢治
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2015-03-27
• [Presentation] 単層カーボンナノチュブ のアンジップ経時変化 (2015)
  • Author(s): 福森 稔・ 田中 啓文 ・田中 大輔・小川 琢冶
  • Organizer: 第62回応用物理学会春季学術講演会
  • Place of Presentation: 東海大学（湘南キャンパス）
  • Year and Date: 2015-03-12 – 2015-03-13
• [Presentation] "カーボンナノチューブ・ポリ酸ネットワークの ニューロン発火特性のカオス解析 " (2015)
  • Author(s): 付 凌翔・ 田向 権・小川 琢治・田中 啓文
  • Organizer: 第62回応用物理学会春季学術講演会
  • Place of Presentation: 東海大学（湘南キャンパス）
  • Year and Date: 2015-03-12 – 2015-03-13
• [Presentation] "ナノアーキテクチャーにおける知能創発 ～有機無機修飾ナノデバイスによる生体信号再現への挑戦～" (2015)
  • Author(s): 田中啓文
  • Organizer: 千葉大学テニュアトラック教員主催セミナー
  • Place of Presentation: 千葉大学
  • Year and Date: 2015-03-11
  • Invited
• [Presentation] Neuron-like signal generation and its chaotic analysis of single-walled carbon nanotube and nanoparticle complex (2014)
  • Author(s): H. Tanaka H. Tamukoh T. Asai T. Ogawa
  • Organizer: ICSPM22
  • Place of Presentation: 熱川ハイツ
  • Year and Date: 2014-12-11
• [Presentation] Fabrication of Nanogap Electrodes by Molecular Ruler Method (2014)
  • Author(s): Hirofumi Tanaka
  • Organizer: MNC2014
  • Place of Presentation: 福岡シーホーク
  • Year and Date: 2014-11-05
  • Invited
• [Presentation] Rectification behavior of single molecule diode connected to SWNTs (2014)
  • Author(s): Murni Handayani, Syun Gohda, Hirofumi Tanaka, Daisuke Tanaka and Takuji Ogawa.
  • Organizer: Osaka University-Hanyang University Student Exchange Program
  • Place of Presentation: 大阪大学
  • Year and Date: 2014-10-28
• [Presentation] カーボンナノチューブネットワークを用いた脳型デバイス (2014)
  • Author(s): 田中啓文
  • Organizer: ナノカーボンバイオセンサーの医療応用研究会
  • Place of Presentation: 科学技術交流財団
  • Year and Date: 2014-10-09
  • Invited
• [Presentation] Electric properties of single-walled carbon nanotube and nanoparticle complex for neuron-like signal generation (2014)
  • Author(s): Hirofumi Tanaka
  • Organizer: National Conference, Lembaga IImu Pengetahuan Indonesia (LIPI)
  • Place of Presentation: The Indonesian Institute of Sciences
  • Year and Date: 2014-09-30
  • Invited
• [Presentation] "Electric Properties of Single-walled Carbon Nanotube and Nanoparticle Complex for Neuron-like Signal Generation" (2014)
  • Author(s): Hirofumi Tanaka
  • Organizer: The Material Research Society of Indonesia (MRS-Id) 2014
  • Place of Presentation: Bali、Indonesia
  • Year and Date: 2014-09-27
  • Invited
• [Presentation] スピンクロスオーバー配位高分子/単層カーボンナノチューブ複合薄膜デバイスの電気伝導特性評価 (2014)
  • Author(s): 田中大輔・明田直樹・田中啓文・小川琢治
  • Organizer: 錯体化学討論会第64回討論会
  • Place of Presentation: 中央大学（後楽園キャンパス）
  • Year and Date: 2014-09-18
• [Presentation] Au(111)上オクタエチルポルフィリンダブルデッカー型単分子磁石のSTMを用いた単一分子操作 (2014)
  • Author(s): 猪瀬朋子・田中大輔・Liu Jie・田中啓文・米田忠弘・小川琢治
  • Organizer: 第75回応用物理学会秋季学術講演会
  • Place of Presentation: 北海道大学（札幌キャンパス）
