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Development of as-grown free-standing carbon nanoribbon and clarification of its structure and physical proporties

Research Project

Project/Area Number 24510153
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionKumamoto University

Principal Investigator

Yokoi Hiroyuki  熊本大学, 自然科学研究科, 准教授 (50358305)

Co-Investigator(Renkei-kenkyūsha) HARA Masahiro  熊本大学, 大学院自然科学研究科, 准教授 (50392080)
KISHIGI Keita  熊本大学, 教育学部, 准教授 (60359966)
Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywords架橋型グラフェンナノリボン / カーボンナノポット / 非平衡反応場 / 液面下化学気相合成 / ラマンスペクトルマッピング / グラフェン端 / ナノ容器 / ナノファイバー / 架橋型カーボンナノリボン / グラフェン / 液面下CVD法 / 非平衡条件 / 新規ナノ構造 / ナノ空間 / ドラッグデリバリ / 新物質 / 新ナノカーボン物質 / ナノ材料 / 電子・電気材料
Outline of Final Research Achievements

We have developed a chemical vapor deposition (CVD) method named ‘submarine-style substrate heating CVD method’, where the deposition is enabled in the environment of a high temperature gradient under the liquid level, and succeeded to synthesize as-grown free-standing carbon nanoribbon. Moreover, we have set up a hand-made mapping measurement system of Raman spectra and revealed that the carbon nanoribbon is made of graphene sheets. However, we could not clarify its electric property as it was difficult to improve its purity. On the other hand, we have succeeded to create a novel carbon nanomaterial using the submarine-style CVD method and named the material ‘carbon nanopot’. Carbon nanopot has a pot-like shape with a deep hollow space and is synthesized in series with the appearance of fiber. Therefore, we expect that the new material can be applied in various fields as fibers as well as pieces.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (25 results)

All 2016 2015 2014 2013 2012 Other

All Journal Article (4 results) (of which Acknowledgement Compliant: 4 results,  Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (17 results) (of which Int'l Joint Research: 1 results,  Invited: 3 results) Remarks (2 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Novel pot-shaped carbon nanomaterial synthesized in a submarine-style substrate heating CVD method2016

    • Author(s)
      Hiroyuki Yokoi, Kazuto Hatakeyama, Takaaki Taniguchi, Michio Koinuma, Masahiro Hara and Yasumichi Matsumoto
    • Journal Title

      Journal of Materials Research

      Volume: 31 Issue: 1 Pages: 117-126

    • DOI

      10.1557/jmr.2015.389

    • NAID

      120005764248

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 新規壺型ナノカーボン物質「カーボンナノポット」の開発2015

    • Author(s)
      横井裕之
    • Journal Title

      化学工業

      Volume: 66 Pages: 743-747

    • Related Report
      2015 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Creating a New Pot-shaped Carbon Nanomaterial2015

    • Author(s)
      Hiroyuki Yokoi
    • Journal Title

      CONVERTECH&e-Print

      Volume: 5 Pages: 104-107

    • NAID

      40020429469

    • Related Report
      2014 Research-status Report
    • Acknowledgement Compliant
  • [Journal Article] 壺型構造を持つ新規ナノカーボン材料の創製2014

    • Author(s)
      横井 裕之
    • Journal Title

      コンバーテック

      Volume: 42 Pages: 54-57

    • Related Report
      2014 Research-status Report
    • Acknowledgement Compliant
  • [Presentation] 酸化グラフェンを利用した新規ナノ構造カーボン物質の開発2016

    • Author(s)
      横井裕之
    • Organizer
      第6回酸化グラフェンシンポジウム
    • Place of Presentation
      九州大学筑紫キャンパス
    • Year and Date
      2016-06-17
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 新規壺型ナノカーボン物質「カーボンナノポット」の創製と特性調査2016

    • Author(s)
      横井裕之
    • Organizer
      カーボンナノ材料研究会
    • Place of Presentation
      大阪科学技術センター
    • Year and Date
      2016-01-14
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Synthesis of Carbon Nanopot with Fe Catalyst supported on Graphene Oxide2015

    • Author(s)
      Hiroyuki Yokoi, Kazuto Hatakeyama, Michio Koinuma, Takaaki Taniguchi, Yasumichi Matsumoto
    • Organizer
      第49回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] 新規壺型ナノカーボン物質「カーボンナノポット」の開発2015

    • Author(s)
      横井裕之
    • Organizer
      くまもと発新技術説明会
    • Place of Presentation
      科学技術振興機構
    • Year and Date
      2015-07-30
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Development of a novel pot-shaped carbon nanomaterial2015

    • Author(s)
      Hiroyuki Yokoi, Kazuto Hatakeyama, Takaaki Taniguchi, Michio Koinuma, Yasumichi Matsumoto
    • Organizer
      The 16th International Conference on the Science and Application of Nanotubes
    • Place of Presentation
      名古屋大学
    • Year and Date
      2015-06-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Study on growth conditions of Carbon Nanopot: Catalysis support property of graphene oxide2015

