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Photomanipulation of varying magnetism in transition-metal complexes of the square antiprisum type

Research Project

Project/Area Number 24540342
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionHokkaido University

Principal Investigator

Yamamoto Shoji  北海道大学, 理学(系)研究科(研究院), 教授 (90252551)

Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Keywords光誘起磁性 / 遷移金属錯体 / 遍歴電子磁性 / 群論 / 経路積分法 / 光誘起相転移 / 遍歴強磁性 / シアノ架橋遷移金属錯体 / 四方逆プリズム型錯イオン / 実時間経路積分 / 角度分解光電子分光 / 遍歴電子強磁性 / 四方逆プリズム型錯体 / モリブデン化合物 / 光学伝導度
Outline of Final Research Achievements

We investigate the photoinduced bidirectional magnetism in Cu2[Mo(CN)8] consisting of square-antiprism-type Mo complexes. If we irradiate this material with blue laser light, it turns from paramagnetic to ferromagnetic. When we further irradiate this magnetized state with orrange laser light, the material is again demagnetized strongly.

First we elucidate the ground-state properties through a group-theoretical analysis. There appear a few different types of antiferromagnetism as well as ferromagnetism of our particular interest. With a realistic set of parameters, the material lies in the paramagnetic down to low temperatures. Then we numerically integrate the time-dependent Schroedinger equation and track the magnetization. The magnetization is indeed enhanced by blue laser light irradiation and again reduced by orrange laser light irradiation. Surprisingly, the final steady demagnetized state is qualitatively different from the initial static paramagnetic state.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (37 results)

All 2016 2015 2014 2013 2012

All Journal Article (10 results) (of which Peer Reviewed: 10 results,  Acknowledgement Compliant: 5 results,  Open Access: 2 results) Presentation (24 results) (of which Int'l Joint Research: 2 results,  Invited: 3 results) Book (3 results)

  • [Journal Article] Nuclear spin-lattice relaxation at field-induced level crossings in a Cr8F8 pivalate single crystal2016

    • Author(s)
      S. Yamamoto
    • Journal Title

      Physica B

      Volume: 481 Pages: 224-231

    • DOI

      10.1016/j.physb.2015.11.015

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Antiferromagnetic order in single crystals of the S=2 quasi-one-dimensional chain MnCl3(bpy)2016

    • Author(s)
      S. Shinozaki, A. Okutani, D. Yoshizawa, T. Kida, T. Takeuchi, S. Yamamoto, O.N. Risset, D.R. Talham, M.W. Meisel, and M. Hagiwara
    • Journal Title

      Phys. Rev. B

      Volume: 93 Issue: 1

    • DOI

      10.1103/physrevb.93.014407

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Phototunable magnetism in copper cctacyanomolybdate2014

    • Author(s)
      J. Ohara, S. Yamamoto
    • Journal Title

      The Scientific World Journal

      Volume: 2014

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Photoinduced directional and bidirectional phase transitions in bistable linear polycyclic aromatic compounds2014

    • Author(s)
      L. Zhang, S. Yamamoto
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 83

    • NAID

      40020091681

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photorefinement of the mixed ground state of a platinum-iodide nanotubular assembly2014

    • Author(s)
      L. Zhang, J. Ohara, S. Yamamoto
    • Journal Title

      JPS Conference Proceedings

      Volume: 3

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Symmetry argument of cyano-bridged copper-molybdenum complexes2013

    • Author(s)
      J. Ohara, S. Yamamoto
    • Journal Title

      Journal of the Korean Physical Society

      Volume: 62 Pages: 1797-1801

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] NMR observations of level crossings in a Cr8F8 pivalate single crystal2013

    • Author(s)
      S. Yamamoto, J. Ohara
    • Journal Title

      Journal of the Korean Physical Society

      Volume: 63 Pages: 499-503

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Theoretical scenario for the proton NMR observation of field-induced level crossings in a single crystal of [Cr8F8(piv)16]2012