  • Year and Date: 2014-09-17
• [Presentation] スピントロニクスを志向したポルフィリンTb二核錯体の合成と物性評価 (2014)
  • Author(s): 坂田直弥・田中大輔・炭谷宣登・猪瀬朋子・田中啓文・小川琢治
  • Organizer: 第25回基礎有機化学討論会
  • Place of Presentation: 東北大学（川内北キャンパス）
  • Year and Date: 2014-09-07 – 2014-09-09
• [Presentation] ポルフィリン単分子磁石の磁気挙動制御 (2014)
  • Author(s): 田中大輔・猪瀬朋子・下野颯騎・酒井 駿・田中啓文・小川琢治
  • Organizer: 第25回基礎有機化学討論会
  • Place of Presentation: 東北大学（川内北キャンパス）
  • Year and Date: 2014-09-07 – 2014-09-09
• [Presentation] Electrical Properties of Single-Molecule Junction Porphyrin-Imide Connected to SWNTs (2014)
  • Author(s): Murni Handayani, Sinichi Katayose, Syun Gohda, Hirofumi Tanaka, Daisuke Tanaka and Takuji Ogawa
  • Organizer: 7th international conference on molecular electronic
  • Place of Presentation: Strasbourg、France
  • Year and Date: 2014-08-28
• [Presentation] Investigation of 2D supramolecular structure of porphyrinbasd terbium(III) single molecular magnets (2014)
  • Author(s): Tomoko Inose, Daisuke Tanaka, Hirofumi Tanaka, Oleksandr Ivasenko, Toshi Nagata, Steven De Feyter, Naoto Ishikawa, Takuji Ogawa
  • Organizer: ICMM
  • Place of Presentation: St. Petersburg、Russia
  • Year and Date: 2014-07-06
• [Presentation] SWITCHING PROPERTIES OF DOUBLE-DECKER PORPHYRIN SINGLE-MOLECULE MAGNETS (2014)
  • Author(s): Daisuke Tanaka, Tomoko Inosea, Ssatsuki Shimonoa, Hirofumi Tanaka, Naoto Ishikawa, Takuji Ogawa
  • Organizer: ICMM
  • Place of Presentation: St. Petersburg、Russia
  • Year and Date: 2014-07-06
• [Presentation] Controlling molecular alignment on HOPG of porphyrin-Tb(III) double-decker single molecular magnets (2014)
  • Author(s): Tomoko Inose, Daisuke Tanaka, Hirofumi Tanaka, Oleksandr Ivasenko, Toshi Nagata, Steven De Feyter, Naoto Ishikawa, Takuji Ogawa
  • Organizer: Electrochemical Society, ECS 225th
  • Place of Presentation: Orlando、USA
  • Year and Date: 2014-05-13 – 2014-05-14
• [Presentation] Single-molecule electronics based on porphyrin molecules for functionality emergence (2014)
  • Author(s): Takuji Ogawa, Hirofumi Tanaka, Daisuke Tanaka, Tomoko Inose, Murni Handayani, Takashi Tamaki, Fuyuko Ojima
  • Organizer: Electrochemical Society, ECS 225th
  • Place of Presentation: Orlando、USA
  • Year and Date: 2014-05-13 – 2014-05-14
  • Invited
• [Presentation] Electrical Properties of Complex of Nanoparticles and Single-Walled Carbon Nanotube (2014)
  • Author(s): Hirofumi Tanaka, Liu Hong, Minoru Fukumori, Daisuke Tanaka and Takuji Ogawa,
  • Organizer: Electrochemical Society, ECS 225th
  • Place of Presentation: Orlando、USA
  • Year and Date: 2014-05-13 – 2014-05-14
• [Presentation] ナノカーボン配線上のリンモリブデン酸ナノ粒子の伝導特性 (2013)
  • Author(s): 田中啓文，洪流，田中大輔，小川琢治
  • Organizer: 春季第61回応用物理学関係連合講演会
  • Place of Presentation: 立命館大学