    • Author(s)
      Hiroyuki Yokoi, Kazuto Hatakeyama, Takaaki Taniguchi, Michio Koinuma, Hiroyuki Yoshikawa, Masahiro Hara, Yasumichi Matsumoto
    • Organizer
      第4回酸化グラフェンシンポジウム
    • Place of Presentation
      熊本大学
    • Year and Date
      2015-06-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] Photo-reduction of graphene oxide for improvement of the purity of carbon nanopot2015

    • Author(s)
      Hiroyuki Yokoi, Kazuto Hatakeyama, Shogo Matsumoto, Mako Ueda, Takaaki Taniguchi, Michio Koinuma, Yasumichi Matsumoto
    • Organizer
      第48回 フラーレン・ナノチューブ・グラフェン 総合シンポジウム
    • Place of Presentation
      東京大学 伊藤国際学術研究センター 伊藤謝恩ホール
    • Year and Date
      2015-02-21 – 2015-02-23
    • Related Report
      2014 Research-status Report
  • [Presentation] 酸化グラフェンを用いた壺型ナノカーボン物質の創製2014

    • Author(s)
      横井裕之, 畠山一翔, 松本正吾, 上田茉子, 谷口貴章, 鯉沼陸央, 松本泰道
    • Organizer
      第3回酸化グラフェンシンポジウム
    • Place of Presentation
      東工大キャンパス・イノベーションセンター
    • Year and Date
      2014-12-18
    • Related Report
      2014 Research-status Report
  • [Presentation] 壺型ナノカーボンファイバー の合成と構造2014

    • Author(s)
      横井裕之, 畠山一翔, 上田茉子, 松本正吾, 谷口貴章, 鯉沼陸央, 松本泰道
    • Organizer
      第41回炭素材料学会年会
    • Place of Presentation
      大野城まどかぴあ
    • Year and Date
      2014-12-08 – 2014-12-10
    • Related Report
      2014 Research-status Report
  • [Presentation] A New Type of Beaded Carbon Nanotubes Synthesized in the Submarine-Style CVD2014

    • Author(s)
      Hiroyuki Yokoi, Kazuto Hatakeyama, Takaaki Taniguchi, Michio Koinuma, Yasumichi Matsumoto
    • Organizer
      2014 Materials Research Society Fall Meeting
    • Place of Presentation
      Hynes Convention Center, Boston, Massachusetts, USA
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] ネックレス型類似新規構造カーボンナノチューブの合成2014

    • Author(s)
      横井裕之, 畠山一翔, 谷口貴章, 鯉沼陸央, 松本泰道
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学札幌キャンパス
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis of carbon nanotube with an unconventional beaded structure2014

    • Author(s)
      Hiroyuki Yokoi, Kazuto Hatakeyama, Mako Ueda, Shogo Matsumoto, Takaaki Taniguchi, Michio Koinuma, Yasumichi Matsumoto
    • Organizer
      第47回 フラーレン・ナノチューブ・グラフェン 総合シンポジウム
    • Place of Presentation
      名古屋大学 IB電子情報館
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 酸化グラフェンの発光機構2014

    • Author(s)
      横井裕之、谷口貴章、鯉沼陸央、松本泰道
    • Organizer
      日本物理学会第69回年次大会
    • Place of Presentation
      東海大学湘南キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 液面下CVD法によるナノカーボン物質の合成2013

    • Author(s)
      横井裕之、大坪一輝、平山翔太
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Synthesis of Nanocarbon Composites Based on Reduced Graphene Oxides2012

    • Author(s)
      エリヤ・インダヒャンティ、横井裕之、畠山一翔、松本泰道
    • Organizer
      第43回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      東北大学百周年記念会館(仙台市)
    • Related Report
      2012 Research-status Report
  • [Presentation] 酸化グラフェンーカーボンナノチューブ複合体の合成

    • Author(s)
      横井裕之、エリヤ インダヒャンティ、大坪一輝、平山翔太、畠山一翔、松本泰道
    • Organizer
      日本金属学会九州支部・日本鉄鋼協会九州支部・軽金属学会九州支部合同学術講演会
    • Place of Presentation
      熊本県民交流館パレア
    • Related Report
      2013 Research-status Report
  • [Presentation] Synthesis of Nanocarbon Composites Based on Reduced Graphene Oxides

    • Author(s)
      エリヤ・インダヒャンティ、横井裕之、畠山一翔、松本泰道
    • Organizer
      日本金属学会九州支部・日本鉄鋼協会九州支部・軽金属学会九州支部合同学術講演会
    • Place of Presentation
      北九州国際会議場(北九州市)
    • Related Report
      2012 Research-status Report
  • [Remarks] 熊本大学ナノカーボン材料学研究室ホームページ

    • URL

      http://www.msre.kumamoto-u.ac.jp/~yokoi-gr/about.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] 熊本大学機能材料設計学研究室横井グループホームページ

    • URL

      http://www.msre.kumamoto-u.ac.jp/~yokoi-gr/index-j.html

    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] ポット型ナノカーボン材料及びその製造方法2015

    • Inventor(s)
      横井裕之、松本泰道
    • Industrial Property Rights Holder
      熊本大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-07-31
    • Related Report
      2015 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] ポット型ナノカーボン材料及びその製造方法2014

    • Inventor(s)
      横井裕之、松本泰道
    • Industrial Property Rights Holder
      熊本大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-156523
    • Filing Date
      2014-07-31
    • Related Report
      2014 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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