    • Author(s)
      S. Yamamoto
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 81, 063705 Pages: 1-4

    • NAID

      210000109545

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Phase competition and photomagnetism in supramolecular assemblies based on cctacyanomolybdates of the square antiprism configuration2012

    • Author(s)
      S. Yamamoto, J. Ohara
    • Journal Title

      Physica Status Solid C

      Volume: 9 Pages: 2565-2569

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Magnetic properties of the S=2 Heisenberg antiferromagnetic chain compound MnCl3(bpy)2012

    • Author(s)
      M. Hagiwara, Y. Idutsu, Z. Honda, S. Yamamoto
    • Journal Title

      J. Physics.: Conference Series

      Volume: 400, 032014 Pages: 1-4

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Photoswitching of bistable homocyclic and heterocyclic aromatic polymers2016

    • Author(s)
      S. Yamamoto
    • Organizer
      Energy Materials Nanotechnology (EMN) Meeting on Optoelectronics 2016
    • Place of Presentation
      Phuket (Thailand)
    • Year and Date
      2016-04-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] フラストレイション系の修正スピン波理論―いかに修正するべきか?2016

    • Author(s)
      山本昌司, 大原潤
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学泉キャンパス(宮城県・仙台市)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 三角格子反強磁性体の磁気Raman散乱理論2016

    • Author(s)
      大原潤, 山本昌司
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学泉キャンパス(宮城県・仙台市)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 反強磁性スピン・チューブの磁気Raman散乱理論2016

    • Author(s)
      井上天, 山本昌司
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学泉キャンパス(宮城県・仙台市)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 低次元フェリ磁性体の核磁気緩和理論2016

    • Author(s)
      乗木優作, 山本昌司
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学泉キャンパス(宮城県・仙台市)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Photoinduced itinerant ferromagnetism in copper octacyanomolybdates2015

    • Author(s)
      J. Ohara, S. Yamamoto
    • Organizer
      nternational Workshop on Itinerant-Electron Magnetism
    • Place of Presentation
      Science Seminar House, Kyoto University(京都府・京都市)
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 異方的量子スピン模型のSchwingerボソン解析2015

    • Author(s)
      井上天, 山本昌司
    • Organizer
      日本物理学会2015年物性分野秋季大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府・吹田市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] ボソンによる三角格子Heisenberg反強磁性体の熱力学記述2015

    • Author(s)
      大原潤, 山本昌司
    • Organizer
      日本物理学会2015年物性分野秋季大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府・吹田市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 複核金属フェリ磁性体の次元クロスオーヴァ2015

    • Author(s)
      乗木優作, 山本昌司
    • Organizer
      日本物理学会2015年物性分野秋季大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府・吹田市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 反強磁性スピン四角柱の修正スピン波理論2015

    • Author(s)
      木村卓, 乗木優作, 山本昌司
    • Organizer
      日本物理学会2015年物性分野秋季大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府・吹田市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 2次元Heisenberg反強磁性体の修正スピン波理論再考2015

    • Author(s)
      乗木優作,山本昌司
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学(東京都新宿区)
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Research-status Report
  • [Presentation] 異方的三角格子反強磁性体の修正スピン波理論2015

    • Author(s)
      大原潤,山本昌司
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学(東京都新宿区)
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Research-status Report
  • [Presentation] Phototunable magnetism in octacyano-bridged bimetallic assemblies2014

    • Author(s)
      S. Yamamoto, J. Ohara
    • Organizer
      Fujihara Seminar: Real-time Dynamics of Physical Phenomena and Manipulation by External Fields
    • Place of Presentation
      Hotel New Ohji(北海道苫小牧市)
    • Year and Date
      2014-09-23 – 2014-09-27
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] コロネン分子の対称性と外場応答2014

    • Author(s)
      大原潤,山本昌司
    • Organizer
      日本物理学会2014年物性分野秋季大会
    • Place of Presentation
      中部大学(愛知県春日井市)
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Research-status Report
  • [Presentation] ポリアセン及びヘテロアセンにおける非可逆/可逆光誘起相転移2014