• [Presentation] 有機・無機ナノ粒子吸着による単層カーボンナノチューブ・グラフェンナノリボンの電子状態変化に関する研究 (2012)
  • Author(s): 田中 啓文，有馬 良，田中 大輔, 小川 琢治
  • Organizer: 第10回ナノ学会講演会
  • Place of Presentation: 大阪大学
• [Presentation] Controlling electrical properties carbon nanosystems by nanoparticle adsorption (2012)
  • Author(s): H. Tanaka, L. Hong, R. Arima, M. Fukumori, D. Tanaka, T. Ogawa
  • Organizer: AsisaNANO 2012
  • Place of Presentation: 中国雲南省麗江
  • Invited
• [Presentation] Electrical property of nanoparticles of naphthalene diimideon single-walled carbon nanotube or graphene nanoribbon (2012)
  • Author(s): M. Fukumori, H. Tanaka, D. Tanaka, T. Ogawa
  • Organizer: AsisaNANO 2012
  • Place of Presentation: 中国雲南省麗江
• [Presentation] ナノカーボン/分子ナノ粒子複合体の電気物性と新機能発現
  • Author(s): 田中啓文
  • Organizer: 日本学術振興会第176委員会第70回講演会
  • Place of Presentation: 産業技術総合研究所臨海副都心センター別館
  • Invited
• [Presentation] ナノカーボン・微粒子複合体の電気伝導特性
  • Author(s): 田中啓文
  • Organizer: フラーレン・ナノチューブ・グラフェン総合シンポジウム若手の会
  • Place of Presentation: 大阪大学
  • Invited
• [Presentation] メカニカルブレークジャンクション法によるポルフィリン-イミド単一分子電気測定
  • Author(s): 片寄慎一、田中啓文、Murni Handayani、山田亮、多田博一、小川琢治
  • Organizer: 第74回応用物理学会秋季学術講演会
  • Place of Presentation: 同志社大学
• [Presentation] グラフェンナノリボン/分子複合体の電気特性
  • Author(s): 福森稔，田中啓文, 田中大輔, 小川琢治
  • Organizer: 第74回応用物理学会秋季学術講演会
  • Place of Presentation: 同志社大学
• [Presentation] Electric properties of porphyrin-imide single molecular junction measured by mechanically controllable break junction method
  • Author(s): Shinichi Katayose, Hirofumi Tanaka, Murni Handayani, Takuji Ogawa
  • Organizer: ACSIN-12 & ICSPM21
  • Place of Presentation: Tsukuba International Congress Center
• [Presentation] Advanced Photoassisted Atomic Switch Produced Using ITO Nanowire Electrodes and Molten Photoconductive Organic semiconductor
  • Author(s): Hirofumi Tanaka
  • Organizer: ACSIN-12 & ICSPM21
  • Place of Presentation: Tsukuba International Congress Center
• [Presentation] カーボンナノチューブ・ポリ酸ネットワークのニューロン発火特性
  • Author(s): 田中啓文，洪流，酒井駿, 田中大輔，小川琢治
  • Organizer: 応用物理学会
  • Place of Presentation: 青山学院大学
• [Presentation] カーボンナノチューブ/ポリ酸ネットワーク中の内在ノイズによるニューロン発火現象
  • Author(s): 田中啓文,浅井哲也,片寄慎一,洪流,小川琢治
  • Organizer: 日本化学会年会
  • Place of Presentation: 名古屋大学
• [Presentation] 少数分子/ナノカーボン複合体の電気伝導特性と新機能発現
  • Author(s): 田中啓文
  • Organizer: 物理学会
  • Place of Presentation: 徳島大学
  • Invited
• [Remarks] 田中啓文研究内容
  • URL: http://www.brain.kyutech.ac.jp/~tanaka/research.html
• [Remarks] 知能創発ナノシステム研究室【田中啓文研究室】ホームページ
  • URL: http://www.brain.kyutech.ac.jp/~tanaka/
• [Patent(Industrial Property Rights)] 非線形素子 (2013)
  • Inventor(s): 田中啓文、浅井哲也、小川琢治
  • Industrial Property Rights Holder: 田中啓文、浅井哲也、小川琢治
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2013-179578
  • Filing Date: 2013-08-30