Guest-host interaction in porous coordination polymers with selective sorption property

• Project/Area Number: 24510154
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Nanomaterials/Nanobioscience
• Research Institution: Osaka Prefecture University
• Principal Investigator: KUBOTA Yoshiki 大阪府立大学, 理学(系)研究科(研究院), 教授 (50254371)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000); Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000); Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
• Keywords: 多孔性材料 / ガス吸着 / 放射光粉末回折 / 精密電子密度解析 / 選択的ガス吸着 / 粉末未知結晶構造解析 / 実空間法 / Metal-Organic Framework / マキシマムエントロピー法 / 放射光粉末回折法

Outline of Final Research Achievements

This study revealed the structural change in the gas adsorption of porous coordination polymers (PCPs) with selective sorption property by the synchrotron powder diffraction method. It was found that a certain interdigitate type PCP has an unusual framework structure in CO2 adsorbed phase. Interdigitate type PCPs usually have framework structure in which the ligand molecules stack by π-π interaction. But in this compound, another pore is formed between the ligand molecules and the amount of adsorbate CO2 increased. The relation between the characteristic flexible framework and selective sorption property of PCPs was revealed.

Research Products

• [Journal Article] Remarkable Oxygen Intake/Release of BaYMn2O5+ Viewed from High-Temperature Crystal Structure (2015)
  • Author(s): Teruki Motohashi, Taira Takahashi, Makoto Kimura, Yuji Masubuchi, Shinichi Kikkawa, Yoshiki Kubota, Yoji Kobayashi, Hiroshi Kageyama, Masaki Takata, Susumu Kitagawa, Ryotaro Matsuda
  • Journal Title: J. Phys. Chem. C Volume: 119 Issue: 5 Pages: 2356-2363
  • DOI: 10.1021/jp511648b
  • Peer Reviewed
• [Journal Article] Hydrogen storage in Pd nanocrystals covered with a metal–organic framework (2014)
  • Author(s): Guangqin Li, Hirokazu Kobayashi, Jared M. Taylor, Ryuichi Ikeda, Yoshiki Kubota, Kenichi Kato, Masaki Takata, Tomokazu Yamamoto, Shoichi Toh, Syo Matsumura, Hiroshi Kitagawa
  • Journal Title: Nature Mater. Volume: 13 Issue: 8 Pages: 802-806
  • DOI: 10.1038/nmat4030
  • Peer Reviewed
• [Journal Article] An Ordered BCC CuPd Nanoalloy Synthesized via the Thermal Decomposition of Pd Nanoparticles Covered with a metal-Organic Framework under Hydrogen Gas (2014)
  • Author(s): Guangqin Li, Hirokazu Kobayashi, Kohei Kusada, Jared M. Taylor, Yoshiki Kubota, Kenichi Kato, Masaki Takata, Tomokazu Yamamoto, Syo Matsumura, Hiroshi Kitagawa
  • Journal Title: Chem. Commun. Volume: 50 Issue: 89 Pages: 13750-13753
  • DOI: 10.1039/c4cc05941g
  • Peer Reviewed
• [Journal Article] Solid Solution Alloy Nanoparticles of Immiscible Pd and Ru Elements Neighboring on Rh: Changeover of the Thermodynamic Behavior for Hydrogen Storage and Enhanced CO-Oxidizing Ability (2014)
  • Author(s): Kohei Kusada, Hirokazu Kobayashi, Ryuichi Ikeda, Yoshiki Kubota, Masaki Takata, Shoichi Toh, Tomokazu Yamamoto, Syo Matsumura, Naoya Sumi, Katsutoshi Sato, Katsutoshi Nagaoka, Hiroshi Kitagawa
  • Journal Title: J. Am. Chem. Soc. Volume: 136 Issue: 5 Pages: 1864-1871
  • DOI: 10.1021/ja409464g