    • Author(s)
      山本昌司
    • Organizer
      日本物理学会第69回年次大会
    • Place of Presentation
      東海大学,平塚市
    • Related Report
      2013 Research-status Report
  • [Presentation] 光で観る四方逆プリズムMo錯体の光磁性2014

    • Author(s)
      大原潤
    • Organizer
      日本物理学会第69回年次大会
    • Place of Presentation
      東海大学,平塚市
    • Related Report
      2013 Research-status Report
  • [Presentation] 梯子型ハロゲン架橋白金錯体の基底状態光制御2013

    • Author(s)
      大原潤
    • Organizer
      日本物理学会物性分野秋季大会
    • Place of Presentation
      徳島大学,徳島市
    • Related Report
      2013 Research-status Report
  • [Presentation] Polarization effect on photoinduced phase transtions in a platinum-iodide square-prism compound2013

    • Author(s)
      張龍龍
    • Organizer
      日本物理学会物性分野秋季大会
    • Place of Presentation
      徳島大学,徳島市
    • Related Report
      2013 Research-status Report
  • [Presentation] Cu2[Mo(CN)8]8H2Oにおける磁化の双方向スウィッチング2013

    • Author(s)
      山本昌司
    • Organizer
      日本物理学会物性分野秋季大会
    • Place of Presentation
      徳島大学,徳島市
    • Related Report
      2013 Research-status Report
  • [Presentation] Phase competition and photomagnetism in supramolecular assemblies based on cctacyanomolybdates of the square antiprism configuration2012

    • Author(s)
      S. Yamamoto
    • Organizer
      International Conference on Optical, Optoelectronic and Photonic Materials and Applications (ICOOPMA 2012)
    • Place of Presentation
      奈良県立公会堂 (奈良県)
    • Related Report
      2012 Research-status Report
  • [Presentation] NMR observations of level crossings in a Cr8F8 pivalate single crystal: The solution to the structured enhancement of 1/T12012

    • Author(s)
      S. Yamamoto
    • Organizer
      International Conference on Magnetism (ICM 2012)
    • Place of Presentation
      Busan Exhibition Convention Center (Korea)
    • Related Report
      2012 Research-status Report
  • [Presentation] Symmetry argument of cyano-bridged copper-molybdenum complexes2012

    • Author(s)
      J. Ohara
    • Organizer
      International Conference on Magnetism (ICM 2012)
    • Place of Presentation
      Busan Exhibition Convention Center (Korea)
    • Related Report
      2012 Research-status Report
  • [Presentation] NMRで観る環状分子磁性体のスピン・ダイナミクス2012

    • Author(s)
      山本昌司
    • Organizer
      日本物理学会シンポジウム『単分子磁性体研究の深化と多角化』
    • Place of Presentation
      横浜国立大学 (横浜市)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 四方逆プリズムMo錯化合物に観る光スウィッチング磁性2012

    • Author(s)
      山本昌司
    • Organizer
      基礎物理学研究所短期研究会『量子スピン系の物理』
    • Place of Presentation
      京都大学 (京都市)
    • Related Report
      2012 Research-status Report
  • [Book] Molybdenum and Its Compounds: Applications, Electrochemical Properties and Geological Implications2014

    • Author(s)
      J. Ohara, S. Yamamoto
    • Total Pages
      449
    • Publisher
      Nova Science, New York
    • Related Report
      2014 Research-status Report
  • [Book] Platinum: Compounds, Production and Applications2013

    • Author(s)
      S. Yamamoto, J. Ohara (L. Varennikov, E. Yedemsky; Editors)
    • Total Pages
      153
    • Publisher
      Nova Science
    • Related Report
      2013 Research-status Report
  • [Book] Platinum: Compounds, Production and Applications2013

    • Author(s)
      S. Yamamoto, J. Ohara (edited by L. Varennikov and E. Yedemsky)
    • Total Pages
      153
    • Publisher
      Nova Science
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2020-05-15  

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