  • Peer Reviewed
• [Journal Article] Shape-Dependent Hydrogen-Storage Properties in Pd Nanocrystals: Which Does Hydrogen Prefer, Octahedron (111) or Cube (100)? (2014)
  • Author(s): Guangqin Li, Hirokazu Kobayashi, Shun Dekura, Ryuichi Ikeda, Yoshiki Kubota, Kenichi Kato, Masaki Takata, Tomokazu Yamamoto, Syo Matsumura, Hiroshi Kitagawa
  • Journal Title: J. Am. Chem. Soc. Volume: 136 Issue: 29 Pages: 10222-10225
  • DOI: 10.1021/ja504699u
  • Peer Reviewed
• [Journal Article] High CO2/N2/O2/CO Separation in a Chemically Robust Porous Coordination Polymer with Low Binding Energy (2014)
  • Author(s): Jingui Duan, Masakazu Higuchi, Rajamani Krishna, Tomokazu Kiyonaga, Yosuke Tsutsumi, Yohei Sato, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa
  • Journal Title: Chem. Sci. Volume: 5 Issue: 2 Pages: 660-666
  • DOI: 10.1039/c3sc52177j
  • Peer Reviewed
• [Journal Article] Microporous Structures Having Phenylene Fin: Significance of Substituent Groups for Rotational Linkers in Coordination Polymers (2014)
  • Author(s): Ryotaro Matsuda, Wataru Kosaka, Ryo Kitaura, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa
  • Journal Title: Microporous and Mesoporous Materials Volume: 189 Pages: 83-90
  • DOI: 10.1016/j.micromeso.2013.10.029
  • Peer Reviewed
• [Journal Article] Structural and Magnetic Properties in Spinel Oxide Fe1-xMnxV2O4 (2014)
  • Author(s): Shogo Kawaguchi, Hiroki Ishibashi, Fumiya Miki, Yoshiki Kubota
  • Journal Title: JPS Conf. Proc. Volume: 1
  • Peer Reviewed
• [Journal Article] Spin-Dependent Molecular Orientation of O2–O2 Dimer Formed in the Nanoporous Coordination Polymer (2013)
  • Author(s): Akihiro Hori, Tatsuo C. Kobayashi, Yoshiki Kubota, Akira Matsuo, Kouichi Kindo, Jungeun Kim, Kenichi Kato, Masaki Takata, Hirotoshi Sakamoto, Ryotaro Matsuda, Susumu Kitagawa
  • Journal Title: J. Phys. Soc. Jpn. Volume: 82 Issue: 8 Pages: 084703-084703
  • DOI: 10.7566/jpsj.82.084703
  • Peer Reviewed
• [Journal Article] Structural Properties in Incommensurately Modulated Spinel Compound CuV2S4 (2013)
  • Author(s): Shogo Kawaguchi, Hiroki Ishibashi, Naruki Tsuji, Jungeun Kim, Kenichi Kato, Masaki Takata, Yoshiki Kubota
  • Journal Title: J. Phys. Soc. Jpn. Volume: 82 Issue: 6 Pages: 064603-064603
  • DOI: 10.7566/jpsj.82.064603
  • NAID: 210000132599
  • Peer Reviewed
• [Journal Article] Crystal structures of X-phase in the Sb–Te binary alloy system (2013)
  • Author(s): Kouichi Kifune, Tomoko Fujita, Takuya Tachizawa, Yoshiki Kubota, Noboru Yamada, Toshiyuki Matsunaga
  • Journal Title: Cryst. Res. Technol. Volume: 48 Issue: 11 Pages: 1011-1021
  • DOI: 10.1002/crat.201300252
  • Peer Reviewed
• [Journal Article] Ligand-based Solid Solution Approach to Stabilisation of Sulphonic Acid Groups in Porous Coordination Polymer Zr604(OH)4 (BDC) 6 (UiO-66) (2012)
  • Author(s): M. L. Foo, T. Fukushima, S. Kitagawa, 他
  • Journal Title: Dalton Trans. Volume: 41 Issue: 45 Pages: 13791-13794
  • DOI: 10.1039/c2dt31195j
  • Peer Reviewed
• [Journal Article] Modular Design of Domain Assembly in Porous Coordination Polymer Crystals via Reactivity-Directed Crystallization Process (2012)
  • Author(s): T. Fukushima, S. Horike, S. Kitagawa, 他
  • Journal Title: J. Am. Chem. Soc. Volume: 134 Issue: 32 Pages: 13341-13347
  • DOI: 10.1021/ja303588m
  • Peer Reviewed
• [Journal Article] Study of Argon Gas Adsorption in Ordered Mesoporous MFI Zeolite Framework (2012)
  • Author(s): Hae Sung Cho, Keiichi Miyasaka, Hyungjun Kim, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa, Ryong Ryoo, Osamu Terasaki
  • Journal Title: J. Phys. Chem. C Volume: 116 Issue: 48 Pages: 25300-25308
  • DOI: 10.1021/jp306268d
  • Peer Reviewed
• [Journal Article] A Stand-Alone Mesoporous Crystal Structure Model from an in situ X-ray Diffraction: Nitrogen Adsorption on 3D Cagelike Mesoporous Silica SBA-16 (2012)
  • Author(s): Keiichi Miyasaka, Hiroko Hano, Yoshiki Kubota, Yangzheng Lin, Ryong Ryoo, Masaki Takata, Susumu Kitagawa, Alexander V. Neimark, Osamu Terasaki
  • Journal Title: Chem. Eur. J. Volume: 18 Issue: 33 Pages: 10300-10311
  • DOI: 10.1002/chem.201201398
  • Peer Reviewed
• [Journal Article] Strutural Analysis of Spinel Compound CuV2S4 with Incommensurate Charge-Density Wave (2012)
  • Author(s): Shogo Kawaguchi, Yoshiki Kubota, Naruki Tsuji, Jungeun Kim, Kenichi Kato, Masaki Takata, Hiroki Ishibashi
  • Journal Title: J. Phys.: Conf. Ser. Volume: 391 Pages: 12095-12095
  • DOI: 10.1088/1742-6596/391/1/012095
  • Peer Reviewed
• [Journal Article] Structural transformation of Sb-based high-speed phase-change material (2012)
  • Author(s): Toshiyuki Matsunaga, Rie Kojima, Noboru Yamada, Yoshiki Kubota, Kouichi Kifune
  • Journal Title: Acta Cryst. B Volume: 68 Issue: 6 Pages: 559-570
  • DOI: 10.1107/s0108768112039961
  • Peer Reviewed
• [Presentation] Relation between the Molecular Orientation and Spin State of O2-O2 dimer Adsorbed on MOF Materials (2014)
  • Author(s): Yoshiki Kubota
  • Organizer: OPU-FZU joint International Symposium on Photocatalysis, Photo-Functional Materials and Nano-Science & Technology
  • Place of Presentation: Osaka Prefecture University (Sakai, Osaka)
  • Year and Date: 2014-12-05
• [Presentation] ナノ細孔内に閉じ込められた酸素分子の配列とその振動モードの観測 (2014)
  • Author(s): 佐藤洋平、藤井駿策、堀彰宏、松田亮太郎、加藤健一、高田昌樹、北川進、久保田佳基
  • Organizer: 日本結晶学会平成26年度年会
  • Place of Presentation: 東京大学
  • Year and Date: 2014-11-01
• [Presentation] The Crystal Structure and Magnetic property of Iodine Adsorbed [Fe(Pz)Pd(CN)4] (2014)
  • Author(s): Yohei Sato, Kazufumi Kimura, Akihiro Hori, Ryo Ohtani, Masaaki Ohba, Kenichi Kato, Masaki Takata, Susumu Kitagawa, Yoshiki Kubota
  • Organizer: 4th International Conference on Metal-Organic Frameworks & Open Framework Compounds (mof2014)
  • Place of Presentation: Kobe International Conference Center
  • Year and Date: 2014-09-30
• [Presentation] Molecular Motion of Oxygen in The Nanopore of Metal-Organic Frameworks (2014)
  • Author(s): Yoshiki Kubota, Yohei Sato, Akihiro Hori, Ryotaro Matsuda, Masaaki Ohba, Kenichi Kato, Masaki Takata, Susumu Kitagawa
  • Organizer: 4th International Conference on Metal-Organic Frameworks & Open Framework Compounds (mof2014)
  • Place of Presentation: Kobe International Conference Center
  • Year and Date: 2014-09-30
• [Presentation] Novel Synthetic Method and Physical Properties for Metal Nanoparticle@Metal-Organic Framework Hybrid Materials (2014)
  • Author(s): Hirokazu Kobayashi, Megumi Mukoyoshi, Hiroshi Kitagawa, Yoshiki Kubota, Tomokazu Yamamoto, Syo Matsumura
  • Organizer: 4th International Conference on Metal-Organic Frameworks & Open Framework Compounds (mof2014)
  • Place of Presentation: Kobe International Conference Center
  • Year and Date: 2014-09-29
• [Presentation] Direct Observation of Intermolecular Interactions by Simultaneous Measurement of Synchrotron X-Ray Diffraction and Raman Scattering (2014)
  • Author(s): Akihiro Hori, Masaaki Ohba, Yoshiki Kubota, Ryotaro Matsuda, Kenichi Kato, Masaki Takata, Susumu Kitagawa
  • Organizer: 4th International Conference on Metal-Organic Frameworks & Open Framework Compounds (mof2014)
  • Place of Presentation: Kobe International Conference Center
  • Year and Date: 2014-09-29
• [Presentation] Significantly Enhanced Hydrogen-Storage Capacity and Speed in Pd Nanocrystals Coated with HKUST-1 (2014)
  • Author(s): Guangqin Li, Hirokazu Kobayashi, Hiroshi Kitagawa, Yoshiki Kubota, Tomokazu Yamamoto, Syo Matsumura
  • Organizer: 4th International Conference on Metal-Organic Frameworks & Open Framework Compounds (mof2014)
  • Place of Presentation: Kobe International Conference Center
  • Year and Date: 2014-09-29
• [Presentation] ヨウ素を吸着した多孔性配位高分子[Fe(pz)Pd(CN)4]の結晶構造と磁性 (2013)
  • Author(s): 佐藤洋平、木村和史、堀彰宏、加藤健一、大谷亮、北川進、大場正昭、久保田佳基
  • Organizer: 日本結晶学会平成25年度年会
  • Place of Presentation: 熊本大学
• [Presentation] THE CRYSTAL STRUCTURE AND MAGNETIC PROPERTY OF IODINE ADSORBED [Fe(pz)Pd(CN)4] (2013)
  • Author(s): Yohei Sato, Kazufumi Kimura, Akihiro Hori, Ken-ichi Kato, Masaki Takata, Ryo Ohtani, Susumu Kitagawa, Masaaki Ohba and Yoshiki Kubota
  • Organizer: The 12th Conference of the Asian Crystallographic Association (AsCA’13)
  • Place of Presentation: Hong Kong University of Science and Technology (HKUST), Hong Kong
• [Presentation] PHASE STABILITY AND CRYSTAL STRUCTURE OF Sb-Te AND Bi-Te BINARY SYSTEM (2013)
  • Author(s): Takuya Tachizawa, Yoshiki Kubota, Kouichi Kifune, Toshiyuki Matsunaga, Noboru Yamada and Masaki Takata
  • Organizer: The 12th Conference of the Asian Crystallographic Association (AsCA’13)
  • Place of Presentation: Hong Kong University of Science and Technology (HKUST), Hong Kong
• [Presentation] 多孔性配位高分子[Cu(dhbc)2(L)]nの未知構造解析 (2013)
  • Author(s): 佐藤洋平、久保田佳基、犬伏康貴、高田昌樹
  • Organizer: 日本放射光学会
  • Place of Presentation: 名古屋大学
• [Presentation] スピンクロスオーバー現象を示すヨウ素包摂多孔性配位高分子の結晶構造解析 (2013)
  • Author(s): 木村和史、久保田佳基、堀彰宏、加藤健一、高田昌樹、大谷亮、北川進、大場正昭
  • Organizer: 日本放射光学会
  • Place of Presentation: 名古屋大学
• [Presentation] Incommensurate crystal structure of charge-density wave phase in spinel compound CuV2S4 (2012)
  • Author(s): Shogo Kawaguchi, Hiroki Ishibashi, Naruki Tsuji, Jungeun Kim, Kenichi Kato, Masaki Takata, Yoshiki Kubota
  • Organizer: Sagamore conference XVII
  • Place of Presentation: Daini Meisui Tei, Hokkaido
• [Presentation] 多孔性配位高分子[Cu(dhbc)2(L)]nの未知構造解析 (2012)
  • Author(s): 佐藤洋平、久保田佳基、犬伏康貴、高田昌樹
  • Organizer: 日本結晶学会
  • Place of Presentation: 東北大学